METHYL 3-HYDROXY-2-NITROBENZOATE
- Product Name
- METHYL 3-HYDROXY-2-NITROBENZOATE
- CAS No.
- 89942-77-8
- Chemical Name
- METHYL 3-HYDROXY-2-NITROBENZOATE
- Synonyms
- METHYL 3-HYDROXY-2-NITROBENZOATE;3-Hydroxy-2-nitro-benzoic acid methyl ester;Benzoic acid, 3-hydroxy-2-nitro-, methyl ester;3-hydroxy-2-nitro-Benzoic acid methyl ester (6CI 7CI 9CI ACI);Benzoic acid, 3-hydroxy-2-nitro-, methyl ester (6CI, 7CI, 9CI, ACI);3-(Methoxycarbonyl)-2-nitrophenol, 2-Hydroxy-6-(methoxycarbonyl)nitrobenzene
- CBNumber
- CB71484259
- Molecular Formula
- C8H7NO5
- Formula Weight
- 197.14
- MOL File
- 89942-77-8.mol
METHYL 3-HYDROXY-2-NITROBENZOATE Property
- Melting point:
- 108-110℃
- Boiling point:
- 310.0±22.0 °C(Predicted)
- Density
- 1.432±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- solid
- pka
- 6.38±0.10(Predicted)
- color
- Off white
- InChI
- InChI=1S/C8H7NO5/c1-14-8(11)5-3-2-4-6(10)7(5)9(12)13/h2-4,10H,1H3
- InChIKey
- FHCNMPYMCKHBTK-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=CC(O)=C1[N+]([O-])=O
Safety
- HS Code
- 2918290090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H227Combustible liquid
H290May be corrosive to metals
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P234Keep only in original container.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P363Wash contaminated clothing before reuse.
P370+P378In case of fire: Use … for extinction.
P390Absorb spillage to prevent material damage.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
P406Store in corrosive resistant/… container with a resistant inner liner.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- M323383
- Product name
- Methyl3-hydroxy-2-nitrobenzoate
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- M323383
- Product name
- Methyl3-hydroxy-2-nitrobenzoate
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 4654-1-Y2
- Product name
- Methyl 3-hydroxy-2-nitrobenzoate
- Packaging
- 1g
- Price
- $130
- Updated
- 2021/12/16
- Product number
- 4654-1-Y2
- Product name
- Methyl 3-hydroxy-2-nitrobenzoate
- Packaging
- 250mg
- Price
- $40
- Updated
- 2021/12/16
- Product number
- 116393
- Product name
- Methyl 3-hydroxy-2-nitrobenzoate
- Purity
- >97%
- Packaging
- 5g
- Price
- $212
- Updated
- 2021/12/16
METHYL 3-HYDROXY-2-NITROBENZOATE Chemical Properties,Usage,Production
Synthesis
602-00-6
89942-77-8
Sulfoxide chloride (SOCl2, 0.6 mL) was slowly added dropwise to anhydrous methanol (MeOH, 10 mL) at 0 °C. The reaction mixture was stirred continuously for 0.5 h at this temperature. Subsequently, 3-hydroxy-2-nitrobenzoic acid (0.6 g, 3.2 mmol) was added to the mixture. The reaction system was heated to reflux and maintained for 4 hours. The progress of the reaction was monitored by thin layer chromatography (TLC, unfolding agent ratio of petroleum ether: ethyl acetate = 1:1) to confirm the completion of the reaction. After completion of the reaction, the mixture was concentrated under vacuum to afford the target product methyl 2-nitro-3-hydroxybenzoate (0.63 g, 100% yield) as a brown solid.
References
[1] Patent: WO2007/125405, 2007, A2. Location in patent: Page/Page column 24; 72-73
[2] Nippon Kagaku Zasshi, 1953, vol. 74, p. 251
[3] Chem.Abstr., 1954, p. 3959
[4] Patent: US2002/52397, 2002, A1
[5] Patent: US5756510, 1998, A
METHYL 3-HYDROXY-2-NITROBENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from METHYL 3-HYDROXY-2-NITROBENZOATE manufacturers
- Product
- methyl 3-hydroxy-2-nitrobenzoate 89942-77-8
- Price
- US $0.00/kg
- Min. Order
- 10kg
- Purity
- 99%
- Supply Ability
- 10 tons
- Release date
- 2025-05-11
- Product
- METHYL 3-HYDROXY-2-NITROBENZOATE 89942-77-8
- Price
- US $0.01/KG
- Min. Order
- 1KG
- Purity
- 98%; 99%
- Supply Ability
- 500g； 1kg; 25kg
- Release date
- 2020-01-10
- Product
- METHYL 3-HYDROXY-2-NITROBENZOATE 89942-77-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2019-12-25