ChemicalBook > CAS DataBase List > 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE

2-METHYL-1-PROPENYLMAGNESIUM BROMIDE

Product Name
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE
CAS No.
38614-36-7
Chemical Name
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE
Synonyms
Isobutenylmagnesium bromide;2,2-Dimethylvinylmagnesium bromide;1-Bromomagnesio-2-methyl-1-propene;2-Methyl-1-acryl magnesium bromide;(2-Methylpropenyl)magnesium bromide;2-METHYL-1-PROPENYLMAGNESIUM BROMIDE;(2-Methylprop-1-en-1-yl)MagnesiuM broMide;(beta,beta-Dimethylvinyl)magnesium bromide;2-METHYL-1-PROPYLMAGNESIUM BROMIDE0.5M THF;2-Methyl-1-propenylmagnesium bromide solution
CBNumber
CB6492180
Molecular Formula
C4H7BrMg
Formula Weight
159.31
MOL File
38614-36-7.mol
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2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Property

Density 
0.952 g/mL at 25 °C
Flash point:
5 °F
form 
Solution
color 
Yellow to dark orange
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Safety

Hazard Codes 
F,C,Xn
Risk Statements 
11-14/15-19-20/21/22-34-37-40-36/37/38-15
Safety Statements 
16-26-27-36/37/39-45-43-36/37
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
419613
Product name
2-Methyl-1-propenylmagnesium bromide solution
Purity
0.5 M in THF
Packaging
100ml
Price
$185
Updated
2025/07/31
Sigma-Aldrich
Product number
419613
Product name
2-Methyl-1-propenylmagnesium bromide solution
Purity
0.5 M in THF
Packaging
800ml
Price
$741.95
Updated
2025/07/31
American Custom Chemicals Corporation
Product number
CHM0309290
Product name
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE
Purity
95.00%
Packaging
5MG
Price
$500.65
Updated
2021/12/16
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2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Chemical Properties,Usage,Production

Chemical Properties

Yellow to dark orange liquid

Uses

2-Methyl-1-propenylmagnesium bromide(0.5?M in THF) is a reagent used in many chemical reactions such as in the preparation of biaryls, alkylarenes, alkenylarenes, alkynylalkenones via nucleophilic addition.Used in the study of palladium-catalyzed coupling with aryl tosylates.

Uses

Used in a synthesis of (2S,3S)-3′-fluoroisoleucine.

Uses

2-Methyl-1-propenylmagnesium bromide can be used in a study of a palladium-catalyzed coupling with aryl tosylates.

reaction suitability

reaction type: Grignard Reaction

2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Suppliers

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View Lastest Price from 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE manufacturers

Career Henan Chemical Co
Product
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE 38614-36-7
Price
US $5.50/KG
Min. Order
1KG
Purity
98%min
Supply Ability
1kg,10kg,100kg
Release date
2020-01-09
Career Henan Chemical Co
Product
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE 8614-36-7
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
500kg
Release date
2019-09-02

38614-36-7, 2-METHYL-1-PROPENYLMAGNESIUM BROMIDERelated Search:

Methylmagnesium Bromide Zinc chloride 4-CHLORO-3-FLUOROPHENYLMAGNESIUM BROMIDE 4-(Trifluoromethoxy)phenylmagnesium bromide 2-BROMOBENZYLMAGNESIUM BROMIDE 5-FLUORO-2-METHOXYPHENYLMAGNESIUM BROMIDE 2,3-DIMETHYLPHENYLMAGNESIUM BROMIDE 3-CHLORO-4-FLUOROPHENYLMAGNESIUM BROMID& 3-BROMOBENZYLMAGNESIUM BROMIDE PHENYLETHYNYLMAGNESIUM BROMIDE 3 4 5-TRIFLUOROPHENYLMAGNESIUM BROMIDE 4-chlorophenylmagnesium bromide 3-CHLOROPHENYLMAGNESIUM BROMIDE 3-(Trifluoromethoxy)phenylmagnesium bromide 0.5 in THF 3,5-DIFLUOROPHENYLMAGNESIUM BROMIDE 1-METHYL-1-PROPENYLMAGNESIUM BROMIDE,1-Methyl-1-propenylmagnesium bromide solution,1-METHYL-1-PROPENYLMAGNESIUM BROMIDE, 0. 5M SOLUTION IN TETRAHYDROFURAN 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE 1-PROPENYLMAGNESIUM BROMIDE

  • 2-METHYL-1-PROPYLMAGNESIUM BROMIDE0.5M THF
  • 2-Methyl-1-propenylmagnesium bromide, 0.5M solution in THF, AcroSeal
  • (2-Methylprop-1-en-1-yl)MagnesiuM broMide
  • 2-Methyl-1-propenylmagnesium bromide 0.5M solution in THF
  • 2-Methyl-1-propenylMagnesiuM broMide, 0.5M solution in THF, J&KSeal
  • (beta,beta-Dimethylvinyl)magnesium bromide
  • 1-Bromomagnesio-2-methyl-1-propene
  • 2,2-Dimethylvinylmagnesium bromide
  • Isobutenylmagnesium bromide
  • 2-Methyl-1-propenylmagnesium bromide solution 0.5 in THF
  • (2-Methylpropenyl)magnesium bromide
  • 2-Methyl-1-propenylMagnesiuM broMide solution 0.5 M in THF
  • 2-Methyl-1-propenylMagnesiuM broMide, 0.5 M solution in THF, SpcSeal
  • 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE
  • 2-Methyl-1-propenylmagnesium bromide solution
  • 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE, 0. 5M SOLUTION IN TETRAHYDROFURAN
  • 2-Methyl-1-propenylmagnesium bromide, 0.5 in THF
  • 2-Methyl-1-propenylmagnesium bromide(0.5?M in THF)
  • 2-Methyl-1-acryl magnesium bromide
  • (2-Methylprop-1-enyl)magnesium bromide, 0.5 M in THF - [M95026]
  • 38614-36-7
  • 8614-36-7
  • CH32CCHMgBr
  • C4H7BrMg
  • Organometallic Reagents
  • Grignard Reagents
  • Alkenyl
  • Chemical Synthesis
  • Grignard Reagents
  • Organometallic Reagents
  • Alkenyl
  • Grignard Reagents
  • Organometallic Reagents
  • Grignard Reagent