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ChemicalBook > CAS DataBase List > Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate

Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate

Applications Applications Guidelines for use Physical properties Handling
Product Name
Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate
CAS No.
52829-07-9
Chemical Name
Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate
Synonyms
TINUVIN 770;BIS(2,2,6,6-TETRAMETHYL-4-PIPERIDYL) SEBACATE;Bis(2,2,6,6-tetraMethylpiperidin-4-yl) decanedioate;t770;ls770;hals770;UV Absorber 770;Bis(2,2,6,6,-tetramethyl-4-piperidyl)sebaceate;BTPS;hals1
CBNumber
CB7163582
Molecular Formula
C28H52N2O4
Formula Weight
480.72
MOL File
52829-07-9.mol
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Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate Property

Melting point:
82-85 °C(lit.)
Boiling point:
499.8±45.0 °C(Predicted)
Density 
1.01±0.1 g/cm3(Predicted)
vapor pressure 
0Pa at 20℃
Flash point:
421 °F
storage temp. 
2-30°C
solubility 
acetone: 19 % (w/w) at 20 °C
pka
10.49±0.10(Predicted)
form 
powder to crystal
color 
White to Almost white
Water Solubility 
18.8mg/L at 23℃
InChI
InChI=1S/C28H52N2O4/c1-25(2)17-21(18-26(3,4)29-25)33-23(31)15-13-11-9-10-12-14-16-24(32)34-22-19-27(5,6)30-28(7,8)20-22/h21-22,29-30H,9-20H2,1-8H3
InChIKey
XITRBUPOXXBIJN-UHFFFAOYSA-N
SMILES
C(OC1CC(C)(C)NC(C)(C)C1)(=O)CCCCCCCCC(OC1CC(C)(C)NC(C)(C)C1)=O
LogP
0.35 at 25℃
CAS DataBase Reference
52829-07-9(CAS DataBase Reference)
EPA Substance Registry System
Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate (52829-07-9)
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Safety

Hazard Codes 
T,N,Xi
Risk Statements 
23-37/38-41-51/53-36
Safety Statements 
26-39-45-61
RIDADR 
UN 2811 6.1/PG 2
WGK Germany 
2
RTECS 
HD8315000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H318Causes serious eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
535834
Product name
Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate
Packaging
100g
Price
$74.5
Updated
2024/03/01
TCI Chemical
Product number
S0448
Product name
Bis(2,2,6,6-tetramethyl-4-piperidyl) Sebacate
Purity
>98.0%(GC)
Packaging
5g
Price
$16
Updated
2024/03/01
TCI Chemical
Product number
S0448
Product name
Bis(2,2,6,6-tetramethyl-4-piperidyl) Sebacate
Purity
>98.0%(GC)
Packaging
25g
Price
$24
Updated
2024/03/01
Alfa Aesar
Product number
H54025
Product name
Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate, 98%
Packaging
100g
Price
$57.9
Updated
2024/03/01
TCI Chemical
Product number
S0448
Product name
Bis(2,2,6,6-tetramethyl-4-piperidyl) Sebacate
Purity
>98.0%(GC)
Packaging
250g
Price
$108
Updated
2024/03/01
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Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate Chemical Properties,Usage,Production

Applications

Light Stabilizer 770  is recommended to be used in polypropylene, impact modified PP (TPO), EPDM, polystyrene, impact polystyrene, ABS, SAN, ASA, polyurethanes, and is also effective in polyamides and polyacetals.

Applications

Light Stabilizer 770 (Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate) is a low molecular weight hindered amine light stabilizer (HALS) for applications demanding particularly high light stability. The benefit of using Light Stabilizer 770 is the high light-stabilizing performance, particularly in PP thick sections to protect the surface. It has broad compatibility and can be easily dispersed. Compared to UV absorbers, the effectiveness of HALS, like Light Stabilizer 770, is not dependent on the polymer’s thickness. For this reason, the use of Light Stabilizer 770 also provides good light stability in articles with higher specific surface, e. g., films and tapes.

Guidelines for use

The recommended concentrations range between 0.1 % and 1.0 %, depending on the substrate, processing conditions and application. The optimum level is substrate and application specific. Extensive performance data of Light Stabilizer 770 in various substrates and for various applications is available upon request.

Physical properties

Handling

In accordance with good industrial practice, handle with care and avoid unnecessary personal contact. Avoid continuous or repetitive breathing of dust. Use only with adequate ventilation. Avoid contact with eyes. Avoid release to the environment. Avoid dust formation and ignition sources.

Chemical Properties

White solid

Uses

T770 (Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate) can be used as a hindered amine UV stabilizer in plastic materials. It can be used in the manufacturing and packaging of pharmaceutical products. Titanium oxide(TiO2)/T770 may be used in amine induced light stabilizers in the synthesis of recyclable water-based polyurethane with poly(oxytetramethylene)glycol (PTMG).

General Description

Bis(2,2,6,6-tetramethyl-4-piperidyl) (T770) sebacate is a low molecular weight ultra violet (UV) hindered amine light stabilizer (HALS) made up of nitroxyl radicals. It acts as a heat controller that can react with phenolic antioxidants incorporated in polymers.

Flammability and Explosibility

Not classified

Biological Activity

Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate(BTMPS; Tinuvin 770) is a sterically hindered amine light and radiation stabilizer produced by Ciba-Geigy, widely used in plastics, that inhibits nicotinic acetylcholine receptors expressed in Xenopus oocytes in a use-dependent manner. BTMPS is a symmetrical conjugate of methylated piperidines that are potent inhibitors on their own, but the kinetics of inhibition and recovery are faster than BTMPS. For neuronal nicotinic receptor subunit combinations, the time constant for recovery from inhibition by BTMPS is approximately 1 to 4 h. Muscle-type receptors (α 1-, β 1-γ, and δ subunits) are also inhibited by BTMPS, but control responses are fully restored after a 5 min washout. Hybrids of muscle and neuronal subunits containing neuronal β subunits (α 1-, β 2-, γ, and δ and α-1-, β 4-, and γ-δ) blocked in a more irreversible manner than normal muscle-type receptors, suggesting an interaction between BTMPS and neuronal acetylcholine receptor β subunits. Glutamate receptors were not inhibited by BTMPS. Exposure to agonist solutions from certain plastic syringes that release BTMPS also resulted in a use-dependent inhibition of nicotinic receptors.[1]

References

[1] R L PAPKE; S F H; A G Craig. Inhibition of nicotinic acetylcholine receptors by bis (2,2,6,6-tetramethyl- 4-piperidinyl) sebacate (Tinuvin 770), an additive to medical plastics.[J]. Journal of Pharmacology and Experimental Therapeutics, 1994, 268 2: 718-726.

Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate Preparation Products And Raw materials

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Preparation Products

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View Lastest Price from Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate manufacturers

Dorne Chemical Technology co. LTD
Product
Light Stabilizer 770 52829-07-9
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
100kg
Release date
2024-05-04
Dorne Chemical Technology co. LTD
Product
Light Stabilizer 770(LS-770) 52829-07-9
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
100kg
Release date
2024-06-15
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
UV770 52829-07-9
Price
US $30.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-30

52829-07-9, Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacateRelated Search:


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