ChemicalBook > CAS DataBase List > 8-bromo-1,4-dioxaspiro[4.5]decane

8-bromo-1,4-dioxaspiro[4.5]decane

Product Name
8-bromo-1,4-dioxaspiro[4.5]decane
CAS No.
68278-51-3
Chemical Name
8-bromo-1,4-dioxaspiro[4.5]decane
Synonyms
8-bromo-1,4-dioxaspiro[4.5]decane;1,4-Dioxaspiro[4.5]decane, 8-bromo-
CBNumber
CB71560380
Molecular Formula
C8H13BrO2
Formula Weight
221.09
MOL File
68278-51-3.mol
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8-bromo-1,4-dioxaspiro[4.5]decane Property

Boiling point:
89-90 °C(Press: 5 Torr)
Density 
1.46±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
InChI
InChI=1S/C8H13BrO2/c9-7-1-3-8(4-2-7)10-5-6-11-8/h7H,1-6H2
InChIKey
JCWBPQVTECHCIP-UHFFFAOYSA-N
SMILES
O1C2(CCC(Br)CC2)OCC1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B994040
Product name
8-bromo-1,4-dioxaspiro[4.5]decane
Packaging
50mg
Price
$110
Updated
2021/12/16
ChemScene
Product number
CS-0049964
Product name
8-Bromo-1,4-dioxaspiro[4.5]decane
Packaging
100mg
Price
$135
Updated
2021/12/16
ChemScene
Product number
CS-0049964
Product name
8-Bromo-1,4-dioxaspiro[4.5]decane
Packaging
1g
Price
$450
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0044483
Product name
8-BROMO-1,4-DIOXASPIRO[4.5]DECANE
Purity
95.00%
Packaging
5MG
Price
$501.68
Updated
2021/12/16
SynQuest Laboratories
Product number
2H10-9-14
Product name
8-Bromo-1,4-dioxaspiro[4.5]decane
Packaging
250mg
Price
$595
Updated
2021/12/16
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8-bromo-1,4-dioxaspiro[4.5]decane Chemical Properties,Usage,Production

Synthesis

A magnetically stirred 1,4-dioxaspiro[4.5]decan-8-ol solution in dry CH2Cl2 was treated with carbon tetrabromide, and the resulting mixture cooled to 0 °C. Triphenylphosphine was added, and the stirring continued at 0 °C under a nitrogen atmosphere for 5 h. After that, H2O and CH2Cl2 were added to the reaction mixture, the organic phase separated, and the aqueous phase extracted with CH2Cl2 (1 x). The combined organic fractions were dried, filtered, and concentrated under reduced pressure. The ensuing residue was subjected to flash chromatography to afford 8-bromo-1,4-dioxaspiro[4.5]decane as a colorless oil.

8-bromo-1,4-dioxaspiro[4.5]decane Preparation Products And Raw materials

Raw materials

Preparation Products

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68278-51-3, 8-bromo-1,4-dioxaspiro[4.5]decaneRelated Search:


  • 8-bromo-1,4-dioxaspiro[4.5]decane
  • 1,4-Dioxaspiro[4.5]decane, 8-bromo-
  • 68278-51-3