ChemicalBook > CAS DataBase List > 8-Hydroxy-2-naphthylamine-3,6-disulfonic acid

8-Hydroxy-2-naphthylamine-3,6-disulfonic acid

Product Name
8-Hydroxy-2-naphthylamine-3,6-disulfonic acid
CAS No.
90-40-4
Chemical Name
8-Hydroxy-2-naphthylamine-3,6-disulfonic acid
Synonyms
SULFO GAMMA ACID;VNWVMZDJPMCAKD-UHFFFAOYSA-N;2-Amino-8-naphthol-6-disulfonic acid;8-Hydroxy-2-naphthylamine-3,6-disulfonic acid;3-amino-5-hydroxynaphthalene-2,7-disulfonic acid;3-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid;3-amino-5-hydroxynaphthalene-2,7-disulphonic acid;2,7-Naphthalenedisulfonicacid, 3-aMino-5-hydroxy-;3-azanyl-5-hydroxy-naphthalene-2,7-disulfonic acid;(2R)-2-amino-3-[[(2R)-2-amino-2-carboxypropyl]trisulfanyl]-2-methylpropanoic acid
CBNumber
CB6875787
Molecular Formula
C10H9NO7S2
Formula Weight
319.31
MOL File
90-40-4.mol
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8-Hydroxy-2-naphthylamine-3,6-disulfonic acid Property

Boiling point:
603.18℃[at 101 325 Pa]
Density 
1.88[at 20℃]
vapor pressure 
0Pa at 25℃
Water Solubility 
35.36g/L at 25℃
LogP
-2.334
EPA Substance Registry System
2,7-Naphthalenedisulfonic acid, 3-amino-5-hydroxy- (90-40-4)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
CHM0388965
Product name
3-AMINO-5-HYDROXYNAPHTHALENE-2,7-DISULFONIC ACID
Purity
95.00%
Packaging
5MG
Price
$504.88
Updated
2021/12/16
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8-Hydroxy-2-naphthylamine-3,6-disulfonic acid Chemical Properties,Usage,Production

Chemical Properties

2-Amino-8-hydroxynaphthalene-3,6-disulfonic acid [90-40-4]. (3-amino-5-hydroxy2,7-disulfonic acid), RR acid, 2 R acid, Columbia acid, C10H9NO7S2, Mr 319.3, and its alkali salts are readily soluble in water. Coupling with diazo compounds takes place under alkaline conditions in the position ortho to the hydroxyl group.

Uses

The RR acid is used as a coupling component in azo dyes, e.g., C.I. Food Black 2 and C.I. Direct Brown 151.

Production Methods

2-Aminonaphthalene-3,6,8-trisulfonic acid liquor is concentrated by evaporation and heated with sodium hydroxide liquor in an autoclave [7]. The temperature is raised to 195℃ over 10 h and held at 195℃ for another 8 – 10 h until completion of the reaction is determined by working up a test sample and obtaining a strength by alkaline coupling equal to the diazotization titer. After dilution, acidification, and stirring while hot until all sulfur dioxide is expelled, the product is filtered off as its monosodium salt at 55℃ and washed with brine. Most of the isomeric 2-amino-3-hydroxynaphthalene-6,8-disulfonic acid impurity is removed in the filtrate. Crude RR acid is obtained in 65 % yield and is suitable for certain outlets. Further purification is necessary for critical derived dyes, and this is achieved by dissolving in dilute alkali, filtering at 80℃, and reprecipitating by addition of sodium chloride and hydrochloric acid. Filtration at 55℃ gives 90 % recovery of product.

Flammability and Explosibility

Not classified

8-Hydroxy-2-naphthylamine-3,6-disulfonic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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8-Hydroxy-2-naphthylamine-3,6-disulfonic acid Suppliers

Chizhou Kailong Import and Export Trade Co., Ltd.
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xg01_gj@163.com
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China
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Amadis Chemical Company Limited
Tel
571-89925085
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0086-571-89925065
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sales@amadischem.com
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China
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131957
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Hefei TNJ Chemical Industry Co.,Ltd.
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+86-0551-65418671 +8618949823763
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0551-65418697
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sales@tnjchem.com
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Hubei Jusheng Technology Co.,Ltd.
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18871490254
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027-59599243
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linda@hubeijusheng.com
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CHINA
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Z-trans Biochemistry Technology (Suzhou) Co.,Ltd
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0512-66317708 13372112871
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huijuan@zitrans.cn
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Shaanxi DIDU pharmaceutical and Chemical Co., Ltd
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15229059051
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1027@dideu.com
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China
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10003
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Z-trans Biochemistry Technology (Suzhou) Co.,Ltd
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0512-66317708 13372112871
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huijuan@zitrans.cn
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Guangzhou Reullei Pharmaceutical Technology Co., Ltd,
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13660253774
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joe.yang@reullei.com
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China
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Suzhou ARTK Medchem Co., Ltd.
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+86-512-68323658 +86-18168183658
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sales1@artkmedchem.com
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China
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39004
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90-40-4, 8-Hydroxy-2-naphthylamine-3,6-disulfonic acidRelated Search:


  • 8-Hydroxy-2-naphthylamine-3,6-disulfonic acid
  • 3-amino-5-hydroxynaphthalene-2,7-disulphonic acid
  • 3-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid
  • 3-amino-5-hydroxynaphthalene-2,7-disulfonic acid
  • (2R)-2-amino-3-[[(2R)-2-amino-2-carboxypropyl]trisulfanyl]-2-methylpropanoic acid
  • 3-azanyl-5-hydroxy-naphthalene-2,7-disulfonic acid
  • 2,7-Naphthalenedisulfonicacid, 3-aMino-5-hydroxy-
  • 2-Amino-8-naphthol-6-disulfonic acid
  • VNWVMZDJPMCAKD-UHFFFAOYSA-N
  • SULFO GAMMA ACID
  • 90-40-4
  • NH2HOC10H4SO3H2
  • Intermediates of Dyes and Pigments