2-Bromo-4-cyanobenzyl alcohol

Product Name: 2-Bromo-4-cyanobenzyl alcohol
CAS No.: 90110-98-8
Chemical Name: 2-Bromo-4-cyanobenzyl alcohol
Synonyms: 2-Bromo-4-cyanobenzyl alcohol;3-BroMo-4-(hydroxyMethyl)benzonitrile;Benzonitrile, 3-broMo-4-(hydroxyMethyl)-
CBNumber: CB71563644
Molecular Formula: C8H6BrNO
Formula Weight: 212.04
MOL File: 90110-98-8.mol

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2-Bromo-4-cyanobenzyl alcohol Property

Boiling point:: 331.9±32.0 °C(Predicted)
Density: 1.67±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 13.57±0.10(Predicted)
Appearance: White to yellow Solid

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Safety

HS Code: 2926907090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

ChemScene

Product number: CS-D0578
Product name: 2-Bromo-4-cyanobenzylalcohol
Purity: >97.0%
Packaging: 1g
Price: $99
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB139276
Product name: 3-Bromo-4-(hydroxymethyl)benzonitrile
Packaging: 250mg
Price: $100
Updated: 2021/12/16

AK Scientific

Product number: V8884
Product name: 3-Bromo-4-(hydroxymethyl)benzonitrile
Packaging: 250mg
Price: $116
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB139276
Product name: 3-Bromo-4-(hydroxymethyl)benzonitrile
Packaging: 500mg
Price: $165
Updated: 2021/12/16

ChemScene

Product number: CS-D0578
Product name: 2-Bromo-4-cyanobenzylalcohol
Purity: >97.0%
Packaging: 5g
Price: $370
Updated: 2021/12/16

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2-Bromo-4-cyanobenzyl alcohol Chemical Properties,Usage,Production

Synthesis

89891-69-0

90110-98-8

General procedure for the synthesis of 3-bromo-4-(hydroxymethyl)benzonitrile from 3-bromo-4-formylbenzonitrile: 3-bromo-4-formylbenzonitrile (1.0 g, 4.8 mmol) was dissolved in methanol (30 mL) and the solution was cooled to 0 °C. Sodium borohydride (180 mg, 4.8 mmol) was added in batches under stirring. When the addition was complete, the reaction mixture was slowly warmed to room temperature and stirring was continued at this temperature for 1 hour. Upon completion of the reaction, the reaction was quenched with 1N hydrochloric acid solution, followed by concentration under reduced pressure to remove the solvent. The residue was extracted with ethyl acetate (25 mL x 3). The organic phases were combined, washed with saturated saline (20 mL), dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to afford the target product 3-bromo-4-(hydroxymethyl)benzonitrile as a white solid (1.0 g, 99% yield). The structure of the product was confirmed by NMR hydrogen spectroscopy (300 MHz, CDCl3) and liquid chromatography-mass spectrometry (LC-MS): 1H NMR (300 MHz, CDCl3) δ 7.82 (s, 1H), 7.49-7.71 (m, 2H), 4.75 (s, 2H); LC-MS m/z 212 [M+1]+.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 24, p. 7317 - 7322
[2] Patent: WO2011/22337, 2011, A1. Location in patent: Page/Page column 102
[3] Patent: WO2010/45503, 2010, A1. Location in patent: Page/Page column 134
[4] Patent: WO2013/36869, 2013, A2. Location in patent: Page/Page column 226

2-Bromo-4-cyanobenzyl alcohol Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromo-4-cyanobenzyl alcohol Suppliers

China 61 India 1 United Kingdom 1 United States 5 Global 68

PharmaBlock Sciences (Nanjing),Inc.

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View Lastest Price from 2-Bromo-4-cyanobenzyl alcohol manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 3-Bromo-4-(hydroxymethyl)benzonitrile 90110-98-8
Price: US $2.20-8.80/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 50kg
Release date: 2025-06-25

Henan Aochuang Chemical Co.,Ltd.

Product: 2-Bromo-4-cyanobenzyl alcohol 90110-98-8
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-18

90110-98-8, 2-Bromo-4-cyanobenzyl alcoholRelated Search:

2-Bromo-4-cyanobenzyl alcohol 3-Bromo-4-methylbenzonitrile

2-Bromo-4-cyanobenzyl alcohol

Benzonitrile, 3-broMo-4-(hydroxyMethyl)-

3-BroMo-4-(hydroxyMethyl)benzonitrile

90110-98-8