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Bis(4-biphenylyl)amine

Product Name
Bis(4-biphenylyl)amine
CAS No.
102113-98-4
Chemical Name
Bis(4-biphenylyl)amine
Synonyms
2BP;Bis(4-biphenyl)amine;N,N-Bis(4-phenylphenyl)amine;IBBP;biphen-4-yl amine;Two(4-biphenyl)aMine;4,4'-IMINOBIS(BIPHEN;Bis(4-biphenylyl)amin;di (4-biphenyl) amine;BIS(4-lBIPHENY) AMINE
CBNumber
CB6425418
Molecular Formula
C24H19N
Formula Weight
321.41
MOL File
102113-98-4.mol
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Bis(4-biphenylyl)amine Property

Melting point:
209 °C
Boiling point:
507.0±39.0 °C(Predicted)
Density 
1.123±0.06 g/cm3(Predicted)
vapor pressure 
0-0Pa at 20-50℃
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Acetonitrile (Slightly), Chloroform (Slightly), DMSO (Slightly)
pka
0.67±0.40(Predicted)
form 
Solid
color 
White to Off-White
InChI
InChI=1S/C24H19N/c1-3-7-19(8-4-1)21-11-15-23(16-12-21)25-24-17-13-22(14-18-24)20-9-5-2-6-10-20/h1-18,25H
InChIKey
JAUCIDPGGHZXRP-UHFFFAOYSA-N
SMILES
C1(C2=CC=CC=C2)=CC=C(NC2=CC=C(C3=CC=CC=C3)C=C2)C=C1
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Safety

HS Code 
2921490090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B2429
Product name
Bis(4-biphenylyl)amine
Purity
>98.0%(GC)
Packaging
1g
Price
$32
Updated
2024/03/01
TCI Chemical
Product number
B2429
Product name
Bis(4-biphenylyl)amine
Purity
>98.0%(GC)
Packaging
5g
Price
$121
Updated
2024/03/01
TRC
Product number
B412968
Product name
Bis-Biphenyl-4-yl-amine
Packaging
500mg
Price
$125
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB62291
Product name
Bis(4-biphenylyl)amine
Packaging
10g
Price
$150
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB62291
Product name
Bis(4-biphenylyl)amine
Packaging
25g
Price
$200
Updated
2021/12/16
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Bis(4-biphenylyl)amine Chemical Properties,Usage,Production

Uses

Bis(4-biphenylyl)amine can be used as organic synthesis intermediate and pharmaceutical intermediate, mainly in laboratory research and development process and chemical production process.

Synthesis


Bis(4-bromophenyl)amine (4.0 g, 12.3 mmol) and phenylboronic acid (4.0 g, 32.7 mmol) were mixed in 250 mL of toluene and 60 mL of ethanol. The solution was bubbled with nitrogen while stirring for 15 minutes. Pd(PPh3)4 (1.4 g, 1.23 mmol) and K3PO4 (13.5 g, 64 mmol) were added in sequence. The mixture was heated to reflux overnight under nitrogen. After cooling, the reaction mixture was filtered through filter paper and the solvent was then evaporated. The solid was redissolved in nitrogen-purged hot toluene and was filtered through a Celite?/silica pad when the solution was still hot. The solvent was then evaporated. The white crystalline solid was washed by hexane and air dried to obtain 3.8 g of Bis(4-biphenylyl)amine.

Bis(4-biphenylyl)amine Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Bis(4-biphenylyl)amine manufacturers

Henan Fengda Chemical Co., Ltd
Product
Bis(4-biphenylyl)amine 102113-98-4
Price
US $200.00-1.00/KG
Min. Order
1KG
Purity
99%, 99.5% Sublimated
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-30
Shanghai Daken Advanced Materials Co.,Ltd
Product
[1,1'-Biphenyl]-4-amine,N-[1,1'-biphenyl]-4-yl- 102113-98-4
Price
US $0.00/KG
Min. Order
1KG
Purity
98.00%
Supply Ability
150KG /month
Release date
2021-11-19
Hebei Xinsheng New Material Technology Co., LTD.
Product
Bis(4-biphenylyl)amine 102113-98-4
Price
US $35.00-25.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 Ton
Release date
2023-11-06

102113-98-4, Bis(4-biphenylyl)amineRelated Search:


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  • BIS(4-lBIPHENY) AMINE
  • N-Biphenyl-4-yl-biphenyl-4-ylamine
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  • OLED materials,pharm chemical,electronic
  • 102113-98-4