Bisphenoxyethanolfluorene

Product Name: Bisphenoxyethanolfluorene
CAS No.: 117344-32-8
Chemical Name: Bisphenoxyethanolfluorene
Synonyms: bpef;BK122;LABOTEST-BB LT00112265;Bisphenoxyethanolfuorene;Bisphenoxyethanolfluorene;9-Fluorenbisphenoxyethanol;BISPHENOXY ETHANOL FLUORENONE;9,9-Bis[4-(2-Hydroxyethoxy)Phe;Bisphenoxyethanolfluorene BPEF;TIANFU-CHEM Bisphenoxyethanolfluorene
CBNumber: CB6747899
Molecular Formula: C29H26O4
Formula Weight: 438.51
MOL File: 117344-32-8.mol

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Bisphenoxyethanolfluorene Property

Melting point:: 117-120 °C(lit.)
Boiling point:: 610.7±55.0 °C(Predicted)
Density: 1.248±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
Water Solubility: Insoluble in water
form: powder to crystal
pka: 13.95±0.10(Predicted)
color: White to Almost white
InChI: InChI=1S/C29H26O4/c30-17-19-32-23-13-9-21(10-14-23)29(22-11-15-24(16-12-22)33-20-18-31)27-7-3-1-5-25(27)26-6-2-4-8-28(26)29/h1-16,30-31H,17-20H2
InChIKey: NQXNYVAALXGLQT-UHFFFAOYSA-N
SMILES: C1(C2=CC=C(OCCO)C=C2)(C2=CC=C(OCCO)C=C2)C2=C(C=CC=C2)C2=C1C=CC=C2
CAS DataBase Reference: 117344-32-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 37
Safety Statements: 26-36
WGK Germany: 3
HS Code: 29094990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P330Rinse mouth.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 437921
Product name: 4,4′-(9-Fluorenylidene)bis(2-phenoxyethanol)
Purity: 97%
Packaging: 25g
Price: $280
Updated: 2023/06/20

TCI Chemical

Product number: F0447
Product name: 9,9-Bis[4-(2-hydroxyethoxy)phenyl]fluorene
Purity: >98.0%(GC)
Packaging: 5g
Price: $43
Updated: 2025/07/31

TCI Chemical

Product number: F0447
Product name: 9,9-Bis[4-(2-hydroxyethoxy)phenyl]fluorene
Purity: >98.0%(GC)
Packaging: 25g
Price: $129
Updated: 2025/07/31

TRC

Product number: F591598
Product name: 2,2''-(((9H-Fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy))diethanol
Packaging: 500mg
Price: $75
Updated: 2021/12/16

AK Scientific

Product number: G733
Product name: 9,9-Bis[4-(2-hydroxyethoxy)phenyl]fluorene
Packaging: 1g
Price: $22
Updated: 2021/12/16

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Bisphenoxyethanolfluorene Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

4,4′-(9-Fluorenylidene)bis(2-phenoxyethanol) may be used for the following syntheses:

poly-(carbotetramethyldisiloxane)s, containing poly[oxy{4,4′-(9-fluorenylidene)bis(2-phenoxyethylene)}oxytetramethyldisiloxane] (a fluorescent aromatic chromophore group)
poly[oxy(arylene)oxy(tetramethyldisilylene)]s, containing fluorescent aromatic chromophore groups in the polymer main chain, via melt copolymerization reaction with 1,2-bis(diethylamino)tetramethyldisilane

General Description

4,4′-(9-Fluorenylidene)bis(2-phenoxyethanol) is an aryldiol.

Synthesis

122-99-6

486-25-9

117344-32-8

The general procedure of Example 12 was as follows:(a) In a glass reactor equipped with a stirrer, a nitrogen introduction tube, a thermometer and a T-tube, 80.0 g (0.444 mol) of 9-fluorenone, 613.5 g (4.44 mol) of 2-phenoxyethanol and 2.0 g of tungstophosphoric acid catalyst [(H3PW12O40).nH2O] were added. (b) The mixture was reacted at 130°C for 4 hours under reduced pressure of 2.0 x 1.03 Pa. Upon completion of the reaction, the amount of polymers in the reaction mixture was 3.9%. To the reaction mixture was added 800.0 g of toluene, neutralized with aqueous sodium hydroxide and washed with water to separate the organic phase. Toluene and excess 2-phenoxyethanol were removed from the organic phase by concentration under reduced pressure. To the concentrate was added 560.0 g of toluene, and the mixture was heated and stirred at 80 °C for 1 hour, then cooled to 70 °C. 0.4 g of 9,9-bis[(4-(2-hydroxyethoxy)phenyl)]fluorene was added as a crystalline species, and the mixture was held at 70°C for 2 hours and then cooled to 20°C. The precipitated crystals were filtered and dried to give 78.0 g of white crystals 9,9-bis[(4-(2-hydroxyethoxy)phenyl)]fluorene (yield: 90.2%, purity: 99.2%). The melting point of the resulting product was 163 °C.

References

[1] Patent: US2012/29244, 2012, A1. Location in patent: Page/Page column 15
[2] Patent: JP6139508, 2017, B2. Location in patent: Paragraph 0024
[3] Patent: EP2123625, 2009, A1. Location in patent: Page/Page column 6
[4] Chemistry Letters, 1998, # 10, p. 1055 - 1056
[5] Chemistry Letters, 1998, # 10, p. 1055 - 1056

Bisphenoxyethanolfluorene Preparation Products And Raw materials

Raw materials

Preparation Products

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Bisphenoxyethanolfluorene Suppliers

Americas 1 Australia 1 China 258 Europe 1 Germany 2 India 4 Japan 7 South Korea 3 Switzerland 1 United Arab Emirates 1 United Kingdom 4 United States 20 Global 303

Jiangsu ever galaxy chemical co.,ltd.

Tel: 0527-81083685 18602515822
Fax: 0086-527-84450055
Email: info@egchemical.com
Country: China
ProdList: 78
Advantage: 65

Chengdu Yuanda chemical co.,ltd

Tel: 028-85356300 18980937689
Fax: +86-28-85356300
Email: chenquanxing@126.com
Country: China
ProdList: 108
Advantage: 55

Zhengzhou HongSheng Pharmaceutical Co., Ltd.

Tel: 0371-0371-13526885213 15637198702
Fax: 0371-63709726
Email: hsyykjchem@163.com
Country: China
ProdList: 3853
Advantage: 58

Changzhow Moisten International Trading Co., Ltd.

Tel: 13606112397
Email: tang13606112397@163.com
Country: China
ProdList: 191
Advantage: 58

Shandong Kanghong New Material Technology Co., Ltd

Tel: 17686625089
Email: shandongkanghong@qq.com
Country: China
ProdList: 98
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
ProdList: 3572
Advantage: 66

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
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View Lastest Price from Bisphenoxyethanolfluorene manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: Bisphenoxyethanolfluorene 117344-32-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-04

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Bisphenoxyethanolfluorene Bpef 117344-32-8
Price: US $180.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-06-05

Shanghai UCHEM Inc.

Product: Bisphenoxyethanolfluorene 117344-32-8
Price: US $87.00-1190.00/kg
Min. Order: 1kg
Purity: 0.98
Supply Ability: 100kg
Release date: 2023-10-20

117344-32-8, BisphenoxyethanolfluoreneRelated Search:

9,9-Bis(4-hydroxyphenyl)fluorene 9,9-Bis(4-hydroxy-3-methylphenyl)fluorene 9,9-Bis[4-(2-acryloyloxyethyloxy)phenyl]fluorene 2-Phenoxyethanol Fluorene 4,4'-(1-Phenylethylidene) biphenol Bisphenoxyethanolfluorene 4,4'-Dihydroxytetraphenylmethane 9,9-Dimethyl-9H-fluorene 4,4'-ISOPROPYLIDENEBIS(2-PHENOXYETHANOL) 4-TRITYLPHENOL Tetraphenylmethane 2,2'-[9H-Fluoren-9-ylidenebis(4,1-phenyleneoxymethylene)]bis-oxirane

9,9 -Bis(4-(2-Hydroxyethoxy) phenyl)Fluorene,4,4' -(9-Fluorenylidene)bis(2-phenoxyethanol)

2,2'-[9H-Fluoren-9-ylidenebis(4,1-phenyleneoxy)]bis[ethanol]

9,9-BIS[4-(2-HYDROXYETHOXY)PHENYL]FLUORENE

4,4'-(9-FLUORENYLIDENE)BIS(2-PHENOXYETHANOL)

9,9-Bis[4-(2-Hydroxyethoxy)Phe

BISPHENOXYETHANOLFLUORENE 9,9-BIS[4-(2-HYDROXYETHOXY)PHENYL]FLUORENE

Bisphenoxyethanolfluorene

bpef

LABOTEST-BB LT00112265

2,2'-[9-Fluorenylidenebis(p-phenylenoxy)]diethanol

BISPHENOXY ETHANOL FLUORENONE

9-Fluorenbisphenoxyethanol

Bisphenoxyethanolfuorene

2,2'-(((9H-Fluorene-9,9-diyl)bis(4,1-phenylene))bis(oxy))diethanol

Bisphenoxyethanolfluorene BPEF

Ethanol,2,2'-[9H-fluoren-9-ylidenebis(4,1-phenyleneoxy)]bis-

9,9-bis [(4-hydroxyethoxy) phenyl] fluorene

9,9-Bis[4-(2-hydroxyethoxy)phenyl]fluorene&gt

9, 9-bis [4-(2-hydroxyethyl) phenyl] fluorene

9,9-bis[4-(2-hydroxyethoxy )phenyl]fiuorene

TIANFU-CHEM Bisphenoxyethanolfluorene

9,9-Bis(4-(2-Hydroxyethoxy)phenyl) Fluorene (BPEF)

Bisphenoxyethanolfluorene, 9,9-bis[4-(2-hydroxyethoxy )phenyl]fiuorene

101-99-bis (4-92 hydroxyethoxy) phenyl) fluorene

4,4'-(9-fluorenylidene)bis(2-phenoxy-ethanol)

BK122

4,4'-(9-fluorenylidene)bis(2-phenoxy-ethanol) BPEF

Bisphenoxyethanolfluorene, 10 mM in DMSO

9,9-Bis[(4-hydroxyphenoxy)phenyl]fluorene

4,4′-(9-Fluorenylidene)bis(2-phenoxyethanol), CAS 117344-32-8

9,9-bis[4-(2-hydroxyethoxy)phenyl]fluorine

117344-32-8

C29H26O4

Oxygen Compounds

Organic Building Blocks

Building Blocks

Alcohols

C9 to C30

Fluorenes & Fluorenones

Fluorenes

Reagent for High-Performance Polymer Research

Fluorenes, etc. (reagent for high-performance polymer research)

Alcohols

C9 to C30

Oxygen Compounds

Fluorenes

Fluorenes & Fluorenones

Fluorenes, etc. (reagent for high-performance polymer research)

Functional Materials

Reagent for High-Performance Polymer Research

Fluorene series

Pharmaceutical intermediates

Fine chemical