1,6-Dibromo-2-naphthol

Product Name: 1,6-Dibromo-2-naphthol
CAS No.: 16239-18-2
Chemical Name: 1,6-Dibromo-2-naphthol
Synonyms: AURORA 701;AKOS BBS-00008050;Dibromonaphthol,95%;1,6-dibromo-2-naphtho;Oc2ccc1cc(Br)ccc1c2Br;1,6-DIBROMO-2-NAPHTHOL;1,6-DIBRONO-2-NAPHTHOL;1,6-Dibromonaphthalen-2-ol;1,6-Dibromo-2-naphthalenol;1,6-Dibromo-2-naphthol,99%
CBNumber: CB7194023
Molecular Formula: C10H6Br2O
Formula Weight: 301.96
MOL File: 16239-18-2.mol

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1,6-Dibromo-2-naphthol Property

Melting point:: 105-107 °C(lit.)
Boiling point:: 368.5±22.0 °C(Predicted)
Density: 1.7523 (rough estimate)
refractive index: 1.5560 (estimate)
storage temp.: Sealed in dry,Room Temperature
pka: 6.94±0.50(Predicted)
form: Powder
color: Pink to purple or light brown
CAS DataBase Reference: 16239-18-2(CAS DataBase Reference)
EPA Substance Registry System: 1,6-Dibromo-2-naphthol (16239-18-2)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39-24/25
WGK Germany: 3
RTECS: QL3500000
HS Code: 29081990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical

Product number: D1872
Product name: 1,6-Dibromo-2-naphthol
Purity: >97.0%(GC)(T)
Packaging: 25g
Price: $104
Updated: 2025/07/31

TCI Chemical

Product number: D1872
Product name: 1,6-Dibromo-2-naphthol
Purity: >97.0%(GC)(T)
Packaging: 250g
Price: $589
Updated: 2025/07/31

TRC

Product number: B426268
Product name: 1,6-Dibromonaphthalen-2-ol
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK220579
Product name: 1,6-Dibromo-2-naphthol
Purity: 98%
Packaging: 25g
Price: $67
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD152664
Product name: 1,6-Dibromo-2-naphthol
Packaging: 50g
Price: $83
Updated: 2021/12/16

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1,6-Dibromo-2-naphthol Chemical Properties,Usage,Production

Chemical Properties

Pink to purple or light brown powder

Synthesis

15231-91-1

16239-18-2

General procedure for the synthesis of 1,6-dibromo-2-naphthol from 6-bromo-2-naphthol: 6-bromo-2-naphthol (500 mg, 2.242 mmol, 1.0 eq.) was reacted with N-bromosuccinimide (NBS, 558.7 mg, 3.319 mmol, 1.4 eq.) in acetone (4.4 mL) and 1 N HCl (22 μL) in a mixed solution of acetone (4.4 mL) and 1 N HCl (22 μL) at room temperature with stirring for 15 min. Upon completion of the reaction, ethyl acetate was added for extraction and the organic phase was washed three times with 1 N HCl to remove unreacted NBS and by-products. Subsequently, the organic phase was dried with anhydrous magnesium sulfate, the desiccant was removed by filtration, and the filtrate was concentrated under reduced pressure on a rotary evaporator to afford the target product 1,6-dibromo-2-naphthol in quantitative yield (677 mg). The product characterization data were as follows: molecular formula C10H6Br2O; molecular weight 300/302/304; 1H NMR (CDCl3, δ): 7.90 (d, J = 1.8 Hz, 1H), 7.87 (d, J = 8.8 Hz, 1H), 7.61 (d, J = 8.8 Hz, 1H), 7.59 (dd, J = 2.1 Hz, J = 9.1 Hz, 1H), 7.24 (d, J = 8.8 Hz, 1H); 13C NMR (CDCl3, δ): 177.5, 151.0, 131.0, 130.6, 130.1, 128.4, 128.3, 127.2, 118.0, 106.1; IR (cm-1): 3443, 1688, 1617, 1586 1382, 1209, 1183, 1130.

References

[1] Patent: US2010/204234, 2010, A1. Location in patent: Page/Page column 15
[2] RSC Advances, 2018, vol. 8, # 32, p. 17806 - 17812
[3] Synthetic Communications, 1996, vol. 26, # 13, p. 2597 - 2601
[4] Chemical Communications, 2018, vol. 54, # 39, p. 4935 - 4938

1,6-Dibromo-2-naphthol Preparation Products And Raw materials

Raw materials

1-Naphthol

Preparation Products

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1,6-Dibromo-2-naphthol Suppliers

Americas 1 Austria 1 Belgium 1 Canada 1 China 116 Europe 1 France 1 Germany 5 India 6 Japan 3 Russia 1 Switzerland 2 United Kingdom 10 United States 29 Global 178

Alchem Pharmtech,Inc.

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View Lastest Price from 1,6-Dibromo-2-naphthol manufacturers

Shenzhen Nexcon Pharmatechs Ltd.

Product: 1,6-Dibromo-2-naphthol 16239-18-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 2000
Release date: 2025-04-18

Career Henan Chemical Co

Product: 1,6-Dibromo-2-naphthol 16239-18-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2019-12-24

16239-18-2, 1,6-Dibromo-2-naphtholRelated Search:

(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL 1-Naphthol 1,3-Dibromo-5,5-dimethylhydantoin Phenmedipham 1,1'-Bi-2-naphthol Terbinafine Hydrochloride 2-Naphthol Terbinafine hydrochloride 2,4-DIBROMO-1-NAPHTHOL 1,6-DIBROMO-2-NAPHTHOL-3-CARBOXYLIC ACID 1,3-Dibromo-2-naphthol METHYL 4,7-DIBROMO-3-METHOXY-2-NAPHTHOATE 1,6-Dibromo-2-naphthol AURORA 2254 AKOS BBS-00007564 5,8-Dibromo-2-naphthol 2,4-DIBROMO-2-NAPHTHOL 2,6-DIBROMO-2-NAPHTHOL

AKOS BBS-00008050

1,6-dibromo-2-naphtho

AURORA 701

1,6-DIBROMO-2-NAPHTHOL

Dibromonaphthol,95%

1,6-DIBRONO-2-NAPHTHOL

1,6-Dibromo-2-hydroxynaphthalene

1,6-Dibromo-2-naphthalenol

1,6-Dibromonaphthalen-2-ol

2-Hydroxy-1,6-dibromonaphthalene

1,6-Dibromo-2-naphthol,99%

1,6-DibroMo-2-naphthol, 99% 25GR

2-Naphthalenol, 1,6-dibromo-

Oc2ccc1cc(Br)ccc1c2Br

16239-18-2

Br2C10H5OH

C10H6Br2O

ARYL HALIDE

Organic Building Blocks

Phenols

Oxygen Compounds

Building Blocks

API intermediates

Organic Building Blocks

Oxygen Compounds

Phenols

Intermediates of Dyes and Pigments