ChemicalBook > CAS DataBase List > 1-OCTENE

1-OCTENE

Product Name
1-OCTENE
CAS No.
111-66-0
Chemical Name
1-OCTENE
Synonyms
OCT-1-ENE;Octen;OCTEN-1;Octylene;Neodene 8;I-Octen;1-C8H16;1-OCTENE;1-0ctene;OCTENE-1
CBNumber
CB6708177
Molecular Formula
C8H16
Formula Weight
112.21
MOL File
111-66-0.mol
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1-OCTENE Property

Melting point:
-101 °C (lit.)
Boiling point:
122-123 °C (lit.)
Density 
0.715 g/mL at 25 °C (lit.)
vapor density 
3.9 (vs air)
vapor pressure 
36 mm Hg ( 38 °C)
refractive index 
n20/D 1.408(lit.)
FEMA 
4293 | 1-OCTENE
Flash point:
70 °F
storage temp. 
Store below +30°C.
solubility 
Soluble in acetone, benzene, and chloroform (Weast, 1986). Miscible with alcohol, ether (Windholz et al., 1983), and many aliphatic hydrocarbons.
pka
>14 (Schwarzenbach et al., 1993)
form 
Liquid
color 
Clear
Specific Gravity
0.714
Odor
gasoline
Odor Threshold
0.001ppm
explosive limit
0.7-6.8%(V)
Water Solubility 
Miscible with water, ether, alcohol and acetone.
Merck 
14,1764
JECFA Number
2191
BRN 
1734497
Henry's Law Constant
0.952 at 25 °C (Hine and Mookerjee, 1975)
Dielectric constant
2.1（20℃）
Stability:
Stable. Highly flammable. Incompatible with strong oxidizing agents, acids.
LogP
4.47 at 20℃
CAS DataBase Reference
111-66-0(CAS DataBase Reference)
EPA Substance Registry System
1-Octene (111-66-0)
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Safety

Hazard Codes 
F,Xn,N
Risk Statements 
11-51/53-65-10-66-50/53-38
Safety Statements 
16-60-62-61
RIDADR 
UN 3295 3/PG 2
WGK Germany 
1
RTECS 
RH2207000
Autoignition Temperature
446 °F
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29012990
Hazardous Substances Data
111-66-0(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331Do NOT induce vomiting.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.20928
Product name
1-Octene
Purity
for synthesis
Packaging
5ml
Price
$37.3
Updated
2024/03/01
Sigma-Aldrich
Product number
8.20928
Product name
1-Octene
Purity
for synthesis
Packaging
250ML
Price
$45.6
Updated
2024/03/01
Sigma-Aldrich
Product number
8.20928
Product name
1-Octene
Purity
for synthesis
Packaging
1L
Price
$52.2
Updated
2024/03/01
Sigma-Aldrich
Product number
74900
Product name
1-Octene
Purity
analytical standard
Packaging
5ml
Price
$70.2
Updated
2024/03/01
Sigma-Aldrich
Product number
74900
Product name
1-Octene
Purity
analytical standard
Packaging
50ml
Price
$406
Updated
2024/03/01
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1-OCTENE Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Chemical Properties

Colorless, clear liquid; gasoline aroma.

Physical properties

Clear, colorless, flammable liquid with a mild but unpleasant hydrocarbon odor. Based on a triangle bag odor method, an odor threshold concentration of 1.0 ppbv was reported by Nagata and Takeuchi (1990).

Uses

Plasticizer; surfactants. Used as a comonomer in the production of high density polyethylene and linear low density polyethylene. Starting material for synthesis of a variety of compounds including nananoic acid.

Uses

1-Octene acts as a comonomer used in the preparation of polyethylene, especially high-density polyethylene (HDPE) and linear low-density polyethylene(LLDPE) resins. It is also used in organic synthesis, surfactants and plasticizers. Further, it is used in process regulators and viscosity adjustors. In addition to this, it is used in the preparation of linear aldehyde through the oxo synthesis (hydroformylation) to get the nonanal.

Uses

1-Octene is a linear α-olefin mainly used as a comonomer in the synthesis of linear low-density polyethylene (LLDPE). Extensive work has been reported on the hydroformylation of 1-octene using various catalysts. It is also an important source to synthesize important petrochemical building blocks via epoxidation reaction.

Definition

ChEBI: An octene with an unsaturation C-1.

Aroma threshold values

High strength odor; recommend smelling in a 1.00% solution or less.

Synthesis Reference(s)

Journal of the American Chemical Society, 93, p. 1487, 1971 DOI: 10.1021/ja00735a030
Tetrahedron Letters, 25, p. 1283, 1984 DOI: 10.1016/S0040-4039(01)80135-0

General Description

A colorless liquid. Flash point 70°F. Insoluble in water and less dense (at about 6 lb / gal) than water. Hence floats on water. Vapors are heavier than air and may settle in depressions. Reported to biodegrade very slowly. Used in organic synthesis, surfactants, and plasticizers.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

1-OCTENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.

Health Hazard

Generally low toxicity. Mildly anesthetic at high vapor concentrations. May irritate eyes.

Source

Identified as one of 140 volatile constituents in used soybean oils collected from a processing plant that fried various beef, chicken, and veal products (Takeoka et al., 1996).

Environmental Fate

Biological. Biooxidation of 1-octene may occur yielding 7-octen-1-ol, which may oxidize to 7- octenoic acid (Dugan, 1972).
Photolytic. Atkinson and Carter (1984) reported a rate constant of 8.1 x 10-18 cm3/molecule?sec for the reaction of 1-octene and OH radicals in the atmosphere.
Chemical/Physical. The reaction of ozone and OH radicals with 1-octene was studied in a flexible outdoor Teflon chamber (Paulson and Seinfeld, 1992). 1-Octene reacted with ozone producing heptanal, a thermally stabilized C7 biradical, and hexane at yields of 80, 10, and 1%, respectively. With OH radicals, only 15% of 1-octene was converted to heptanal. In both reactions, the remaining compounds were tentatively identified as alkyl nitrates (Paulson and Seinfeld, 1977). Grosjean et al. (1996) investigated the atmospheric chemistry of 1-octene with ozone and an ozone-nitrogen oxide mixture under ambient conditions. The reaction of 1-octene and ozone in the dark yielded formaldehyde, hexanal, heptanal, cyclohexanone, and a compound tentatively identified as 2-oxoheptanal. The sunlight irradiation of 1-octene with ozone-nitrogen oxide yielded the following carbonyls: formaldehyde, acetaldehyde, propanal, 2-butanone, butanal, pentanal, glyoxal, hexanal, heptanal, and pentanal.
Chemical/Physical. Complete combustion in air yields carbon dioxide and water.

Purification Methods

Distil 1-octene under nitrogen from sodium which removes water and peroxides. Peroxides can also be removed by percolation through dried, acid washed, alumina. Store it under N2, or Ar in the dark. [Strukul & Michelin J Am Chem Soc 107 7563 1985, Beilstein 1 H 221, 1 II 199, 1 IV 874.]

1-OCTENE Preparation Products And Raw materials

Raw materials

Grignard reagent Sodium 1-Bromopentane Diethyl ether Allyl bromide Magnesium Iodomethane

Preparation Products

CIS-4-DECENAL Octanoic acid Starch Sodiilm octenylsuccinate 1-Nonanol JasMonyl Dicapryl Phthalate Citral 2,4,4-TRIMETHYL-1-PENTENE 1,2-Epoxyoctane Nonanoic acid
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View Lastest Price from 1-OCTENE manufacturers

Henan Fengda Chemical Co., Ltd
Product
1-OCTENE 111-66-0
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Hebei Duling International Trade Co. LTD
Product
1-Octene 111-66-0
Price
US $20.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 tons
Release date
2022-09-15
Career Henan Chemical Co
Product
1-OCTENE 111-66-0
Price
US $7.40/KG
Min. Order
1000KG
Purity
99%
Supply Ability
10T
Release date
2018-08-04

111-66-0, 1-OCTENERelated Search:

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