CYCLOPROPYL PHENYL SULFIDE
- Product Name
- CYCLOPROPYL PHENYL SULFIDE
- CAS No.
- 14633-54-6
- Chemical Name
- CYCLOPROPYL PHENYL SULFIDE
- Synonyms
- CYCLOPROPYL PHENYL S;Cyclopropylthiobenzene;Phenylthiocyclopropane;cyclopropyl(phenyl)sulfane;CYCLOPROPYL PHENYL SULFIDE;1-(Phenylthio)cyclopropane;Benzene, (cyclopropylthio)-;CYCLOPROPYL PHENYL SULPHIDE;CyclopropylPhenylSulfide>(Cyclopropylsulfanyl)benzene
- CBNumber
- CB7164145
- Molecular Formula
- C9H10S
- Formula Weight
- 150.24
- MOL File
- 14633-54-6.mol
CYCLOPROPYL PHENYL SULFIDE Property
- Boiling point:
- 62-63 °C/1 mmHg (lit.)
- Density
- 1.045 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.581(lit.)
- Flash point:
- 197 °F
- form
- clear liquid
- color
- Colorless to Light yellow to Light orange
- BRN
- 2075701
- CAS DataBase Reference
- 14633-54-6(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- RIDADR
- UN 2810 6.1/PG 3
- WGK Germany
- 3
- HazardClass
- 9
- HS Code
- 29309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 227242
- Product name
- Cyclopropyl phenyl sulfide
- Purity
- 99%
- Packaging
- 5g
- Price
- $78
- Updated
- 2023/01/07
- Product number
- 227242
- Product name
- Cyclopropyl phenyl sulfide
- Purity
- 99%
- Packaging
- 25g
- Price
- $172
- Updated
- 2023/01/07
- Product number
- C1014
- Product name
- Cyclopropyl Phenyl Sulfide
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $66
- Updated
- 2024/03/01
- Product number
- C1014
- Product name
- Cyclopropyl Phenyl Sulfide
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $214
- Updated
- 2024/03/01
- Product number
- L12321
- Product name
- Cyclopropyl phenyl sulfide, 98+%
- Packaging
- 1g
- Price
- $24.65
- Updated
- 2024/03/01
CYCLOPROPYL PHENYL SULFIDE Chemical Properties,Usage,Production
Chemical Properties
CLEAR YELLOWISH LIQUID
Uses
Cyclopropyl phenyl sulfide was used as a reagent in the conversion of a ketone into a spirocyclobutanone.
Synthesis Reference(s)
Synthetic Communications, 10, p. 311, 1980 DOI: 10.1080/00397918008062755
Synthesis
Phenylthiocyclopropane is easily prepared from 1-phenylthio-3-chloropropane (itself obtained on reaction of 1-bromo- 3-chloropropane and phenylthiolates) and Potassium Amide in liquid ammonia (eq 1).
1,3-Bis(phenylthio)propane reacts with n-Butyllithium in THF to produce Phenylthiocyclopropane on reaction with only 1 equiv n-Buli, or 1-lithio-1-phenylthiocyclopropane (2) if 2 equiv are used (eq 2).
Phenylthiocyclopropane has also been synthesized from 3-tributylstannylpropanal (available from tributylstannyllithium and Acrolein) and trimethylsilyl phenyl sulfide in the presence of Titanium(IV) Chloride as acid catalyst (eq 3), and on substitution of (i) Cyclopropyllithium with Diphenyl Disulfide (eq 4), (ii) cyclopropyl bromide with potassium benzenethiolate (eq 5) or (iii) 1,1-dibromocyclopropane, also with benzenethiolates, and by reduction of α- bromocyclopropyl phenyl sulfide with sodium methanethiolate (eq 6). In addition, cyclopropyl phenyl sulfoxide can be reduced to (1) in more than 70% yield with Chlorotrimethylstannane-benzenethiol (eq 7).
CYCLOPROPYL PHENYL SULFIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from CYCLOPROPYL PHENYL SULFIDE manufacturers
- Product
- CYCLOPROPYL PHENYL SULFIDE 14633-54-6
- Price
- US $34.00-1.20/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-08
- Product
- CYCLOPROPYL PHENYL SULFIDE 14633-54-6
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27