ChemicalBook > CAS DataBase List > ETHYL 1-METHYL-3-PHENYL-1H-PYRAZOLE-5-CARBOXYLATE

ETHYL 1-METHYL-3-PHENYL-1H-PYRAZOLE-5-CARBOXYLATE

Product Name
ETHYL 1-METHYL-3-PHENYL-1H-PYRAZOLE-5-CARBOXYLATE
CAS No.
10250-63-2
Chemical Name
ETHYL 1-METHYL-3-PHENYL-1H-PYRAZOLE-5-CARBOXYLATE
Synonyms
SALOR-INT L201367-1EA;1H-Pyrazole-5-carboxylic acid, 1;Ethyl 1-Methyl-3-phenylpyrazole-5-carboxylate;ETHYL 1-METHYL-3-PHENYL-1H-PYRAZOLE-5-CARBOXYLATE;Ethyl 1-methyl-3-phenyl-1H-pyrazole-5-carboxylate 97%;1H-Pyrazole-5-carboxylic acid, 1-methyl-3-phenyl-, ethyl ester;JR-13855, Ethyl 1-methyl-3-phenyl-1H-pyrazole-5-carboxylate, 95%;5-(Ethoxycarbonyl)-1-methyl-3-phenyl-1H-pyrazole, 1-[5-(Ethoxycarbonyl)-1-methyl-1H-pyrazol-3-yl]benzene
CBNumber
CB7156353
Molecular Formula
C13H14N2O2
Formula Weight
230.26
MOL File
10250-63-2.mol
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ETHYL 1-METHYL-3-PHENYL-1H-PYRAZOLE-5-CARBOXYLATE Property

Melting point:
27 °C
Boiling point:
380.6±30.0 °C(Predicted)
Density 
1.13±0.1 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
0.04±0.10(Predicted)
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Safety

Hazard Note 
Harmful
HS Code 
2933199090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
E929203
Product name
Ethyl1-Methyl-3-phenylpyrazole-5-carboxylate
Packaging
500mg
Price
$75
Updated
2021/12/16
Usbiological
Product number
448668
Product name
Ethyl 1-Methyl-3-phenylpyrazole-5-carboxylate
Packaging
100mg
Price
$305
Updated
2021/12/16
Apolloscientific
Product number
OR9786
Product name
Ethyl1-methyl-3-phenyl-1H-pyrazole-5-carboxylate
Purity
95+%
Packaging
1g
Price
$56
Updated
2021/12/16
SynQuest Laboratories
Product number
4H23-1-81
Product name
Ethyl 1-methyl-3-phenyl-1H-pyrazole-5-carboxylate
Purity
95.0%
Packaging
1g
Price
$90
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
COR0003866
Product name
ETHYL 1-METHYL-3-PHENYL-1H-PYRAZOLE-5-CARBOXYLATE
Purity
95.00%
Packaging
1G
Price
$203.7
Updated
2021/12/16
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ETHYL 1-METHYL-3-PHENYL-1H-PYRAZOLE-5-CARBOXYLATE Chemical Properties,Usage,Production

Synthesis

6296-54-4

302-15-8

10250-63-2

To a solution of ethyl 2,4-dioxo-4-phenylbutyrate (1.0 g, 4.5 mmol), methylhydrazine sulfate (1.0 g, 6.8 mmol) and sodium hydroxide (0.5 g, 13.6 mmol) in ethanol (50 mL) was added the reaction mixture. The reaction mixture was stirred at 70 °C overnight. After completion of the reaction, the reaction was quenched with ice water (100 mL), extracted with ethyl acetate, the organic phase was washed with brine, dried over anhydrous sodium sulfate, filtered and concentrated to give the crude product. The crude product was purified by silica gel column chromatography eluting with appropriate eluent to give ethyl 1-methyl-3-phenyl-1H-pyrazole-5-carboxylate (247.5 mg, 23.9%). Mass spectrum (ESI) m/z: 231.1 [M + 1].

References

[1] Patent: US2018/271846, 2018, A1. Location in patent: Paragraph 0176; 0178; 0179

ETHYL 1-METHYL-3-PHENYL-1H-PYRAZOLE-5-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from ETHYL 1-METHYL-3-PHENYL-1H-PYRAZOLE-5-CARBOXYLATE manufacturers

Career Henan Chemica Co
Product
ETHYL 1-METHYL-3-PHENYL-1H-PYRAZOLE-5-CARBOXYLATE 10250-63-2
Price
US $0.37/KG
Min. Order
1KG
Purity
99%
Supply Ability
10kg,100kg
Release date
2020-11-09