ChemicalBook > CAS DataBase List > 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE

4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE

Product Name
4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE
CAS No.
19312-06-2
Chemical Name
4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE
Synonyms
4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE;4,4-Dimethyl-2-phenyl-2-oxazoline 96%;Oxazole, 4,5-dihydro-4,4-dimethyl-2-phenyl-;4,4-Dimethyl-2-phenyl-4,5-dihydro-1,3-oxazole;4,4-Dimethyl-2-phenyl-2-oxazoline
CBNumber
CB6376123
Molecular Formula
C11H13NO
Formula Weight
175.23
MOL File
19312-06-2.mol
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4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Property

Melting point:
20-24 °C(lit.)
Boiling point:
124 °C20 mm Hg(lit.)
Density 
1.025 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.5322(lit.)
Flash point:
217 °F
pka
4.82±0.70(Predicted)
BRN 
132225
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
346292
Product name
4,4-Dimethyl-2-phenyl-2-oxazoline
Purity
96%
Packaging
10g
Price
$65.3
Updated
2023/06/20
Sigma-Aldrich
Product number
346292
Product name
4,4-Dimethyl-2-phenyl-2-oxazoline
Purity
96%
Packaging
50g
Price
$45
Updated
2022/05/15
American Custom Chemicals Corporation
Product number
CHM0115329
Product name
4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE
Purity
95.00%
Packaging
10G
Price
$1117.91
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0115329
Product name
4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE
Purity
95.00%
Packaging
50G
Price
$2468.07
Updated
2021/12/16
AK Scientific
Product number
0600AQ
Product name
4,4-Dimethyl-2-phenyl-2-oxazoline
Packaging
50g
Price
$105
Updated
2021/12/16
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4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Chemical Properties,Usage,Production

Uses

4,4-Dimethyl-2-phenyl-2-oxazoline may be used in the synthesis of an ester-ammonium salt via rupture of oxazoline ring.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 2032, 1960 DOI: 10.1021/ja01493a045
Tetrahedron Letters, 27, p. 5269, 1986 DOI: 10.1016/S0040-4039(00)85187-4

General Description

4,4-Dimethyl-2-phenyl-2-oxazoline is an 2-aryl-2-oxazoline and has been tested as as ligand for the Suzuki coupling reaction of aryl bromides and arylboronic acids. 4,4-Dimethyl-2-phenyl-2-oxazoline forms mildly hygroscopic complexes, of general formulae [ZnX2(ox)2] (ox =4,4-Dimethyl-2-phenyl-2-oxazoline), with ether solutions of [ZnX2] (X = Cl, Br, I).Except ZnI2, which does not form an isolable complex due to steric reasons.

4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Suppliers

China 23 Germany 2 Switzerland 1 Ukraine 1 United Kingdom 1 United States 11 Global 39
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19312-06-2, 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINERelated Search:

4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE 2-(2-METHOXYPHENYL)-4,4-DIMETHYL-2-OXAZOLINE 2-(4-BROMO-PHENYL)-4,4-DIMETHYL-4,5-DIHYDRO-OXAZOLE 2-(2,6-DIMETHOXYPHENYL)-4,4-DIMETHYL-2-OXAZOLINE 2-(3-BROMOPHENYL)-4,5-DIHYDRO-4,4-DIMETHYLOXAZOLE 2-(2-FLUOROPHENYL)-4,5-DIHYDRO-4,4-DIMETHYLOXAZOLE 2-(4-CHLOROPHENYL)-4,5-DIHYDRO-4,4-DIMETHYLOXAZOLE 2-(2-BROMOPHENYL)-4,5-DIHYDRO-4,4-DIMETHYLOXAZOLE 2-(4-METHOXYPHENYL)-4,4-DIMETHYL-4,5-DIHYDRO-1,3-OXAZOLE 4,4-DIMETHYL-2-(4'-METHYL-2-BIPHENYLYL)-2-OXAZOLINE 4,5-DIHYDRO-4,4-DIMETHYL-2-O-TOLYLOXAZOLE Oxazole, 2-(4-fluorophenyl)-4,5-dihydro-4,4-dimethyl- 2-(3,4-DIMETHOXYPHENYL)-4,4-DIMETHYL-4,5-DIHYDRO-1,3-OXAZOLE 4,5-DIHYDRO-4,4-DIMETHYL-2-P-TOLYLOXAZOLE 4-(4,5-DIHYDRO-4,4-DIMETHYLOXAZOL-2-YL)BENZENAMINE 4,5-DIHYDRO-4,4-DIMETHYL-2-(4-NITROPHENYL)OXAZOLE [4-(HYDROXYMETHYL)-2-PHENYL-4,5-DIHYDRO-1,3-OXAZOL-4-YL]METHANOL 4,5-DIHYDRO-4,4-DIMETHYL-2-(3-NITROPHENYL)OXAZOLE

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