1-Aziridinecarboxylicacid,1,1-dimethylethylester(9CI)

Product Name: 1-Aziridinecarboxylicacid,1,1-dimethylethylester(9CI)
CAS No.: 97308-23-1
Chemical Name: 1-Aziridinecarboxylicacid,1,1-dimethylethylester(9CI)
Synonyms: 1-Boc-aziridine;N-Boc-aziridine;N-(tert-butoxycarbonyl)aziridine;tert-butyl aziridine-1-carboxylate;1-Aziridinecarboxylicacid tert-butyl ester;tert-Butyl aziridine-1-carboxylate - [B8345];1-Aziridinecarboxylic acid, 1,1-diMethylethyl ester;1-Aziridinecarboxylicacid,1,1-dimethylethylester(9Cl);1-Aziridinecarboxylicacid,1.1-dimethylethylester(qci);1-Aziridinecarboxylicacid,1,1-dimethylethylester(9CI)
CBNumber: CB71298863
Molecular Formula: C7H13NO2
Formula Weight: 143.18
MOL File: 97308-23-1.mol

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1-Aziridinecarboxylicacid,1,1-dimethylethylester(9CI) Property

Boiling point:: 174.8±9.0 °C(Predicted)
Density: 1.088±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Store in freezer, under -20°C
pka: -3.23±0.20(Predicted)
Appearance: Colorless to light yellow Liquid
InChI: InChI=1S/C7H13NO2/c1-7(2,3)10-6(9)8-4-5-8/h4-5H2,1-3H3
InChIKey: VBYPJHLRWKGNAI-UHFFFAOYSA-N
SMILES: N1(C(OC(C)(C)C)=O)CC1

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC

Product number: B807042
Product name: N-(tert-Butoxycarbonyl)aziridine
Packaging: 100mg
Price: $115
Updated: 2021/12/16

TRC

Product number: B807042
Product name: N-(tert-Butoxycarbonyl)aziridine
Packaging: 500mg
Price: $440
Updated: 2021/12/16

TRC

Product number: B807042
Product name: N-(tert-Butoxycarbonyl)aziridine
Packaging: 1g
Price: $745
Updated: 2021/12/16

Synthonix

Product number: B8345
Product name: tert-Butylaziridine-1-carboxylate
Purity: 97.0%
Packaging: 250mg
Price: $75
Updated: 2021/12/16

ChemScene

Product number: CS-0079678
Product name: tert-Butylaziridine-1-carboxylate
Packaging: 100mg
Price: $78
Updated: 2021/12/16

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1-Aziridinecarboxylicacid,1,1-dimethylethylester(9CI) Chemical Properties,Usage,Production

Uses

N-(tert-Butoxycarbonyl)aziridine is a useful reagent for organic synthesis and other chemical processes. It is used as a reagent in the preparation of substituted indolines and carbazoles by benzyne-mediated cyclization-functionalization.

Synthesis

151-56-4

24424-99-5

97308-23-1

Example 47 Synthesis of N-Boc aziridine 166: To a solution of aziridine 165 (125 mg, 0.49 mmol) in dichloromethane (7 mL) was added triethylamine (70 μL), DMAP (catalytic amount), and di-tert-butyl dicarbonate (Boc anhydride, 113 mg, 0.52 mmol) in sequence. The reaction mixture was stirred at room temperature for 1 h and then concentrated under reduced pressure to remove the solvent. The residue was purified by fast column chromatography (eluent: hexane solution of 40% ethyl acetate) to afford 154 mg (88% yield) of the title compound, N-Boc aziridine 166, as a light colored oil.1H NMR (CDCl3, 300 MHz): δ 6.82 (m, 1H); 4.47 (br m, 1H); 4.23 (t, 2H, J = 4.7 Hz); 3.81 (t, 2H, J = 4.7 Hz); 3.75 (s, 3H); 3.00 (br d, 1H, J = 18.0 Hz); 2.90-2.85 (m, 2H); 2.65-2.55 (m, 1H); 2.10 (s, 3H); 1.44 (s, 9H).

References

[1] Chemical Communications, 1998, # 2, p. 253 - 254
[2] Patent: US6534037, 2003, B1
[3] Patent: US5952375, 1999, A
[4] Patent: US5763483, 1998, A
[5] Patent: US2004/53999, 2004, A1

1-Aziridinecarboxylicacid,1,1-dimethylethylester(9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Aziridinecarboxylicacid,1,1-dimethylethylester(9CI) Suppliers

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97308-23-1, 1-Aziridinecarboxylicacid,1,1-dimethylethylester(9CI)Related Search:

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