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TETRATHIAFULVALENE

Product Name
TETRATHIAFULVALENE
CAS No.
31366-25-3
Chemical Name
TETRATHIAFULVALENE
Synonyms
TTF;ARHH;RHOH;NSC 222862;etrathiafulvalene;TETRATHIAFULVALENE;Tetrathiafulvalene 97%;Tetrathiafulvalene,98%;Tetrathiafulvalene,97%;ω-2,2’-Bi-1,3-dithiole
CBNumber
CB6359496
Molecular Formula
C6H4S4
Formula Weight
204.34
MOL File
31366-25-3.mol
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TETRATHIAFULVALENE Property

Melting point:
116-119 °C (lit.)
Boiling point:
90℃ (1 Torr)
Density 
1.448 (estimate)
refractive index 
1.6000 (estimate)
storage temp. 
2-8°C
form 
Crystals or Crystalline Powder
color 
Orange to brownish
Water Solubility 
It is insoluble in water. Soluble in organic solvents.
Sensitive 
Air & Light Sensitive
λmax
369nm(CHCl3)(lit.)
Merck 
14,9242
BRN 
1617956
InChIKey
FHCPAXDKURNIOZ-UHFFFAOYSA-N
CAS DataBase Reference
31366-25-3(CAS DataBase Reference)
EPA Substance Registry System
1,3-Dithiole, 2-(1,3-dithiol-2-ylidene)- (31366-25-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
43-52/53
Safety Statements 
36/37-61-24/25
RIDADR 
3335
WGK Germany 
3
F 
10-23
TSCA 
Yes
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P321Specific treatment (see … on this label).

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
183180
Product name
Tetrathiafulvalene
Purity
97%
Packaging
250mg
Price
$72.8
Updated
2023/06/20
Sigma-Aldrich
Product number
183180
Product name
Tetrathiafulvalene
Purity
97%
Packaging
1g
Price
$244
Updated
2023/06/20
TCI Chemical
Product number
T0980
Product name
Tetrathiafulvalene
Purity
>98.0%(GC)
Packaging
1g
Price
$160
Updated
2024/03/01
TCI Chemical
Product number
T0980
Product name
Tetrathiafulvalene
Purity
>98.0%(GC)
Packaging
5g
Price
$475
Updated
2024/03/01
Alfa Aesar
Product number
L19229
Product name
Tetrathiafulvalene, 97%
Packaging
250mg
Price
$56.65
Updated
2024/03/01
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TETRATHIAFULVALENE Chemical Properties,Usage,Production

Chemical Properties

ORANGE TO BROWNISH CRYSTALS OR CRYSTALLINE POWDER

Uses

Electron donor for supramolecular synthesis,1 charge-transfer complex synthesis2 with 7,7,8,8-tetracyanoquinodimethane (cat. no. 157635), and for electron transfer to diazonium salts.3

Uses

Tetrathiafulvalene, holds wide application in HPLC, NMR. This heterocyclic compound contributed to the development of molecular electronics. They are used as a organic super conductors.

Uses

Molecular sensors; radical catalyst.

Definition

ChEBI: Tetrathiafulvalene is a member of the class of fulvalenes that is ethene substituted by 1,3-dithiol-2-ylidene groups at positions 1 and 2. It is an organosulfur heterocyclic compound and a member of fulvalenes.

General Description

Tetrathiafulvalene (TTF) is an electron-donor which consists of oligomers, dendrimers and polymers which can be used in the formation of redox macromolecules.

Purification Methods

Recrystallise it from cyclohexane/hexane under an argon atmosphere [Kauzlarich et al. J Am Chem Soc 109 4561 1987]. [Beilstein 19/11 V 380.]

TETRATHIAFULVALENE Preparation Products And Raw materials

Raw materials

Preparation Products

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TETRATHIAFULVALENE Suppliers

Belgium 1 China 117 Germany 2 India 3 Japan 2 South Korea 1 Switzerland 1 United Kingdom 5 United States 15 Global 147
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View Lastest Price from TETRATHIAFULVALENE manufacturers

Career Henan Chemical Co
Product
TETRATHIAFULVALENE 31366-25-3
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2020-01-07

31366-25-3, TETRATHIAFULVALENERelated Search:

TETRAKIS(OCTADECYLTHIO)TETRATHIAFULVALENE,Tetrakis(octadecylthio)tetrathiafulvalene [Organic Electronic Material] BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE BIS(CARBONYLDITHIO)TETRATHIAFULVALENE 4,4',5-TRIMETHYLTETRATHIAFULVALENE Bis(methylenedithio)tetrathiafulvalene [Organic Electronic Material],BIS(METHYLENEDITHIO)TETRATHIAFULVALENE TETRATHIAFULVALENE TRIS(TETRATHIAFULVALENE) BIS(TETRAFLUOROBORATE) COMPLEX,TETRATHIAFULVALENE FLUOROBORATE 4,4'-DIMETHYLTETRATHIAFULVALENE TPT-TTF TETRAKIS(METHYLTHIO)TETRATHIAFULVALENE,Tetrakis(methylthio)tetrathiafulvalene [Organic Electronic Material] Bis-cyclohexyl-tetrathiafulvalene,BIS-TETRAMETHYLENE-TETRATHIAFULVALENE 4,4'-DIMETHYL-5,5'-DIPHENYLTETRATHIAFULVALENE 4,4'-DI-PHENYL-TETRATHIAFULVALENE 2H4-Tetrathiafulvalene,TETRATHIAFULVALENE-D4 2,3,6,7-TETRAKIS(BENZOYLTHIO)TETRATHIAFULVALENE BIS(ETHYLENEDIOXY)TETRATHIAFULVALENE 2,3,6,7-TETRAKIS(ETHYLTHIO)TETRATHIAFULVALENE BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE-D8

  • 1,3-Dithiole, 2-(1,3-dithiol-2-ylidene)-
  • 1,4,5,8-Tetrathiafulvalen
  • 1,4,5,8-Tetrathiafulvalene
  • 2-(1,3-dithiol-2-ylidene)-1,3-dithiol
  • Δ2,2μ-Bi-1,3-dithiole, TTF
  • Delta2,2'-bi-1,3-dithiol
  • [2,2']-Bi[1,3]-dithioylidene
  • Tetrathiafulvalene, 99+% 1GR
  • Tetrathiafulvalene, 99+% 250MG
  • Anti-RHOH, C-Terminal antibody produced in rabbit
  • ARHH
  • GTP-binding protein TTF
  • RHOH
  • Rho-related GTP-binding protein RhoH
  • Tetrathiafulvalene (purified by sublimation)
  • NSC 222862
  • Tetrathiafulvalene 97%
  • Tetrathiafulvalene, 98.5%
  • 2,2'-bi(1,3-dithiolylidene)
  • DELTA2,2'-BI-1,3-DITHIOLE
  • DELTA^2^,^2^-Bi-1,3-dithiole~TTF
  • delta-2:2-bis(1,3-dithiazole)
  • TetrathiafulvaleneTTForangextl
  • Tetrathiafulvalene,98%
  • Tetrathiafulvalene,97%
  • Tetrathiafulvalene, 99+%
  • 2-(1,3-Dithiol-2-ylidene)-1,3-dithiole
  • 2-(1,3-dithiol-2-ylidene)-3-dithiole
  • ω-2,2’-Bi-1,3-dithiole
  • Tetrathiafulvalene,98+%TTF
  • TETRATHIAFULVALENE TTF
  • TETRATHIAFULVALENE
  • TTF
  • etrathiafulvalene
  • tetrathiafulvalene dication
  • 2,2'-Bi(1,3-dithiolylidene)
  • 31366-25-3
  • C6H4S4
  • Heterocyclic Building Blocks
  • Others
  • S-Containing
  • Building Blocks
  • Donors (Charge Transfer Complexes)
  • TTF Derivatives
  • Charge Transfer Complexes for Organic Metals
  • Functional Materials
  • TTF Derivatives
  • Building Blocks
  • Chemical Synthesis
  • Heterocyclic Building Blocks
  • Materials Science
  • Organic and Printed Electronics
  • Organic Field Effect Transistor (OFET) Materials
  • Others
  • p-Type Organic Semiconductors
  • p-Type Small Molecules
  • S-Containing
  • Charge Transfer Complexes for Organic Metals