Tetramethoxymethane
- Product Name
- Tetramethoxymethane
- CAS No.
- 1850-14-2
- Chemical Name
- Tetramethoxymethane
- Synonyms
- TETRAMETHYL ORTHOCARBONATE;NSC 359558;Dimethoxymethylal;TETRAMETHOXYMETHANE;Methane, tetramethoxy-;Tetramethyl orthocarbonate 98%;Orthocarbonic acid, tetramethyl ester
- CBNumber
- CB6746771
- Molecular Formula
- C5H12O4
- Formula Weight
- 136.15
- MOL File
- 1850-14-2.mol
Tetramethoxymethane Property
- Melting point:
- -5 °C (lit.)
- Boiling point:
- 114 °C (lit.)
- Density
- 1.023 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.385(lit.)
- Flash point:
- 44 °F
- storage temp.
- Refrigerator
- solubility
- Chloroform, Ethyl Acetate, Methanol
- form
- Liquid
- color
- Colorless
- Sensitive
- Moisture Sensitive
- BRN
- 1737682
- CAS DataBase Reference
- 1850-14-2(CAS DataBase Reference)
- NIST Chemistry Reference
- Tetramethoxymethane(1850-14-2)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 10-36/37/38
- Safety Statements
- 26-37
- RIDADR
- UN 3272 3/PG 2
- WGK Germany
- 3
- F
- 21
- HS Code
- 2909.19.6000
- HazardClass
- 3.1
- PackingGroup
- II
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 132624
- Product name
- Tetramethyl orthocarbonate
- Purity
- 98%
- Packaging
- 5g
- Price
- $69.2
- Updated
- 2024/03/01
- Product number
- 132624
- Product name
- Tetramethyl orthocarbonate
- Purity
- 98%
- Packaging
- 25g
- Price
- $613
- Updated
- 2024/03/01
- Product number
- T1045
- Product name
- Tetramethoxymethane
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $250
- Updated
- 2024/03/01
- Product number
- T1045
- Product name
- Tetramethoxymethane
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $999
- Updated
- 2024/03/01
- Product number
- H66617
- Product name
- Tetramethyl orthocarbonate
- Purity
- 95%
- Packaging
- 1g
- Price
- $40.65
- Updated
- 2024/03/01
Tetramethoxymethane Chemical Properties,Usage,Production
Description
Tetramethoxymethane can be usede in ?CO2 fixation, formation of orthocarbonates from diols and electrophilic introduction of an ester functionality.
Uses
Tetramethoxymethane has application within an electrolyte solution for the use of rechargeable lithium batteries. It has also been used as a reactant in the synthesis of novel anti-HIV-1 compounds.
Synthesis
Tetramethoxymethane has been prepared by heating a solution of Sodium Methoxide in methanol with chloropicrin, Trichloroacetonitrile, or thiocarbonyl perchlorate; the best yields have been obtained with the perchlorate. Alternatively, disodium hexamethoxystannate (prepared in situ from sodium methoxide and tetrachlorostannane) can be refluxed with Carbon Disulfide in methanol to form the orthocarbonate.
Purification Methods
Tetramethyl orthocarbonate (methyl orthocarbonate, tetramethoxy methane) [1850-14-2] M 136.2, m -5.6o, -5o, -2o, b 113.5o/760mm, 113.5 -114o/755mm, 112-114o/atm, d 4 1.0202, n D 1.3860. Purify it in the same way as for tetraethyl orthocarbonate. [Smith Acta Chem Scand 10 1006 1956, Tiekelmann & Post J Org Chem 13 266 1948, Kantlehner et al. Synthesis 73 1977, Beilstein 3 IV 4.]
Tetramethoxymethane Preparation Products And Raw materials
Raw materials
Preparation Products
Tetramethoxymethane Suppliers
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View Lastest Price from Tetramethoxymethane manufacturers
- Product
- Tetramethoxymethane 1850-14-2
- Price
- US $7.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- Judy@coreychem.com
- Release date
- 2019-12-18