CYCLOHEXYLZINC BROMIDE
- Product Name
- CYCLOHEXYLZINC BROMIDE
- CAS No.
- 7565-57-3
- Chemical Name
- CYCLOHEXYLZINC BROMIDE
- Synonyms
- CYCLOHEXYLZINC BROMIDE;bromozinc(1+),cyclohexane;cyclohexylzinc(II) broMide;cyclohexylzinc bromide solution;Cyclohexylzinc bromide, 0.5 M in THF;Cyclohexylzinc bromide, 0.50 M in THF;Cyclohexylzinc bromide solution 0.5 in THF;Cyclohexylzinc broMide solution 0.5 M in THF;Cyclohexylzinc broMide, 0.5 M solution in THF, SpcSeal;CYCLOHEXYLZINC BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
- CBNumber
- CB6705378
- Molecular Formula
- C6H11BrZn
- Formula Weight
- 228.45
- MOL File
- 7565-57-3.mol
CYCLOHEXYLZINC BROMIDE Property
- Melting point:
- 114.0-116.0 °C
- Density
- 0.963 g/mL at 25 °C
- Flash point:
- 3 °F
- storage temp.
- 2-8°C
- Water Solubility
- Reacts with water.
- Sensitive
- Air Sensitive
- Exposure limits
- ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
Safety
- Hazard Codes
- F,Xn,C
- Risk Statements
- 14-19-22-36/37/38-40-37-34-11
- Safety Statements
- 16-23-26-36-45-36/37/39
- RIDADR
- UN 2056 3/PG 2
- WGK Germany
- 1
- HazardClass
- 4.3
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H250Catches fire spontaneously if exposed to air
H261In contact with water releases flammable gas
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H333May be harmful if inhaled
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231Handle under inert gas.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
P405Store locked up.
P422Store contents under …
N-Bromosuccinimide Price
- Product number
- 498033
- Product name
- Cyclohexylzinc bromide solution
- Purity
- 0.5 M in THF
- Packaging
- 50ml
- Price
- $287
- Updated
- 2024/03/01
- Product number
- H58852
- Product name
- Cyclohexylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
- Packaging
- 50ml
- Price
- $217
- Updated
- 2024/03/01
- Product number
- C991955
- Product name
- Cyclohexylzinc bromide solution
- Packaging
- 25ml
- Price
- $385
- Updated
- 2021/12/16
- Product number
- 2030
- Product name
- Cyclohexylzincbromide
- Packaging
- 50mL
- Price
- $285
- Updated
- 2021/12/16
- Product number
- 121891
- Product name
- Cyclohexylzincbromide
- Purity
- 0.50MinTHF97%
- Packaging
- 50ml
- Price
- $306
- Updated
- 2021/12/16
CYCLOHEXYLZINC BROMIDE Chemical Properties,Usage,Production
Uses
It is used as primary and secondary intermediate.
Uses
Cyclohexylzinc bromide is an organozinc reagent, generally used in Negishi coupling. Examples include the cross-coupling of alkylzinc halides with aryl/heteroaryl halides using Pd-PEPPSI-IPent and nickel-catalyzed synthesis of 4-substituted coumarins.
It can react with the SO2 surrogate, 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) to afford zinc sulfinate salts which can be alkylated to synthesize various useful sulfones.
CYCLOHEXYLZINC BROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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