2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONE

Product Name: 2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONE
CAS No.: 16691-79-5
Chemical Name: 2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONE
Synonyms: bismethoxycarbonyldiphenylcyclopentadienone;2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONE;DIMETHYL 3,4-DIPHENYLCYCLOPENTADIENONE-2,5-DICARBOXYLATE;Dimethyl 2-oxo-4,5-diphenylcyclopenta-3,5-diene-1,3-dicarboxylate;3,4-DIPHENYLCYCLOPENTADIENONE-2,5-DICARBOXYLIC ACID DIMETHYL ESTER;2-oxo-4,5-diphenylcyclopenta-3,5-diene-1,3-dicarboxylic acid dimethyl ester;3,5-Cyclopentadiene-1,3-dicarboxylic acid, 2-oxo-4,5-diphenyl-, dimethyl ester;Dimethyl 3,4-Diphenylcyclopentadienone-2,5-dicarboxylate 3,4-Diphenylcyclopentadienone-2,5-dicarboxylic Acid Dimethyl Ester
CBNumber: CB7198203
Molecular Formula: C21H16O5
Formula Weight: 348.35
MOL File: 16691-79-5.mol

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2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONE Property

Melting point:: 175 °C
Boiling point:: 445.4±45.0 °C(Predicted)
Density: 1.302±0.06 g/cm3(Predicted)
form: powder to crystal
color: Light yellow to Brown

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Safety

HS Code: 2918.30.3000

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TCI Chemical

Product number: B1962
Product name: 2,5-Bis(methoxycarbonyl)-3,4-diphenylcyclopentadienone
Packaging: 1g
Price: $119
Updated: 2024/03/01

TCI Chemical

Product number: B1962
Product name: 2,5-Bis(methoxycarbonyl)-3,4-diphenylcyclopentadienone
Packaging: 5g
Price: $359
Updated: 2024/03/01

AK Scientific

Product number: 5347AL
Product name: 2,5-Bis(methoxycarbonyl)-3,4-diphenylcyclopentadienone
Packaging: 1g
Price: $283
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0008037
Product name: 2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONE
Purity: 95.00%
Packaging: 5MG
Price: $497.38
Updated: 2021/12/16

AK Scientific

Product number: 5347AL
Product name: 2,5-Bis(methoxycarbonyl)-3,4-diphenylcyclopentadienone
Packaging: 5g
Price: $795
Updated: 2021/12/16

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2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONE Chemical Properties,Usage,Production

Uses

2,5-Bis(methoxycarbonyl)-3,4-diphenylcyclopentadienone is used a reagent for cycloaddition reactions.

Preparation

Preparative Method of 2,5-Bis(methoxycarbonyl)-3,4-diphenylcyclopentadienone: equimolar amounts of benzil and dimethyl 2-propanone-1,3-dicarboxylate in MeOH or EtOH with OH- are allowed to react at 25 °C for 1 day to give the intermediate dimethyl 3,4-diphenyl-4- hydroxycyclopent-2-enone-2,5-dicarboxylate in 70-96% yield. Treatment of the intermediate with acid in benzene or in Ac₂O with heating gives the dienone in 98% yield containing 3% of the Diels-Alder dimer^[1-2].

References

1. Cookson, R. C.; Henstock, J. B.; Hudec, J.; Whitear, B. R. D. JCS(C) 1967, 1986.
2. White, D. M. JOC 1974, 39, 1951.

2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONE Suppliers

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16691-79-5, 2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONERelated Search:

Dicyclopentadiene METHYL SORBATE 2-METHYLENE-PENTANEDIOIC ACID DIMETHYL ESTER 2,3-DIPHENYL-1,3-BUTADIENE 1,3-Acetonedicarboxylic acid 2-N-PROPYL-2(E)-PENTENOICACID Dimethyl 1,3-acetonedicarboxylate 2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONE Sorbic acid TRANS,TRANSMUCONALDEHYDE trans,trans-Muconic acid 2,5-Dimethyl-3,4-diphenylcyclopentadienone 1,2,3,4-TETRAMETHYL-1,3-CYCLOPENTADIENE 5-METHOXY-3-OXOVALERIC ACID METHYL ESTER

bismethoxycarbonyldiphenylcyclopentadienone

DIMETHYL 3,4-DIPHENYLCYCLOPENTADIENONE-2,5-DICARBOXYLATE

2,5-BIS(METHOXYCARBONYL)-3,4-DIPHENYLCYCLOPENTADIENONE

3,4-DIPHENYLCYCLOPENTADIENONE-2,5-DICARBOXYLIC ACID DIMETHYL ESTER

Dimethyl 3,4-Diphenylcyclopentadienone-2,5-dicarboxylate 3,4-Diphenylcyclopentadienone-2,5-dicarboxylic Acid Dimethyl Ester

Dimethyl 2-oxo-4,5-diphenylcyclopenta-3,5-diene-1,3-dicarboxylate

2-oxo-4,5-diphenylcyclopenta-3,5-diene-1,3-dicarboxylic acid dimethyl ester

3,5-Cyclopentadiene-1,3-dicarboxylic acid, 2-oxo-4,5-diphenyl-, dimethyl ester

16691-79-5

C21H16O5