BIS(TRIMETHYLSILYL)CHLOROMETHANE

Product Name: BIS(TRIMETHYLSILYL)CHLOROMETHANE
CAS No.: 5926-35-2
Chemical Name: BIS(TRIMETHYLSILYL)CHLOROMETHANE
Synonyms: BIS(TRIMETHYLSILYL)CHLOROMETHANE;Chloro-bis(trimethylsilyl)methane;BIS(TRIMETHYLSILYL)METHYL CHLORIDE;Chloro-bis-trimethylsilanyl-methane;Chlorobis(trimethylsilyl)methane 97%;(Chloromethylene)bis(trimethylsilane);chloro(trimethylsilyl)methyl]-trimethylsilane;Silane, 1,1'-(chloromethylene)bis[1,1,1-trimethyl-
CBNumber: CB6449614
Molecular Formula: C7H19ClSi2
Formula Weight: 194.85
MOL File: 5926-35-2.mol

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BIS(TRIMETHYLSILYL)CHLOROMETHANE Property

Boiling point:: 57-60 °C/15 mmHg (lit.)
Density: 0.892 g/mL at 25 °C (lit.)
refractive index: n20/D 1.449(lit.)
Flash point:: 120 °F
solubility: soluble in common organic solvents (DMF, THF, Et2O, CH2Cl2).
Specific Gravity: 0.892
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
BRN: 1736681

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Safety

Hazard Codes: Xi
Risk Statements: 10-36/37/38
Safety Statements: 26-36/37/39
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
F: 21
TSCA: No
HazardClass: 3.2
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 361747
Product name: Chlorobis(trimethylsilyl)methane
Purity: 97%
Packaging: 5g
Price: $124
Updated: 2024/03/01

Sigma-Aldrich

Product number: 361747
Product name: Chlorobis(trimethylsilyl)methane
Purity: 97%
Packaging: 25g
Price: $467
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: ORS0005253
Product name: BIS(TRIMETHYLSILYL)METHYL CHLORIDE
Purity: 95.00%
Packaging: 5G
Price: $872.33
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ORS0005253
Product name: BIS(TRIMETHYLSILYL)METHYL CHLORIDE
Purity: 95.00%
Packaging: 25G
Price: $1408.61
Updated: 2021/12/16

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BIS(TRIMETHYLSILYL)CHLOROMETHANE Chemical Properties,Usage,Production

Physical properties

bp 57–60°C(15 mmHg); flash point 48 °C; d 0.892 gmL?1 (25 °C).

Uses

Silane, 1,1-(Chloromethylene)bis[1,1,1]- trimethyl- can be used as versatile C1 building block; broad application in Peterson olefination reactions; Grignard reagent participates readily in Kumada cross-coupling reactions with aryl and vinyl halides; useful in synthesis of methylenephosphine analogs and as sterically demanding ligand for a number of main group and transition metal complexes.

Uses

Chlorobis(trimethylsilyl)methane can be used as a reagent for the preparation of:

Para-bis(trimethylsilyl)ethylstyrene (PBTES) monomer, which is used to synthesize corresponding network polymer of styrene.
Bis(trimethylsilyl)methyl magnesium chloride (Grignard reagent), which is used in the synthesis of bis(trimethylsilyl) allyl compounds by reacting with alkenyl bromide via the Kumada coupling reaction.
N-[Bis(trimethylsilyl)methyl]heterocumulenes.

Preparation

a convenient one-pot procedure has been developed by Kemp and Cowley in which trimethylsilylchloride reacts with dichloromethane in the presence of nBuLi at ?110°Cto give bis(trimethylsilyl)dichloromethane.1 This intermediate is sequentially treated with nBuLi and ethanol to yield chlorobis(trimethylsilyl)methane. A number of other syntheses have been described

BIS(TRIMETHYLSILYL)CHLOROMETHANE Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(TRIMETHYLSILYL)CHLOROMETHANE Suppliers

China 20 Germany 2 Singapore 1 Switzerland 1 United Kingdom 2 United States 7 Global 33

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5926-35-2, BIS(TRIMETHYLSILYL)CHLOROMETHANERelated Search:

Chloromethane BIS(TRIMETHYLSILYL)CHLOROMETHANE Chloromethyltrimethylsilane Bis(trimethylsilyl)methane 1,3-DISILABUTANE BIS(TRIMETHYLSILYL)DICHLOROMETHANE 1,3-DISILAPROPANE

BIS(TRIMETHYLSILYL)CHLOROMETHANE

BIS(TRIMETHYLSILYL)METHYL CHLORIDE

Chloro-bis(trimethylsilyl)methane

Chlorobis(trimethylsilyl)methane 97%

Chloro-bis-trimethylsilanyl-methane

(Chloromethylene)bis(trimethylsilane)

Silane, 1,1'-(chloromethylene)bis[1,1,1-trimethyl-

chloro(trimethylsilyl)methyl]-trimethylsilane

5926-35-2

C7H19ClSi2

CH33Si2CHCl

Organometallic Reagents

Organosilicon

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