Description Uses Chemical Synthesis Preparation Sources
ChemicalBook > CAS DataBase List > Bismuth nitrate pentahydrate

Bismuth nitrate pentahydrate

Description Uses Chemical Synthesis Preparation Sources
Product Name
Bismuth nitrate pentahydrate
CAS No.
10035-06-0
Chemical Name
Bismuth nitrate pentahydrate
Synonyms
BISMUTH(III) NITRATE;BISMUTH TRINITRATE PENTAHYDRATE;Bismuth(Ⅲ) nitrate pentahydrate;BISMUTH(III) NITRATE PENTAHYDRATE;BismuthNitrateGr;Bismuth trinitrate;Bismuth(III)-nitrat;Bismuth Nitrate ACS;BISMUTH NITRATE 5H2O;BismuthNitrate5H2OAcs
CBNumber
CB6438568
Molecular Formula
BiH10N3O14
Formula Weight
485.07
MOL File
10035-06-0.mol
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Bismuth nitrate pentahydrate Property

Melting point:
30 °C(lit.)
Boiling point:
75-80 °C(lit.)
Density 
2,83 g/cm3
solubility 
Soluble in dilute nitric acid solution, dilute acetic acid, glycerol and acetone. Insoluble in alcohol, ethyl acetateSoluble in acetone, acetic acid and glycerol. Insoluble in ethanol and ethyl acetate.
form 
Solid
Specific Gravity
2.83
color 
White
Odor
Slight nitric acid odor
Water Solubility 
MAY DECOMPOSE
Sensitive 
Hygroscopic
Merck 
14,1271
Stability:
Stable. Incompatible with strong acids, strong reducing agents, organic materials, finely powdered metals, moisture. Strong oxidizer.
InChI
InChI=1S/Bi.3NO3.5H2O/c;3*2-1(3)4;;;;;/h;;;;5*1H2/q+3;3*-1;;;;;
InChIKey
FBXVOTBTGXARNA-UHFFFAOYSA-N
SMILES
[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.O.O.O.O.O.[Bi+3]
CAS DataBase Reference
10035-06-0(CAS DataBase Reference)
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Safety

Hazard Codes 
O,Xi
Risk Statements 
8-36/37/38
Safety Statements 
17-26-36-37/39
RIDADR 
UN 1477 5.1/PG 2
WGK Germany 
2
RTECS 
EB2984430
F 
8
TSCA 
Yes
HazardClass 
5.1
PackingGroup 
II
HS Code 
28342990
Toxicity
LD50 orally in Rabbit: 4042 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H272May intensify fire; oxidizer

H318Causes serious eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
248592
Product name
Bismuth(III) nitrate pentahydrate
Purity
reagent grade, 98%
Packaging
100g
Price
$52
Updated
2024/03/01
Sigma-Aldrich
Product number
248592
Product name
Bismuth(III) nitrate pentahydrate
Purity
reagent grade, 98%
Packaging
500g
Price
$119
Updated
2024/03/01
Alfa Aesar
Product number
012231
Product name
Bismuth(III) nitrate pentahydrate, ACS, 98%
Packaging
250g
Price
$61.5
Updated
2024/03/01
Alfa Aesar
Product number
012231
Product name
Bismuth(III) nitrate pentahydrate, ACS, 98%
Packaging
1kg
Price
$172
Updated
2023/06/20
Strem Chemicals
Product number
93-8304
Product name
Bismuth(III) nitrate pentahydrate, 98% (ACS)
Purity
98% (ACS)
Packaging
50g
Price
$39
Updated
2024/03/01
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Bismuth nitrate pentahydrate Chemical Properties,Usage,Production

Description

Bismuth nitrate is the bismuth salt form of nitrate, usually existing in pentahydrate form. People apply bismuth salt to the skin for hemorrhoids. People use bismuth as an enema for pouchitis. This condition involves inflammation in an artificial rectum created after surgery for ulcerative colitis. Bismuth salts are also added to cosmetics, batteries, paints, and pigment plastics in manufacturing. Bismuth nitrate is used to catalyze various kinds of reactions including chemo-selective synthesis of acylals from aromatic aldehydes, one-pot synthesis of alpha-amino phosphates as well as pharmaceutically functionalized piperidine derivatives, protection of carbonyl compounds and various kinds of Michel reactions. It is also an excellent oxidant for a variety of 4-substituted Hantzsch 1, 4-dihydropyridines.It is a convenient reagent for selective oxidation of sufides to sulfoxides.

Uses

Bismuth(III) nitrate pentahydrate is a non-toxic, inexpensive, easy to handle and air insensitive reagent, commonly used in organic synthesis with a wide range of applications.

Bismuth(III) nitrate pentahydrate is a convenient and selective reagent for conversion of thiocarbonyls to their carbonyl compounds.
Bismuth(III) nitrate pentahydrate and air as a cocatalyst is claimed to be a superior reagent for the oxidative deprotection of dithioacetals.

Chemical Synthesis

Bismuth(III) nitrate pentahydrate may be used in the following processes:

  1. Conversion of thioamides and thioureas to their oxo derivatives.
  2. Transformation of aromatic aldehydes to carboxylic acids under microwave and solvent free conditions.
  3. Synthesize coumarins by Pechmann condensation under solvent free conditions.
  4. As a precursor in the synthesis of pure and lanthanum-modified bismuth ferrite (BFO) ceramics.
  5. As a nitrating agent in the synthesis of methyl nitramino-2,4,6-trinitrobenzenes under microwave irradiation.
  6. As a catalyst in the preparation of 4-amino-5-pyrimidine carbonitrile and pyrimidinone derivatives.
  7. Synthesis of glycosides by Fischer glycosylation of unprotected sugars.
  8. Synthesis of bismuth oxide (Bi2O3) nanoparticles.
  9. Oxidation of 4-substituted Hantzsch 1,4-dihydropyridines.
  10. Selective oxidation of sufides to sulfoxides.

Preparation

Bismuth nitrate pentahydrate can be obtained by dissolving metallic bismuth granules in nitric acid, or by pouring molten metallic bismuth into an acid solution while stirring.

Sources

https://en.wikipedia.org/wiki/Bismuth(III)_nitrate
Bhattacharya, Asish K., and T. Kaur.  Cheminform 38.30(2007):0745-0748.
Aggen, David H., et al. Tetrahedron 35.31(2004):3675-3679.
Brahmachari, Goutam, and S. Das. Cheminform 43.28(2012):1479-1484.
Srivastava, Neeta, S. K. Dasgupta, and B. K. Banik. Tetrahedron Letters 34.17(2003):1191-1193.
Banik, Bimal K., I. Garcia, and F. R. Morales. Cheminform 38.33(2007):no-no.
Srivastava, N, and B. K. Banik. Cheminform 68.6(2003):2109-14.
https://www.sigmaaldrich.com/catalog/product/aldrich/254150?lang=en&region=US
https://www.webmd.com/vitamins/ai/ingredientmono-1502/bismuth

Chemical Properties

White Crystal

Physical properties

Lustrous triclinic crystals; acid taste; hygroscopic; density 2.83 g/cm3; decomposes at 75°C; reacts slowly with water; soluble in acids and acetone; insoluble in alcohol.

Uses

An excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines.1 Convenient reagent for selective oxidation of sufides to sulfoxides.2

Uses

Luminous paints, preparation of bismuth saltsBismuth(III) nitrate pentahydrate is an oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. It also serves as a reagent for selective oxidation of sufides to sulfoxides. Further, it is involved in the preparation of Dragendorff reagent and used as a TLC stain. It is also used to prepare other bismuth compounds.

Uses

Bismuth Nitrate Pentahydrate acts as a precursor in the prepoaration of photocatalysts.

Preparation

Bismuth nitrate is prepared by dissolving bismuth in concentrated nitric acid, followed by evaporation and crystallization .

General Description

Bismuth(III) nitrate pentahydrate is a non-toxic, inexpensive, easy to handle and air insensitive reagent, commonly used in organic synthesis with a wide range of applications.

Bismuth nitrate pentahydrate Preparation Products And Raw materials

Raw materials

Bismuth(III) Oxide Bismuth Nitric acid

Preparation Products

BISMUTH ALUMINATE Copper-Bismuth catalyst BISMUTH POTASSIUM CITRATE Bismuth subcarbonate
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View Lastest Price from Bismuth nitrate pentahydrate manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Bismuth nitrate pentahydrate 10035-06-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-12-11
Hebei Weibang Biotechnology Co., Ltd
Product
Bismuth nitrate pentahydrate 10035-06-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-29
Hebei Chuanghai Biotechnology Co,.LTD
Product
Bismuth nitrate pentahydrate 10035-06-0
Price
US $9.60/KG
Min. Order
1KG
Purity
98%
Supply Ability
5000kg
Release date
2024-08-21

10035-06-0, Bismuth nitrate pentahydrateRelated Search:

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