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ChemicalBook > CAS DataBase List > (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

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Product Name
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CAS No.
167709-31-1
Chemical Name
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms
SL-A121-2;(S)-3,5-t-Bu-MeOBIPHEP;(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine];(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(S)-2,2'-Bis[bis(3,5-di-tert-butylphenyl)phosphino]-6,6'- dimethoxy-1,1'-biphenyl;(S)-(-)-2,2'-Bis[di-(3,5-di-t-butylphenyl)-phosphino]- 6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-2,2''-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl;(S)-(-)-2,2'-Bis[di-(3,5-di-tert-butylphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CBNumber
CB71180991
Molecular Formula
C70H96O2P2
Formula Weight
1031.46
MOL File
167709-31-1.mol
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(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Property

Boiling point:
856.5±65.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
white
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Safety

WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-0045
Product name
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
15-0045
Product name
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging
500mg
Price
$355
Updated
2024/03/01
Strem Chemicals
Product number
15-0045
Product name
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging
2g
Price
$1207
Updated
2024/03/01
Strem Chemicals
Product number
15-0045
Product name
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging
10g
Price
$4824
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0001344
Product name
(S)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYLPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL
Purity
95.00%
Packaging
500MG
Price
$914.41
Updated
2021/12/16
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(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Usage,Production

Reactions

  1. Pd-catalyzed enantioselective Heck reaction.
  2. Used in enantioselective lactam synthesis via Pd-catalyzed intramolecular allylic alkylation.
  3. Used in enantioselective Au-catalyzed polycyclization reactions. 

Chemical Properties

White powder

Uses

(S)-3,5-t-Bu-MeOBIPHEP can be used as a ligand in the stereoselective preparation of allenoates via palladium-catalyzed asymmetric carbonylation of propargylic carbonates. It can also be used in the C-C coupling reactions.

General Description

sold in collaboration with Solvias AG

(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers

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View Lastest Price from (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% manufacturers

Career Henan Chemical Co
Product
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% 167709-31-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

167709-31-1, (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%Related Search:

(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chloro[(R)-(-)5,5μ-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4μ-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

  • (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
  • (S)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYLPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
  • (S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine]
  • (S)-3,5-t-Bu-MeOBIPHEP, SL-A121-2, (S)-2,2μ-Bis[bis(3,5-di-tert-butyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl
  • (S)-(-)-2,2'-Bis[di-(3,5-di-tert-butylphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl
  • (S)-3,5-t-Bu-MeOBIPHEP
  • SL-A121-2
  • (S)-(-)-2,2'-Bis[di-(3,5-di-t-butylphenyl)-phosphino]- 6,6'-dimethoxy-1,1'-biphenyl
  • (S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] >=97%, optical purity ee: >=99%
  • Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis[3,5-bis(1,1-dimethylethyl)phenyl]-
  • (S)-2,2'-Bis[bis(3,5-di-tert-butylphenyl)phosphino]-6,6'- dimethoxy-1,1'-biphenyl
  • (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
  • (S)-(-)-2,2''-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl
  • (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl
  • (S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine
  • 167709-31-1
  • Chiral Phosphine
  • MeOBIPHEP Series