ChemicalBook > CAS DataBase List > 2-vinylbenzaldehyde

2-vinylbenzaldehyde

Product Name
2-vinylbenzaldehyde
CAS No.
28272-96-0
Chemical Name
2-vinylbenzaldehyde
Synonyms
2-vinylbenzaldehyde;2-ETHENYLBENZALDEHYDE;Lacidipine Impurity 2;Benzaldehyde, 2-ethenyl-;LACIDIPINE VINYL ALDEHYDE
CBNumber
CB64678922
Molecular Formula
C9H8O
Formula Weight
132.16
MOL File
28272-96-0.mol
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2-vinylbenzaldehyde Property

Boiling point:
77-82 °C(Press: 1.7 Torr)
Density 
1.040±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Chloroform (Sparingly), Ethyl Acetate (Slightly)
form 
Oil
color 
Colourless
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
E678170
Product name
2-Ethenylbenzaldehyde
Packaging
50mg
Price
$50
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM1031490
Product name
2-ETHENYLBENZALDEHYDE
Purity
95.00%
Packaging
5MG
Price
$500.67
Updated
2021/12/16
Matrix Scientific
Product number
173038
Product name
2-Vinylbenzaldehyde
Packaging
1g
Price
$720
Updated
2021/12/16
Matrix Scientific
Product number
173038
Product name
2-Vinylbenzaldehyde
Packaging
5g
Price
$1530
Updated
2021/12/16
Matrix Scientific
Product number
173038
Product name
2-Vinylbenzaldehyde
Packaging
10g
Price
$2430
Updated
2021/12/16
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2-vinylbenzaldehyde Chemical Properties,Usage,Production

Uses

2-Ethenylbenzaldehyde is a useful reactant in organic synthesis.

Synthesis

2039-88-5

68-12-2

28272-96-0

Step 1: 1-bromo-2-vinylbenzene (3 g, 16.4 mmol) was dissolved in anhydrous THF (20 mL) under nitrogen protection and cooled to -78 °C. N-butyllithium (2.5 M hexane solution, 7.2 mL, 18.0 mmol) was slowly added dropwise, keeping the temperature below -70 °C. After the dropwise addition was completed, the reaction mixture was continued to be stirred at -70 °C for 1 hour. Subsequently, N,N-dimethylformamide (1.8 g, 24.6 mmol) was added to the reaction system and slowly warmed up to room temperature and continued stirring for 30 minutes. After the reaction was completed, the mixture was poured into water (20 mL) and the aqueous layer was extracted with ethyl acetate (20 mL x 2). The organic layers were combined, dried with anhydrous sodium sulfate and concentrated under reduced pressure to give 2-vinylbenzaldehyde (2.0 g, 91% yield).

References

[1] Journal of Organic Chemistry, 2011, vol. 76, # 7, p. 1979 - 1991
[2] Patent: US2017/37038, 2017, A1. Location in patent: Paragraph 0096; 0147; 0148
[3] Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 2222 - 2229
[4] Angewandte Chemie - International Edition, 2017, vol. 56, # 9, p. 2473 - 2477
[5] Angew. Chem., 2017, vol. 129, p. 2513 - 2517,5

2-vinylbenzaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-vinylbenzaldehyde manufacturers

Nanjing jinheyou Trading Co., Ltd.
Product
2-ETHENYLBENZALDEHYDE 28272-96-0
Price
US $0.00/g
Min. Order
1g
Purity
95%min
Supply Ability
20kg/month
Release date
2019-11-19

28272-96-0, 2-vinylbenzaldehydeRelated Search:


  • 2-ETHENYLBENZALDEHYDE
  • Benzaldehyde, 2-ethenyl-
  • 2-vinylbenzaldehyde
  • LACIDIPINE VINYL ALDEHYDE
  • Lacidipine Impurity 2
  • 28272-96-0