ChemicalBook > CAS DataBase List > 2,2'-Biimidazole

2,2'-Biimidazole

Product Name
2,2'-Biimidazole
CAS No.
492-98-8
Chemical Name
2,2'-Biimidazole
Synonyms
bisimidazole;1H,1'H-2,2'-BiiMidazole;DK7399;DK7719;NSC 522950;2-BIIMIDAZOLE;2,2'-BIIMIDAZOLE;2,2'-Diimidazole;2,2'-Biimidazole;2,2'-Bisimidazole
CBNumber
CB6356248
Molecular Formula
C6H6N4
Formula Weight
134.14
MOL File
492-98-8.mol
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2,2'-Biimidazole Property

Melting point:
>350°C
Boiling point:
455.5±28.0 °C(Predicted)
Density 
1.371±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
pka
pK1: 5.01(+1) (25°C,μ= 0.3)
color 
Light yellow to Brown to Dark green
λmax
274nm(HCl aq.)(lit.)
InChI
InChI=1S/C6H6N4/c1-2-8-5(7-1)6-9-3-4-10-6/h1-4H,(H,7,8)(H,9,10)
InChIKey
AZUHIVLOSAPWDM-UHFFFAOYSA-N
SMILES
C1(C2NC=CN=2)NC=CN=1
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Safety

Hazard Codes 
Xi
HS Code 
2933.29.4300
HazardClass 
IRRITANT
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B2487
Product name
2,2'-Biimidazole
Purity
>98.0%(HPLC)(T)
Packaging
1g
Price
$157
Updated
2024/03/01
TCI Chemical
Product number
B2487
Product name
2,2'-Biimidazole
Purity
>98.0%(HPLC)(T)
Packaging
5g
Price
$543
Updated
2024/03/01
TRC
Product number
B695145
Product name
1H,1''H-2,2''-Biimidazole
Packaging
500mg
Price
$90
Updated
2021/12/16
AK Scientific
Product number
4239AE
Product name
2,2'-Biimidazole
Packaging
1g
Price
$103
Updated
2021/12/16
ChemScene
Product number
CS-W021324
Product name
1H,1'H-2,2'-Biimidazole
Purity
≥97.0%
Packaging
5g
Price
$142
Updated
2021/12/16
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2,2'-Biimidazole Chemical Properties,Usage,Production

Chemical Properties

2,2'-Biimidazole is soluble in polar solvents such as methanol, water and dimethyl sulfoxide (DMSO).

Uses

1H,1''H-2,2''-Biimidazole is used in the preparation of complexes that exhibits photoluminescence and optical properties. Also used in the preparation of bismuth biimidazoles as semi-conductors.

Application

2,2'-Biimidazole is an important organic reagent used as:
(1) Preparation of catalytically active coordination compounds. It is a Lewis base capable of producing coordination compounds with metal ions such as Cu(I), Ag(I), Au(I-II) and palladium, which are used as efficient catalysts in other chemical reactions.
(2) Construction of hypercrosslinked polymers 2,2′-biimidazolyl HCPs, which are used as adsorbents and sensors for iodine capture and DNP detection in the field of environmental remediation.
(3) Synthesis of fluorescent proteins, nanoparticles and other ligand compounds.

Synthesis

120 ml of distilled water was added to 1,092 g (14.2 mol, 4.0 eq.) of ammonium acetate at 40 ℃, 500 g of 20 wt percent aqueous glyoxal (3.45 mol) was then slowly added dropwise to the resulting slurry for three hours while stirring vigorously. Immediately after the addition was finished, the reaction mixture was neutralized with distilled water to adjust the pH to 5-7. The produced brown-colored solid was filtered and washed alternately with 500 ml of acetone and 500 ml of distilled water several times to obtain 82.0 g (53.2 percent yield) of 2,2'-Biimidazole.

2,2'-Biimidazole Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2'-Biimidazole Suppliers

Henan Copyrene New Material Technology Co., Ltd.
Tel
13144621062
Email
15938783487@163.com
Country
China
ProdList
56
Advantage
58
SiChuang NanBu Honesty Technology Co., Ltd.
Tel
0838-5675166 15883665058
Fax
0838-5675535
Email
nbcxkj@126.com
Country
China
ProdList
668
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7639
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
Country
China
ProdList
42982
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
13355009207 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18739
Advantage
57
Shanghai Jian Chao Chemical Technology Co., Ltd.
Tel
18017383231 18017383231
Fax
qq:2817624287
Email
lyh_antaeus@163.com
Country
China
ProdList
9352
Advantage
55
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
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View Lastest Price from 2,2'-Biimidazole manufacturers

Hebei Mojin Biotechnology Co., Ltd
Product
2,2'-BIIMIDAZOLE 492-98-8
Price
US $100.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5000KG
Release date
2023-08-25
Hebei Guanlang Biotechnology Co., Ltd.
Product
2,2'-BIIMIDAZOLE 492-98-8
Price
US $10.00/PCS
Min. Order
1KG
Purity
99%
Supply Ability
100 mt
Release date
2021-05-08
Shaanxi Dideu Medichem Co. Ltd
Product
2,2'-Biimidazole 492-98-8
Price
US $0.10/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000 tons
Release date
2019-12-31