Methyl 4-iodosalicylate

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Methyl 4-iodosalicylate

Structure

Product Name: Methyl 4-iodosalicylate
CAS No.: 18179-39-0
Chemical Name: Methyl 4-iodosalicylate
Synonyms: Methyl4-Iodosilicylate;METHYL 4-IODOSALICYLATE;Methyl4-Iodosalicylate>Methyl 4-iodosalicylate 97%;4-Iodosalicylic Acid Methyl Ester;2-Hydroxy-4-iodobenzoic Acid Methyl Ester;Benzoic acid, 2-hydroxy-4-iodo-, methyl ester;Methyl 4-iodosalicylate, 5-Iodo-2-(methoxycarbonyl)phenol;Methyl 2-Hydroxy-4-iodobenzoate 4-Iodosalicylic Acid Methyl Ester 2-Hydroxy-4-iodobenzoic Acid Methyl Ester
CBNumber: CB6498889
Molecular Formula: C8H7IO3
Formula Weight: 278.04
MOL File: 18179-39-0.mol

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Methyl 4-iodosalicylate Property

Melting point:: 69-73 °C
Boiling point:: 309.7±32.0 °C(Predicted)
Density: 1.880±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
form: powder to crystal
pka: 8.91±0.10(Predicted)
color: White to Gray to Brown
Sensitive: Light Sensitive
InChIKey: WUFUURSWOJROKY-UHFFFAOYSA-N

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Safety

Hazard Codes: T
Risk Statements: 25
Safety Statements: 45
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
F: 8
Hazard Note: Toxic
PackingGroup: III
HS Code: 2918290090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Danger
Hazard statements: H301Toxic if swalloed

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 652636
Product name: Methyl 4-iodosalicylate
Purity: 97%
Packaging: 25g
Price: $103.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 652636
Product name: Methyl 4-iodosalicylate
Purity: 97%
Packaging: 5g
Price: $67.8
Updated: 2023/06/20

TCI Chemical

Product number: M1908
Product name: Methyl 4-Iodosalicylate
Purity: >98.0%(GC)
Packaging: 5g
Price: $105
Updated: 2024/03/01

TCI Chemical

Product number: M1908
Product name: Methyl 4-Iodosalicylate
Purity: >98.0%(GC)
Packaging: 25g
Price: $320
Updated: 2024/03/01

Alfa Aesar

Product number: B25438
Product name: Methyl 4-iodosalicylate, 98%
Packaging: 5g
Price: $42.65
Updated: 2024/03/01

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Methyl 4-iodosalicylate Chemical Properties,Usage,Production

Structure

2-hydroxy-4-iodobenzoic acid methyl ester (methyl 4-iodosalicylate, C8H7IO3) allows for an effective way of incorporating the methyl salicylates within larger organic molecules, using such methodologies as McClure protocols, which take advantage of the iodine atom at the 4-position of the aromatic ring for the formation of carbon-carbon bonds. The iodine atom is also capable of forming supramolecular synthons, which may be useful for crystal engineering. At 90 K, the methyl 4-iodosalicylat displays monoclinic (P21/c) symmetry with one molecule in the asymmetric unit. Intermolecular hydrogen bonding interactions occur between the hydroxy groups of one molecule and the carbonyl oxygen atom of the methyl ester of an adjacent molecule to form a centrosymmetric dimeric pair with H⋯O = 2.53 (4) Å. An O3—H3⋯O2 intramolecular hydrogen bond also exists with an H⋯O distance of 2.05 (4) Å. The C5⋯C8 [3.326 (3) Å] and O3⋯H1C (2.51 Å) interactions provide only short contacts between the stacks of offset (102) parallel sheets, which make up the crystal. These sheets, in turn, contain the inversion-generated hydrogen-bonded dimers. The non-hydrogen atoms of the molecule are essentially coplanar with no displacement from the mean molecular plane greater than 0.132 Å.

Methyl 4-iodosalicylate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl 4-iodosalicylate manufacturers

Career Henan Chemical Co

Product: METHYL 4-IODOSALICYLATE 18179-39-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-02

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