ChemicalBook > CAS DataBase List > (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
Description- Product Name
- (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
- CAS No.
- 185449-86-9
- Chemical Name
- (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
- Synonyms
- 3,4-a'']dinaphthalen-4-yl)dimethylamine;3,4-a']dinaphthalen-4-yl)dimethylamine,98%;3,4-a']dinaphthalen-4-yl)dimethylamine,min.98%;3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%;(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a;N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bS)-N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bS)-N,N,2,6-tetraMethyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine;Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N,2,6-tetramethyl-, (11bS)-;(11bS)-N,N,2,6-Tetramethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine,99%e.e.
- CBNumber
- CB6487814
- Molecular Formula
- C24H22NO2P
- Formula Weight
- 387.41
- MOL File
- 185449-86-9.mol
More
Less
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Property
- Melting point:
- 228-229°C
- Boiling point:
- 571.0±53.0 °C(Predicted)
- alpha
- +636° (c 0.30, CH2Cl2)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 1.32±0.20(Predicted)
- form
- Powder
- color
- off-white
- Sensitive
- moisture sensitive
More
Less
Safety
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38-22
- Safety Statements
- 26-36/37/39
More
Less
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
More
Less
N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 15-1255
- Product name
- (S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%
- Packaging
- 100mg
- Price
- $195
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1255
- Product name
- (S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%
- Packaging
- 500mg
- Price
- $779
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- ING0001353
- Product name
- (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
- Purity
- 95.00%
- Packaging
- 500MG
- Price
- $1127.86
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 090119
- Product name
- N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
- Purity
- 95+%
- Packaging
- 1g
- Price
- $1647
- Updated
- 2021/12/16
AK Scientific
- Product number
- 9701AA
- Product name
- N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
- Packaging
- 1g
- Price
- $2273
- Updated
- 2021/12/16
More
Less
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Chemical Properties,Usage,Production
Description
1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids.
2. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position.
3. Ligand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
4. Ligand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes.
5. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition.
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
185449-86-9, (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINERelated Search:
(R)-MONOPHOS
(11bS)-N,N-dimethyl-2,6-diphenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-
4-amine
3,4-a']dinaphthalen-4-yl)dipropylaMine
(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(11bS)-8,9,10,11,12,13,14,15-octahydro-N,N-bis[(1S)-1-phenylethyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
N,N-diisopropyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
(R)-MONOPHOS