1-Bromo-3,5-diphenylbenzene
- Product Name
- 1-Bromo-3,5-diphenylbenzene
- CAS No.
- 103068-20-8
- Chemical Name
- 1-Bromo-3,5-diphenylbenzene
- Synonyms
- 5'-Bromo-1,1':3',1''-terphenyl;M-DPPBr;5-diphenylbenzene;5'-Bromo-m-terphenyl;5'-Bromo-m-terphenyl;5'-Bromo-m-terphenyl >1-BroMo-3,5-diphenylbenzen;5'-Bromo-m-terphenyl;1,3-diphenyl-5-broMobenzene;1-Bromo-3,5-diphenylbenzene
- CBNumber
- CB6969701
- Molecular Formula
- C18H13Br
- Formula Weight
- 309.2
- MOL File
- Mol file
1-Bromo-3,5-diphenylbenzene Property
- Melting point:
- 105-106℃
- Boiling point:
- 401.1±14.0 °C(Predicted)
- Density
- 1.309
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- color
- White to Almost white
- λmax
- 252nm(CH2Cl2)(lit.)
- InChI
- InChI=1S/C18H13Br/c19-18-12-16(14-7-3-1-4-8-14)11-17(13-18)15-9-5-2-6-10-15/h1-13H
- InChIKey
- IOPQERQQZZREDR-UHFFFAOYSA-N
- SMILES
- C1(C2=CC(Br)=CC(C3=CC=CC=C3)=C2)=CC=CC=C1
Safety
- RIDADR
- UN 3152 9/PG II
- HazardClass
- 9
- PackingGroup
- II
- HS Code
- 2903998090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B4308
- Product name
- 5'-Bromo-m-terphenyl
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $81
- Updated
- 2025/07/31
- Product number
- B4308
- Product name
- 5'-Bromo-m-terphenyl
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $244
- Updated
- 2025/07/31
- Product number
- B700400
- Product name
- 5''-Bromo-1,1'':3'',1''''-terphenyl
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- X4093
- Product name
- 1-Bromo-3,5-diphenylbenzene
- Packaging
- 25g
- Price
- $193
- Updated
- 2021/12/16
- Product number
- FB33670
- Product name
- 1-Bromo-3,5-diphenylbenzene
- Packaging
- 50g
- Price
- $500
- Updated
- 2021/12/16
1-Bromo-3,5-diphenylbenzene Chemical Properties,Usage,Production
Chemical Properties
off-whtie powder
Uses
1-Bromo-3,5-diphenylbenzene is used in the synthesis of Aromatic Dendrimers Bearing 2,4,6-Triphenyl-1,3,5-triazine Cores.
Synthesis
626-39-1
98-80-6
103068-20-8
To a 500 mL reactor was sequentially added 1,3,5-tribromobenzene 25 g (79 mmol), phenylboronic acid 23.3 g (191 mmol), potassium carbonate 32.9 g (238 mmol), tetrakis(triphenylphosphine)palladium 6.12 g (3 mmol), distilled water 50 mL, and toluene 125 mL.The mixture was stirred in 125 mL of 1 ,4-dioxane and refluxed for 24 hours. Upon completion of the reaction, the organic layer was separated and concentrated under reduced pressure. The product was purified by recrystallization from toluene and methanol to give 21 g of 5-bromo-1,1:3,1-triphenylene in 85% yield.
References
[1] Patent: KR2015/130797, 2015, A. Location in patent: Paragraph 0467-0472
[2] Synthesis, 2004, # 13, p. 2181 - 2185
[3] Dyes and Pigments, 2018, vol. 158, p. 42 - 49
[4] Patent: EP2447250, 2012, A1. Location in patent: Page/Page column 37
[5] Bulletin of the Korean Chemical Society, 2014, vol. 35, # 10, p. 3041 - 3046
1-Bromo-3,5-diphenylbenzene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-Bromo-3,5-diphenylbenzene manufacturers
- Product
- 1-Bromo-3,5-diphenylbenzene 103068-20-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2025-03-10
- Product
- 1-Bromo-3,5-diphenylbenzene 103068-20-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 150KG /month
- Release date
- 2021-11-16
- Product
- 1-Bromo-3,5-diphenylbenzene 103068-20-8
- Price
- US $200.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-30