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RHODIUM(II) HEPTAFLUOROBUTYRATE DIMER

Product Name
RHODIUM(II) HEPTAFLUOROBUTYRATE DIMER
CAS No.
73755-28-9
Chemical Name
RHODIUM(II) HEPTAFLUOROBUTYRATE DIMER
Synonyms
Nsc225291;Rhodium(II) perfluorobutyrate dimer;Rhodium(II)heptafluorobutryatedimer;RHODIUM(II) HEPTAFLUOROBUTYRATE DIMER;Dirhodium tetrakis(perfluorobutyrate);Dirhodium tetrakis(perfluorobutanoate);Tetrakis(heptafluorobutyrate)dirhodium;Tetrakis(heptafluorobutanoato)dirhodium;Dirhodium tetrakis(heptafluorobutyrate);Dirhodium heptafluorobutyrate(II) dimer
CBNumber
CB6461553
Molecular Formula
C16F28O8Rh2
Formula Weight
1057.93
MOL File
73755-28-9.mol
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RHODIUM(II) HEPTAFLUOROBUTYRATE DIMER Property

Melting point:
>300 °C (lit.)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
powder
EPA Substance Registry System
Rhodium(II) perfluorobutyrate dimer (73755-28-9)
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
424889
Product name
Rhodium(II) heptafluorobutyrate dimer
Purity
97%
Packaging
250mg
Price
$87
Updated
2024/03/01
Sigma-Aldrich
Product number
424889
Product name
Rhodium(II) heptafluorobutyrate dimer
Purity
97%
Packaging
1g
Price
$430
Updated
2024/03/01
Activate Scientific
Product number
AS148182
Product name
Rhodium(II)heptafluorobutryatedimer
Purity
98%
Packaging
100mg
Price
$185
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
OGM0000937
Product name
RHODIUM(II) HEPTAFLUOROBUTYRATE DIMER
Purity
95.00%
Packaging
250MG
Price
$635.48
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
OGM0000937
Product name
RHODIUM(II) HEPTAFLUOROBUTYRATE DIMER
Purity
95.00%
Packaging
1G
Price
$878.03
Updated
2021/12/16
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RHODIUM(II) HEPTAFLUOROBUTYRATE DIMER Chemical Properties,Usage,Production

Uses

Recently used in the catalytic preparation of macrocycles and in the efficient synthesis of chiral β-substituted (E)-crotylsilanes.

Application

Rhodium(ii) heptafluorobutyrate dimer is a catalyst that can be used for carbene reactions of diazo compounds, hydrosilylation of alkenes and alkynes, and silyl carbonylation of alkynes.

Preparation

Rhodium(ii) heptafluorobutyrate dimer is prepared from Dirhodium(II) Tetraacetate by ligand displacement in refluxing  perfluorobutyric acid containing perfluorobutyric anhydride.

reaction suitability

reagent type: catalyst
core: rhodium

storage

air stable, very hygroscopic; stored in desiccator.

RHODIUM(II) HEPTAFLUOROBUTYRATE DIMER Preparation Products And Raw materials

Raw materials

Preparation Products

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RHODIUM(II) HEPTAFLUOROBUTYRATE DIMER Suppliers

Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
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Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
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Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
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Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41462
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Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
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China
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51456
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Tianjin Kailiqi Biotechnology Co., Ltd.
Tel
15076683720
Fax
022-23754520
Email
klq@cw-bio.com
Country
China
ProdList
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Aikon International Limited
Tel
025-66113011 18112977050
Fax
02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
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Changzhou Carman Chemical Co., ltd
Tel
0519-0519-83534936 18151214939
Email
1521178147@qq.com
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China
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Zhengzhou Alfa Chemical Co.,Ltd
Tel
+8618530059196
Email
sale04@alfachem.cn
Country
China
ProdList
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73755-28-9, RHODIUM(II) HEPTAFLUOROBUTYRATE DIMERRelated Search:


  • RHODIUM(II) HEPTAFLUOROBUTYRATE DIMER
  • Rhodium(II)heptafluorobutryatedimer
  • Nsc225291
  • Dirhodium tetrakis(heptafluorobutyrate)
  • Dirhodium tetrakis(perfluorobutanoate)
  • Dirhodium tetrakis(perfluorobutyrate)
  • Rhodium(II) perfluorobutyrate dimer
  • Tetrakis(heptafluorobutanoato)dirhodium
  • Tetrakis(heptafluorobutyrate)dirhodium
  • RhodiuM(II) heptafluorobutyrate diMer 97%
  • Dirhodium(II) Tetrakis(perfluorobutyrate)
  • Rhodium, tetrakis[m-(2,2,3,3,4,4,4-heptafluorobutanoato-kO:kO')]di-, (Rh-Rh)
  • Bis[(2,2,3,3,4,4,4-heptafluorobutanoyl)oxy]rhodium Dimer
  • Dirhodium heptafluorobutyrate(II) dimer
  • 73755-28-9
  • C16F28O8Rh2
  • CF3CF2CF2CO22Rh2
  • Catalysis and Inorganic Chemistry
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Rhodium Salts
  • RhodiumMetal and Ceramic Science
  • Salts