ChemicalBook > CAS DataBase List > 2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILE

2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILE

Product Name
2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILE
CAS No.
147992-80-1
Chemical Name
2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILE
Synonyms
2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILE;1-(Methoxymethyl)-5-(trifluoromethoxy)benzene;3-Pyridinecarbonitrile, 2-chloro-4-(dimethylamino)-
CBNumber
CB6464044
Molecular Formula
C8H8ClN3
Formula Weight
181.62
MOL File
147992-80-1.mol
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2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILE Property

Melting point:
84-86°
Boiling point:
343.4±42.0 °C(Predicted)
Density 
1.26±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
pka
1.71±0.10(Predicted)
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Safety

HazardClass 
IRRITANT
HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

AK Scientific
Product number
4550AD
Product name
2-Chloro-4-(dimethylamino)nicotinonitrile
Packaging
250mg
Price
$443
Updated
2021/12/16
Matrix Scientific
Product number
045877
Product name
2-Chloro-4-(dimethylamino)nicotinonitrile
Purity
>95%
Packaging
500mg
Price
$486
Updated
2021/12/16
Matrix Scientific
Product number
045877
Product name
2-Chloro-4-(dimethylamino)nicotinonitrile
Purity
>95%
Packaging
1g
Price
$603
Updated
2021/12/16
SynQuest Laboratories
Product number
3H37-5-1G
Product name
2-Chloro-4-(dimethylamino)pyridine-3-carbonitrile
Purity
95%
Packaging
1g
Price
$640
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0037689
Product name
2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILE
Purity
95.00%
Packaging
500MG
Price
$864.17
Updated
2021/12/16
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2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILE Chemical Properties,Usage,Production

Synthesis

98694-71-4

147992-80-1

A slurry was prepared from 2-(1,3-bisdimethylamino-allyl)malononitrile (120.0 g, 632 mmol) in methanol (1500 mL). HCl gas was slowly passed at 0 °C and the reaction mixture became homogeneous after about 1 hour. Stirring was maintained at 0 °C and continued for 9 h under continuous passage of HCl gas. Subsequently, N2 was bubbled through the reaction mixture for 2 hours to remove residual HCl and then evaporated to remove all solvent. The residual solid was redissolved in CH2Cl2 and washed sequentially with water, aqueous K2C2O3 and water. The organic layer was separated and dried with Na2SO4. After filtration to remove the desiccant, the solvent was evaporated under reduced pressure to give the pure product 2-chloro-4-(dimethylamino)nicotinonitrile (113.0 g, 98% yield). The product was characterized by 1H NMR (300 MHz, CDCl3): δ 7.96 ppm (d, J=6.4 Hz, 1H); 6.59 (d, J=6.4 Hz, 1H); 3.30 (s, 6H). Mass spectrum (ESI, M+1): 181.9.

References

[1] Patent: WO2006/81072, 2006, A1. Location in patent: Page/Page column 30-31

2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILE Suppliers

J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Wuhan Chemwish Technology Co., Ltd
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86-027-67849912
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86-027-87531808
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sales@chemwish.com
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China
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35896
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Shenzhen Polymeri Biochemical Technology Co., Ltd.
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+86-400-002-6226 +86-13028896684;
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China
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Shanghai Haohong Pharmaceutical Co., Ltd.
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Energy Chemical
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Bide Pharmatech Ltd.
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Shanghai Tengjun Biotechnology Co. LTD
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147992-80-1, 2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILERelated Search:


  • 2-CHLORO-4-(DIMETHYLAMINO)NICOTINONITRILE
  • 3-Pyridinecarbonitrile, 2-chloro-4-(dimethylamino)-
  • 1-(Methoxymethyl)-5-(trifluoromethoxy)benzene
  • 147992-80-1