ALLYLDIPHENYLPHOSPHINE OXIDE

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ALLYLDIPHENYLPHOSPHINE OXIDE

Product Name: ALLYLDIPHENYLPHOSPHINE OXIDE
CAS No.: 4141-48-4
Chemical Name: ALLYLDIPHENYLPHOSPHINE OXIDE
Synonyms: NSC 98715;NSC 616249;NISTC4141484;Alydiphenylphosphine oxide;ALLYLDIPHENYLPHOSPHINE OXIDE;Diphenylallylphosphine oxide;Allyldiphenylphosphine oxide 97%;[allyl(phenyl)phosphoryl]benzene;Allyldiphenylphosphine Oxide >Diphenyl-2-propenylphosphine oxide
CBNumber: CB6427654
Molecular Formula: C15H15OP
Formula Weight: 242.25
MOL File: 4141-48-4.mol

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ALLYLDIPHENYLPHOSPHINE OXIDE Property

Melting point:: 110-114 °C(lit.)
Boiling point:: 200-202 °C(Press: 2 Torr)
Density: 1.0769 g/cm3
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: sol THF; slightly sol ether; insol hexane.
form: solid

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical

Product number: A1463
Product name: Allyldiphenylphosphine Oxide
Purity: >98.0%(GC)
Packaging: 1g
Price: $179
Updated: 2021/12/16

TRC

Product number: A614518
Product name: Allyldiphenylphosphine Oxide
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA75422
Product name: Allyldiphenylphosphine Oxide
Packaging: 5G
Price: $84
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA75422
Product name: Allyldiphenylphosphine Oxide
Packaging: 10g
Price: $146.4
Updated: 2021/12/16

Chem-Impex

Product number: 41118
Product name: Allyldiphenylphosphineoxide,98%(GC)
Purity: 98%(GC)
Packaging: 1G
Price: $188.16
Updated: 2021/12/16

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ALLYLDIPHENYLPHOSPHINE OXIDE Chemical Properties,Usage,Production

Uses

Reactant for:

Preparaton of a-substituted alkylsilanes via regio- and chemoselective copper-catalyzed silylzincation and electrophilic substitution from terminal alkenes, and prepn. of α-substituted alcohols via Fleming-Tamao oxidation of alkylsilanes
Olefin isomerization with Grubbs′ catalysts occluded in a hydrophobic matrix of polydimethylsiloxane (PDMS)
C9-substituted trans-hydrindene via diastereotopic group-selective intramolecular Diels-Alder reaction
Isomerization of allyl group-containing compounds to propenyl group-containing compounds in the presence of a Grubbs second-generation Ru catalyst
Ruthenium-catalyzed olefin cross-metathesis of vinyl and allyl phosphine oxides to give alkenyl phosphine oxides and bis-phosphine oxides

Synthesis

The synthesis method of Allyldiphenylphosphine Oxide: (1) rearrangement of allyl diphenylphosphinite and (2) Arbuzov reaction of alkyl diphenylphosphinite with Allyl Bromide. Other new methods have also been developed. Structurally related analogs prepared include 2- methylallyldiphenylphosphine oxide, 2-phenylallyldiphenylphosphine oxide, 1- methoxyallyldiphenylphosphine oxide, crotyldiphenylphosphine oxide, and 1-substituted allylic diphenylphosphine oxide[1].

Synthesis

Purification: recrystallization from ether/hexane, benzene/petroleum ether, cyclohexane, or benzene[2].

References

1. (a) Ukai, J.; Ikeda, Y.; Ikeda, N.; Yamamoto, H. TL 1983, 24, 4029. (b) Ikeda, Y.; Ukai, J.; Ikeda, N.; Yamamoto, H. T 1987, 43, 723. (c) Burke, S. D.; Armistead, D. M.; Shankaran, K. TL 1986, 27, 6295.
2. Berlin, K. D.; Calvert, J. F. Proc. Okla. Acad. Sci. 1966, 46, 78

ALLYLDIPHENYLPHOSPHINE OXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4141-48-4, ALLYLDIPHENYLPHOSPHINE OXIDERelated Search:

ALLYLDIPHENYLPHOSPHINE Allylboronic acid pinacol ester ALLYLTRIETHOXYSILANE Probenazole Allicin ALLYLUREA Diethyl allylmalonate Allylbenzene Allyl Benzyl Ether Dimethyl allylmalonate Allyl methyl carbonate DIETHYL ALLYLPHOSPHONATE 1-allylhydrazine hydrochloride Allylhydrazine Dihydrochloride ALLYLHYDRAZINE 2-Allyloxyethanol Diphenylphosphine oxide ALLYLDIPHENYLPHOSPHINE OXIDE

Phosphine oxide,diphenyl-2-propen-1-yl-

ALLYLDIPHENYLPHOSPHINE OXIDE

Alydiphenylphosphine oxide

NISTC4141484

Diphenylallylphosphine oxide

[allyl(phenyl)phosphoryl]benzene

[phenyl(prop-2-enyl)phosphoryl]benzene

Diphenyl-2-propenylphosphine oxide

NSC 616249

NSC 98715

Allyldiphenylphosphine oxide 97%

Allyldiphenylphosphine Oxide &gt

4141-48-4

H2CCHCH2PC6H52O

C15H15OP

Catalysis and Inorganic Chemistry

Phosphorus Compounds

Phosphine Ligands

Catalysis and Inorganic Chemistry

Phosphine Ligands

Phosphorus Compounds