Reaction
ChemicalBook > CAS DataBase List > Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)

Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)

Reaction
Product Name
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
CAS No.
1702744-45-3
Chemical Name
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
Synonyms
Nicl(O-Tolyl)(Tmeda);chloro(2-methylphenyl)(N,N,N`,N`-tetramethyl-1,2-ethylenediamine)nickel;Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II);Chloro(2-methylphenyl)(N,N,N'',N''-tetramethyl-1,2-ethylenediamine)nickel(II);CHLORO(2-METHYLPHENYL)(N,N,N',N'-TETRAMETHYL-1,2-ETHYLENEDIAMINE)NICKEL(II),99%(CONTAINSABOUT5%O-CHLOROTOLUENE)NICL(O-TOLYL)(TMEDA);Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 10% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
CBNumber
CB63357073
Molecular Formula
C13H23ClN2Ni
Formula Weight
301.48152
MOL File
1702744-45-3.mol
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Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Property

form 
Powder
color 
dark-orange
Sensitive 
air sensitive
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Safety

Risk Statements 
45-42/43
Safety Statements 
53-22-36/37/39-45
TSCA 
No
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
804398
Product name
[(TMEDA)Ni(o-tolyl)Cl]
Purity
95%
Packaging
100MG
Price
$88.3
Updated
2023/06/20
Strem Chemicals
Product number
28-0165
Product name
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 5% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
Packaging
500mg
Price
$114
Updated
2024/03/01
Strem Chemicals
Product number
28-0165
Product name
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 5% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
Packaging
2g
Price
$342
Updated
2024/03/01
Strem Chemicals
Product number
28-0165
Product name
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 5% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
Packaging
10g
Price
$1369
Updated
2024/03/01
ChemSupplyAustralia
Product number
300971
Product name
N,N,N’,N’-Tetramethylethylenediaminechloro(2-methylphenyl)nickel(II), 97%
Packaging
250mg
Price
$60.5
Updated
2021/12/16
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Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Chemical Properties,Usage,Production

Reaction

  1. Air-Stable Nickel precatalyst for cross-coupling
  2. Precatalyst allowing various ligands to be used (monoand bidendate phosphines, diimines and NHCs)

Uses

Effective precatalyst for a variety of nickel-catalyzed transformations, including Suzuki-Miyaura, Buchwald-Hartwig and other cyclizations and oxidative couplings.

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Suppliers

Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
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China
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Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
Tianjin Kailiqi Biotechnology Co., Ltd.
Tel
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Fax
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Email
klq@cw-bio.com
Country
China
ProdList
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Aikon International Limited
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Fax
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China
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Beijing Jin Ming Biotechnology Co., Ltd.
Tel
010-60605840 15801484223;
Email
psaitong@jm-bio.com
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Bide Pharmatech Ltd.
Tel
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sales@picasso-e.com
Country
China
ProdList
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Wuhan Shenxinda Chemical Technology Co., Ltd.
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Baoji Funuokang Industrial Co., Ltd
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Shanghai Haohong Scientific Co., Ltd.
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Country
China
ProdList
39990
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1702744-45-3, Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)Related Search:


  • CHLORO(2-METHYLPHENYL)(N,N,N',N'-TETRAMETHYL-1,2-ETHYLENEDIAMINE)NICKEL(II),99%(CONTAINSABOUT5%O-CHLOROTOLUENE)NICL(O-TOLYL)(TMEDA)
  • Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 10% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
  • Nicl(O-Tolyl)(Tmeda)
  • Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
  • chloro(2-methylphenyl)(N,N,N`,N`-tetramethyl-1,2-ethylenediamine)nickel
  • Chloro(2-methylphenyl)(N,N,N'',N''-tetramethyl-1,2-ethylenediamine)nickel(II)
  • 1702744-45-3
  • C13H23ClN2Ni