ChemicalBook > CAS DataBase List > 1-(4-BROMOPHENYL)IMIDAZOLE

1-(4-BROMOPHENYL)IMIDAZOLE

Product Name
1-(4-BROMOPHENYL)IMIDAZOLE
CAS No.
10040-96-7
Chemical Name
1-(4-BROMOPHENYL)IMIDAZOLE
Synonyms
1-(4-BROMOPHENYL)IMIDAZOLE;1-(4-Bromophenyl)imidazole >1-(4-Bromophenyl)-1H-imidazole;1H-Imidazole, 1-(4-bromophenyl)-;1-(4-Bromophenyl)-1H-imidazole 98%;1-Bromo-4-(1H-imidazol-1-yl)benzene
CBNumber
CB6701648
Molecular Formula
C9H7BrN2
Formula Weight
223.07
MOL File
10040-96-7.mol
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1-(4-BROMOPHENYL)IMIDAZOLE Property

Melting point:
118-120°C
Boiling point:
323.4±25.0 °C(Predicted)
Density 
1.50±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
powder to crystal
pka
5.24±0.10(Predicted)
color 
White to Light yellow
CAS DataBase Reference
10040-96-7(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-41-37/38
Safety Statements 
26-36/37/39-39
HazardClass 
IRRITANT
HS Code 
2933299090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B4101
Product name
1-(4-Bromophenyl)imidazole
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$79
Updated
2025/07/31
TCI Chemical
Product number
B4101
Product name
1-(4-Bromophenyl)imidazole
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$387
Updated
2025/07/31
TRC
Product number
B700238
Product name
1-(4-Bromophenyl)imidazole
Packaging
10mg
Price
$45
Updated
2021/12/16
Oakwood
Product number
018307
Product name
1-(4-Bromophenyl)imidazole
Purity
98%
Packaging
250mg
Price
$30
Updated
2021/12/16
Matrix Scientific
Product number
004932
Product name
1-(4-Bromophenyl)imidazole
Purity
98%
Packaging
1g
Price
$33
Updated
2021/12/16
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1-(4-BROMOPHENYL)IMIDAZOLE Chemical Properties,Usage,Production

Synthesis

288-32-4

5467-74-3

10040-96-7

A magnetic stirrer, imidazole (59 mg, 0.5 mmol), 4-bromophenylboronic acid (1.0 mmol), cuprous sulfide (4 mg, 0.025 mmol), and methanol (2 mL) were added to a 10 mL round bottom flask followed by N,N,N',N'-tetramethylethylenediamine (TMEDA, 0.075 mL, 0.5 mmol). The flask was sealed with a rubber septum and an 18-gauge needle was inserted to allow air to enter the reaction system while preventing contamination of the mixture. The reaction mixture was stirred at 400 to 600 rpm for an appropriate time. After completion of the reaction, the reaction mixture was extracted with ethyl acetate (2 x 15 mL). The organic layers were combined and washed with saturated aqueous ethylenediaminetetraacetic acid disodium salt solution (15 mL), followed by drying with anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure and the residue was purified by silica gel column chromatography (eluent: hexane-ethyl acetate) to afford the target product 1-(4-bromophenyl)imidazole. The structure of the product was characterized by 1H NMR, 13C NMR, high resolution mass spectrometry (HRMS) and melting point (if solid).

References

[1] Synthesis, 2008, # 5, p. 795 - 799
[2] Tetrahedron, 2018, vol. 74, # 5, p. 606 - 617
[3] Green Chemistry, 2018, vol. 20, # 21, p. 4891 - 4900
[4] Catalysis Communications, 2018, vol. 109, p. 38 - 42
[5] Tetrahedron, 2012, vol. 68, # 38, p. 7794 - 7798

1-(4-BROMOPHENYL)IMIDAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1-(4-BROMOPHENYL)IMIDAZOLE manufacturers

Career Henan Chemical Co
Product
1-(4-BROMOPHENYL)IMIDAZOLE 10040-96-7
Price
US $1.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
200KG
Release date
2018-12-23