ChemicalBook > CAS DataBase List > (R,R)-(+)-HYDROBENZOIN

(R,R)-(+)-HYDROBENZOIN

Product Name: (R,R)-(+)-HYDROBENZOIN
CAS No.: 52340-78-0
Chemical Name: (R,R)-(+)-HYDROBENZOIN
Synonyms: (1R,2R)-1,2-Diphenylethane-1,2-diol;(R,R)-(+)-HYDROBENZOIN;(R,R)-(+)-Hydrobenzoine;(1R,2R)-(+)-HYDROBENZOIN;(αR,βR)-Bibenzyl-α,β-diol;(R,R)-(+)-Hydrobenzoin>(R,R)-(+)-Hydrobenzoin, 98+%;(R,R)-(+)-Hydrobenzoin;(R,R)-(+)-1,2-DIPHENYLETHANEDIOL;(R,R)-1,2-DIPHENYL-1,2-ETHANEDIOL
CBNumber: CB7160273
Molecular Formula: C14H14O2
Formula Weight: 214.26
MOL File: 52340-78-0.mol

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(R,R)-(+)-HYDROBENZOIN Property

Melting point:: 146-149 °C(lit.)
Boiling point:: 314.4°C (rough estimate)
Density: 1.0781 (rough estimate)
refractive index: 95 ° (C=1, CHCl3)
storage temp.: Sealed in dry,Room Temperature
solubility: Soluble in DMSO
form: Crystalline Powder or Crystals
pka: 13.38±0.20(Predicted)
color: White to beige or light brown
optical activity: [α]28/D +93°, c = 2.5 in ethanol
Merck: 14,4777
BRN: 2050815
InChI: InChI=1S/C14H14O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-16H/t13-,14-/m1/s1
InChIKey: IHPDTPWNFBQHEB-ZIAGYGMSSA-N
SMILES: [C@H](C1=CC=CC=C1)(O)[C@@H](C1=CC=CC=C1)O
CAS DataBase Reference: 52340-78-0(CAS DataBase Reference)

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Safety

Safety Statements: 22-24/25
WGK Germany: 3
F: 10
HS Code: 29062990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 256277
Product name: (R,R)-(+)-Hydrobenzoin
Purity: 99%, optical purity ee: 99% (HPLC)
Packaging: 5g
Price: $127
Updated: 2023/06/20

Sigma-Aldrich

Product number: 256277
Product name: (R,R)-(+)-Hydrobenzoin
Purity: 99%, optical purity ee: 99% (HPLC)
Packaging: 25g
Price: $274
Updated: 2023/06/20

TCI Chemical

Product number: H0818
Product name: (R,R)-(+)-Hydrobenzoin
Purity: >99.0%(GC)
Packaging: 5g
Price: $80
Updated: 2025/07/31

TCI Chemical

Product number: H0818
Product name: (R,R)-(+)-Hydrobenzoin
Purity: >99.0%(GC)
Packaging: 25g
Price: $267
Updated: 2025/07/31

TRC

Product number: A585190
Product name: (1R,2R)-1,2-diphenylethane-1,2-diol
Packaging: 500mg
Price: $60
Updated: 2021/12/16

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(R,R)-(+)-HYDROBENZOIN Chemical Properties,Usage,Production

Chemical Properties

white to beige or light brown crystalline powder

Uses

(R,R)-(+)-Hydrobenzoin may be used in the oxyselenenylation step in the multi-step synthesis of cyclopentitols and aminocyclopentitols from cyclopentene. It may also be used as a ligand for the asymmetric addition of diethylzinc to aldehydes in the presence or absence of titanium tetra-isopropoxide to form (R)- or (S)-form of the corresponding secondary alcohol, respectively.

Definition

ChEBI: (R,R)-hydrobenzoin is a hydrobenzoin.

General Description

(R,R)-(+)-Hydrobenzoin is a chiral 1,2-diol useful as a chiral reagent, building block, ligand or auxiliary in asymmetric synthesis.

IC 50

Human Endogenous Metabolite

(R,R)-(+)-HYDROBENZOIN Preparation Products And Raw materials

Raw materials

(DHQ)2PHAL Potassium osmate(VI) dihydrate TRANS-STILBENE tert-Butanol Tiron 4-Methylmorpholine N-oxide monohydrate

Preparation Products

Phenylacetic acid

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View Lastest Price from (R,R)-(+)-HYDROBENZOIN manufacturers

Career Henan Chemical Co

Product: (R,R)-(+)-HYDROBENZOIN 52340-78-0
Price: US $1.00/g
Min. Order: 1g
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-10

52340-78-0, (R,R)-(+)-HYDROBENZOINRelated Search:

ROCAGLAMIDE DIMETHYLCYANAMIDE Ammonium bicarbonate (1R, 2S)-DIPHENYL-1, 2-ETHANEDIOL MESO-HYDROBENZOIN,HYDROBENZOIN MESO,MESO-HYDROBENZOIN,meso-Hydrobenzoin,99%,MESO-HYDROBENZOIN / 1,2-DIPHENYL-1,2-ETHANEDIOL Benzopinacole (R)-(+)-2-HYDROXY-1,2,2-TRIPHENYLETHYL ACETATE (R)-(+)-1,1,2-TRIPHENYL-1,2-ETHANEDIOL (R,R)-(+)-HYDROBENZOIN RAC HYDROBENZOIN,(n)-hydrobenzoin,Hydrobenzoin (racemic),(+/-)-HYDROBENZOIN,HYDROBENZOIN Tetrahexylammonium hydrogensulphate (S,S)-(-)-HYDROBENZOIN rac trans-10,11-Dihydro-10,11-dihydroxy Carbamazepine TRANS-9,10-DIHYDROXY-9,10-DIHYDROPHENANTHRENE 1,1,2,2-TETRAKIS(4-METHYLPHENYL)-1,2-ETHANEDIOL (R,R)-(+)-1,2-DI(1-NAPHTHYL)-1,2-ETHANEDIOL 1,1,2,2-TETRAKIS(4-METHOXYPHENYL)-1,2-ETHANEDIOL HYDROBENZOIN / 1,2-DIPHENYL-1,2-ETHANEDIOL HPL

(1R,2R)-(+)-HYDROBENZOIN

(1R,2R)-(+)-1,2-DIPHENYL-1,2-ETHANEDIOL

(R,R)-(+)-HYDROBENZOIN

(R,R)-(+)-1,2-DIPHENYL-1,2-ETHANEDIOL

(R,R)-1,2-DIPHENYL-1,2-ETHANEDIOL

(R,R)-(+)-1,2-DIPHENYLETHANEDIOL

(R,R)-1,2-DIPHENYL-ETHYLENE GLYCOL

(R,R)-(+)-HYDROBENZOIN, 99% (99% EE/HPL&

(R,R)-(+)-Hydrobenzoine

(R,R)-(+)-1,2-Diphenyl-1,2-ethanediol, 98+%

(1R,2R)-DIPHENYL-1,2-ETHANEDIOL / (R,R)-(+)-HYDROBENZOIN

(R,R)-(+)-Hydrobenzoin, 98+%

(R,R)-1,2-Diphenyl-1,2-ethanediol, (R,R)-1,2-Diphenylethylene glycol

(1R,2R)-1,2-Diphenylethylene glycol

(αR,βR)-Bibenzyl-α,β-diol

(R,R)-(+)-Hydrobenzoin

(R,R)-(+)-1,2-Diphenyl-1,2-ethanediol, 98+% 500MG

(1R,2R)-1,2-Diphenylethane-1,2-diol

1,2-Ethanediol, 1,2-diphenyl-, (1R,2R)-

(R,R)-(+)-Hydrobenzoin 99%, optical purity ee: 99% (HPLC)

(R,R)-(+)-Hydrobenzoin&gt

(R,R)-(+)-Hydrobenzoin

52340-78-0

C6H5CHOHCHOHC6H5

Polyols

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Asymmetric Synthesis