2-BROMO-N,N,4-TRIMETHYLANILINE
- Product Name
- 2-BROMO-N,N,4-TRIMETHYLANILINE
- CAS No.
- 23667-06-3
- Chemical Name
- 2-BROMO-N,N,4-TRIMETHYLANILINE
- Synonyms
- 2-BROMO-N,N,4-TRIMETHYLANILINE;Benzenamine, 2-bromo-N,N,4-trimethyl-
- CBNumber
- CB7110304
- Molecular Formula
- C9H12BrN
- Formula Weight
- 214.1
- MOL File
- Mol file
2-BROMO-N,N,4-TRIMETHYLANILINE Property
- storage temp.
- Inert atmosphere,Room Temperature
- Appearance
- Colorless to light yellow Liquid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B613163
- Product name
- 2-Bromo-N,N,4-trimethylaniline
- Packaging
- 50mg
- Price
- $90
- Updated
- 2021/12/16
- Product number
- HCH0344007
- Product name
- 2-BROMO-N,N,4-TRIMETHYLANILINE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $257.25
- Updated
- 2021/12/16
- Product number
- 4354CU
- Product name
- 2-Bromo-N,N,4-trimethylaniline
- Packaging
- 5g
- Price
- $365
- Updated
- 2021/12/16
- Product number
- A130093
- Product name
- 2-Bromo-N,N,4-trimethylaniline
- Purity
- 97%
- Packaging
- 10g
- Price
- $453
- Updated
- 2021/12/16
- Product number
- CD12093159
- Product name
- 2-Bromo-N,N,4-trimethylaniline
- Purity
- 97+%
- Packaging
- 10g
- Price
- $505
- Updated
- 2021/12/16
2-BROMO-N,N,4-TRIMETHYLANILINE Chemical Properties,Usage,Production
Synthesis
99-97-8
23667-06-3
General procedure for the synthesis of 2-bromo-N,N,4-trimethylaniline from N,N-dimethyl-p-toluidine: In a round-bottomed flask, N,N-dimethyl-p-toluidine (1 mmol) was mixed with 48% aqueous hydrobromic acid (1 mL) in dimethyl sulfoxide (DMSO, 1 mL). The reaction mixture was stirred at the indicated temperature for 1-4 hours. After completion of the reaction, it was cooled to room temperature and the pH of the reaction solution was adjusted to 7-8 with 4 M aqueous sodium hydroxide.Subsequently, the reaction mixture was extracted twice with ethyl acetate (EtOAc) and the organic phases were combined. The organic phase was dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to afford the target product 2-bromo-N,N,4-trimethylaniline.
References
[1] Journal of Chemical Research, 2014, vol. 38, # 10, p. 593 - 596
[2] Synthesis, 2009, # 21, p. 3672 - 3676
[3] Synthetic Communications, 2010, vol. 40, # 19, p. 2954 - 2962
[4] Tetrahedron Letters, 2007, vol. 48, # 45, p. 7969 - 7973
[5] Chemische Berichte, 1908, vol. 41, p. 2117
2-BROMO-N,N,4-TRIMETHYLANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
2-BROMO-N,N,4-TRIMETHYLANILINE Suppliers
- Tel
- --
- Fax
- --
- sales@ajchem.in
- Country
- India
- ProdList
- 6100
- Advantage
- 58