Uses Application
ChemicalBook > CAS DataBase List > 3,6-DIBROMOTHIENO[3,2-B]THIOPHENE

3,6-DIBROMOTHIENO[3,2-B]THIOPHENE

Uses Application
Product Name
3,6-DIBROMOTHIENO[3,2-B]THIOPHENE
CAS No.
392662-65-6
Chemical Name
3,6-DIBROMOTHIENO[3,2-B]THIOPHENE
Synonyms
BTH-3Sn;3,6-DIBROMOTHIENO[3,2-B]THIOPHENE;Thieno[3,2-b]thiophene, 3,6-dibromo-;3,6-Dibromothieno[3,2-b]thiophene>3,6-Dibromothiophene [3,2-B] thiophene;3,6-DIBROMOTHIENO[3,2-B]THIOPHENE ISO 9001:2015 REACH
CBNumber
CB71476285
Molecular Formula
C6H2Br2S2
Formula Weight
298.02
MOL File
392662-65-6.mol
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3,6-DIBROMOTHIENO[3,2-B]THIOPHENE Property

Melting point:
127 °C
Boiling point:
332.4±37.0 °C(Predicted)
Density 
2.209±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
form 
powder to crystal
color 
White to Yellow to Orange
InChI
InChI=1S/C6H2Br2S2/c7-3-1-9-6-4(8)2-10-5(3)6/h1-2H
InChIKey
DFMPVYZMICAYCS-UHFFFAOYSA-N
SMILES
C12C(Br)=CSC=1C(Br)=CS2
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Safety

HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D3679
Product name
3,6-Dibromothieno[3,2-b]thiophene
Purity
>98.0%(GC)
Packaging
200mg
Price
$41
Updated
2025/07/31
TCI Chemical
Product number
D3679
Product name
3,6-Dibromothieno[3,2-b]thiophene
Purity
>98.0%(GC)
Packaging
1g
Price
$182
Updated
2025/07/31
TRC
Product number
D426198
Product name
3,6-Dibromothieno[3,2-b]thiophene
Packaging
50mg
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD62226
Product name
3,6-Dibromothieno[3,2-b]thiophene
Packaging
50mg
Price
$46
Updated
2021/12/16
Apolloscientific
Product number
OR480723
Product name
3,6-Dibromothieno[3,2-b]thiophene
Purity
98%
Packaging
1g
Price
$77
Updated
2021/12/16
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3,6-DIBROMOTHIENO[3,2-B]THIOPHENE Chemical Properties,Usage,Production

Uses

3,6-Dibromothiophene[3,2-B]thiophene is used as a pharmaceutical and electronic intermediate.

Application

3,6-Dibromothiophene[3,2-B]thiophene is an organic synthesis intermediate and a pharmaceutical intermediate, mainly used in laboratory research and development and chemical and pharmaceutical synthesis processes.

Synthesis

124638-53-5

392662-65-6

The general procedure for the synthesis of 3,6-dibromothieno[3,2-b]thiophene from tetrabromothieno[3,2-B]thiophene was carried out as follows: tetrabromothieno[3,2-B]thiophene (9.12 g, 20 mmol), acetic acid (500 ml), and toluene (200 ml) were added to the reactor, followed by zinc powder (2.62 g, 40 mmol). The reaction mixture was filtered and the filtrate was concentrated to give the intermediate 3,6-dibromothieno[3,2-b]thiophene (5.36 g, 90% yield). After completion of the reaction, the synthesis of intermediate C-28-2 was carried out.

References

[1] Patent: CN107056798, 2017, A. Location in patent: Paragraph 0065; 0066; 0067
[2] Patent: WO2016/92065, 2016, A1. Location in patent: Page/Page column 21; 22
[3] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 22, p. 3465 - 3470
[4] Patent: CN103172646, 2016, B. Location in patent: Paragraph 0114-0116
[5] Chemical Communications, 2005, # 9, p. 1161 - 1163

3,6-DIBROMOTHIENO[3,2-B]THIOPHENE Preparation Products And Raw materials

Raw materials

Preparation Products

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3,6-DIBROMOTHIENO[3,2-B]THIOPHENE Suppliers

AbaChemScene
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732-484-9848
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United States
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Matrix Scientific
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View Lastest Price from 3,6-DIBROMOTHIENO[3,2-B]THIOPHENE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
3,6-DIBROMOTHIENO[3,2-B]THIOPHENE 392662-65-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
10MT
Release date
2025-09-11
Henan Fengda Chemical Co., Ltd
Product
3,6-DIBROMOTHIENO[3,2-B]THIOPHENE 392662-65-6
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-23
Zhuozhou Wenxi import and Export Co., Ltd
Product
3,6-dibromo-thieno[3,2-b]thiophene 392662-65-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10