4-BROMO-2-METHYL-2H-INDAZOLE
- Product Name
- 4-BROMO-2-METHYL-2H-INDAZOLE
- CAS No.
- 590417-93-9
- Chemical Name
- 4-BROMO-2-METHYL-2H-INDAZOLE
- Synonyms
- 2-Methyl-4-bromoindazole;4-Bromo-2-methylindazole;-BROMO-2-METHYL-2H-INDAZOLE;4-BROMO-2-METHYL-2H-INDAZOLE;4-Bromo-2-methyl-1H-indazole;2H-Indazole, 4-bromo-2-methyl-;4-Bromo-2-methyl-2H-indazole
- CBNumber
- CB71215954
- Molecular Formula
- C8H7BrN2
- Formula Weight
- 211.06
- MOL File
- 590417-93-9.mol
4-BROMO-2-METHYL-2H-INDAZOLE Property
- Boiling point:
- 322.7±15.0 °C(Predicted)
- Density
- 1.60±0.1 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- solid
- pka
- -0.02±0.30(Predicted)
- Appearance
- White to off-white Solid
- InChI
- InChI=1S/C8H7BrN2/c1-11-5-6-7(9)3-2-4-8(6)10-11/h2-5H,1H3
- InChIKey
- OFOZLGCQBJDWRJ-UHFFFAOYSA-N
- SMILES
- N1=C2C(C(Br)=CC=C2)=CN1C
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- SYX00128
- Product name
- 4-Bromo-2-methyl-2H-indazole
- Purity
- Aldrich
- Packaging
- 1g
- Price
- $259
- Updated
- 2025/07/31
- Product number
- B697248
- Product name
- 4-Bromo-2-methyl-2H-indazole
- Packaging
- 250mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- B697248
- Product name
- 4-Bromo-2-methyl-2H-indazole
- Packaging
- 500mg
- Price
- $70
- Updated
- 2021/12/16
- Product number
- 3H32-9-X4
- Product name
- 4-Bromo-2-methyl-2H-indazole
- Packaging
- 250mg
- Price
- $64
- Updated
- 2021/12/16
- Product number
- 3H32-9-X4
- Product name
- 4-Bromo-2-methyl-2H-indazole
- Packaging
- 1g
- Price
- $111
- Updated
- 2021/12/16
4-BROMO-2-METHYL-2H-INDAZOLE Chemical Properties,Usage,Production
Uses
4-Bromo-2-methyl-2H-indazole is mainly used as a chemical reagent and organic synthesis intermediate in the field of scientific research.
Synthesis
420-37-1
186407-74-9
590417-93-9
The general procedure for the synthesis of 4-bromo-2-methyl-2H-indazole from trimethoxonium tetrafluoroborate and 4-bromo-1H-indazole was as follows: with reference to Example 33, 4-bromo-1H-indazole (2.24 g, 11.4 mmol) was dissolved in ethyl acetate (110 mL) and trimethoxonium tetrafluoroborate (2.19 g, 14.8 mmol) was added. The reaction mixture was stirred at room temperature for 3 hours. After completion of the reaction, the reaction solution was diluted with ethyl acetate, washed sequentially with aqueous sodium bicarbonate and dried over anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure and the resulting residue was purified by silica gel column chromatography (eluent: ethyl acetate/hexane=10/90→40/60) to afford 4-bromo-2-methyl-2H-indazole (2.29 g, 95% yield). The product was characterized by 1H-NMR (CDCl3): δ 4.23 (3H, s), 7.13 (1H, dd, J=8.5,7.2 Hz), 7.23 (1H, dd, J=7.2,0.8 Hz), 7.60-7.44 (1H, m), 7.91 (1H, m). The mass spectrum (ESI+) showed the molecular ion peak m/z 211 (M+H).
References
[1] Patent: EP2141150, 2010, A1. Location in patent: Page/Page column 63-64
4-BROMO-2-METHYL-2H-INDAZOLE Preparation Products And Raw materials
Raw materials
Preparation Products
4-BROMO-2-METHYL-2H-INDAZOLE Suppliers
- Tel
- 0512-0512-68437753 13861119411
- 331723639@qq.com
- Country
- China
- ProdList
- 207
- Advantage
- 58
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- +86 (0) 571 85 58 67 18
- Fax
- 0086-571-85864795
- Country
- China
- ProdList
- 18207
- Advantage
- 66
- Tel
- 13526569071
- sales@leadmedpharm.com
- Country
- China
- ProdList
- 7892
- Advantage
- 64
- Tel
- 10-61256048 13810278579
- Fax
- +86 10 61256049
- sales@zeroschem.com
- Country
- China
- ProdList
- 1370
- Advantage
- 59
- Tel
- 021-50135380
- shchemsky@sina.com
- Country
- China
- ProdList
- 32321
- Advantage
- 50
- Tel
- Fax
- E-Mail Inquiry
- info@syntechem.com
- Country
- China
- ProdList
- 12984
- Advantage
- 57
- Tel
- +86-25-68710855, +86-25-68710897
- Fax
- 025-68710856
- sales@springpharma.net
- Country
- China
- ProdList
- 1261
- Advantage
- 62
- Tel
- 021-58388037;21-58388037 13472507714
- 35177634@qq.com;1589045147@qq.com
- Country
- China
- ProdList
- 803
- Advantage
- 55
View Lastest Price from 4-BROMO-2-METHYL-2H-INDAZOLE manufacturers
- Product
- 4-BROMO-2-METHYL-2H-INDAZOLE 590417-93-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2020-01-02