ChemicalBook > CAS DataBase List > LITHIUM METABORATE

LITHIUM METABORATE

Product Name: LITHIUM METABORATE
CAS No.: 13453-69-5
Chemical Name: LITHIUM METABORATE
Synonyms: Boricacidlithiumsalt;SPECTROMELT C 20;SPECTROMELT A 20;Lithiummetaborat;ithium metaborate;LITHIUM METABORATE;SPECTROMELT(R) C20;LITHIUM BORATE (META);LITHIUM METABORATE AR;lithium metaborate, acs
CBNumber: CB7208760
Molecular Formula: BH2LiO2
Formula Weight: 51.76
MOL File: 13453-69-5.mol

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LITHIUM METABORATE Property

Melting point:: 845 °C (lit.)
Density: 1,4 g/cm³
bulk density: 1300kg/m3
storage temp.: Store at +5°C to +30°C.
solubility: soluble in ethanol.
form: Powder
Specific Gravity: 1.4
color: White
Water Solubility: Soluble in water(27.5g/L).
Sensitive: Hygroscopic
Exposure limits: ACGIH: TWA 2 mg/m3; STEL 6 mg/m3
Stability:: Stable.
InChI: InChI=1S/BHO2.Li.H/c2-1-3;;/h2H;;
InChIKey: YMSYNVBIEXZZJS-UHFFFAOYSA-N
SMILES: B(=O)O.[LiH]
CAS DataBase Reference: 13453-69-5(CAS DataBase Reference)
EPA Substance Registry System: Lithium metaborate (13453-69-5)

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Safety

Risk Statements: 20/21/22-41
Safety Statements: 24/25
WGK Germany: 1
F: 3
TSCA: Yes
HS Code: 2840 20 90

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H318Causes serious eye damage

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 205524
Product name: Lithium metaborate
Purity: 99.9% trace metals basis
Packaging: 100g
Price: $127
Updated: 2025/07/31

Sigma-Aldrich

Product number: 205524
Product name: Lithium metaborate
Purity: 99.9% trace metals basis
Packaging: 500g
Price: $462.65
Updated: 2025/07/31

Sigma-Aldrich

Product number: 1.12996
Product name: Spectromelt A 20
Purity: lithium metaborate
Packaging: 1kg
Price: $926
Updated: 2025/07/31

Strem Chemicals

Product number: 93-0334
Product name: Lithium metaborate, anhydrous, (99.9%-Li)
Packaging: 50g
Price: $43
Updated: 2023/01/06

Strem Chemicals

Product number: 93-0334
Product name: Lithium metaborate, anhydrous, (99.9%-Li)
Packaging: 250g
Price: $174
Updated: 2023/01/06

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LITHIUM METABORATE Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

Lithium Metaborate is commonly used as a fused compound or a component for an assay. It has been used for the analysis of wild rice for silicon, calcium, magnesium and potassium. Lithium metaborate was used to fuse with solid samples for decomposition.

Uses

Lithium metaborate is used for flux.

Preparation

Lithium metaborate, LiBO2, may be prepared by fusing together either lithium hydroxide or lithium carbonate and boric acid in the proper stoichiometric ratio. Recrystallization from water at about room temperature yields lithium metaborate- octahydrate, LiBO2·8H2O. The octahydrate may be dried to yield a dihydrate, LiBO2-2H2O, or a half-hydrate, LiBO2·0.5H2O.

General Description

Lithium metaborate (LiBO₂) is the lithium salt of boric acid. It can be synthesized by reacting orthoboric acid with lithium carbonate. Its crystals belong to the monoclinic crystal system having space group P2₁/c. Three polymorphic forms have been identified on ambient pressure devitrification of LiBO₂: α-, γ- and β′-LiBO₂.

Flammability and Explosibility

Not classified

Structure and conformation

Lithium metaborate has several crystal forms.
Below 100 °C, LiBO₂·8H₂O is firstly dehydrated to a lower hydrate LiBO₂·2H₂O ^[1].
When the temperature is higher than 190°C, the dehydrated amorphous hydrate could crystallize into other poorly crystalline phases designated as LiBO₂·xH₂O (x=0.3/0.5)^[2].
An anhydrous monoclinic α-LiBO₂ could be obtained when the baking temperature reaches 600 °C. The α form consists of infinite chains of trigonal planar metaborate anions [BO2O^-]n.
At 950 °C, by applying 15 kbar of pressure to a LiCl flux containing α-LiBO_2,α-LiBO₂ could be converted to metastable γ-LiBO₂ crystals which were small, but of high quality^[3]. γ-LiBO² has tetragonal symmetry with lattice parameter a=4.1961 ?, c=6.5112 ?, space group I-42d and a density of 2.882 g/cm³.

References

[1] E.I.Kamitsos, A.P.Patsis, M.A.Karakassides, G.D.Chryssikos, Infrared reflectance spectra of lithium borate glasses, Journal of Non-Crystalline Solids, 1990, 126, 52-67.
[2] Li Lei, Duanwei He, Kai He, Jiaqian Qin, Shanmin Wang, Pressure-induced coordination changes in LiBO2, Journal of Solid State Chemistry, 2009, 182, 3041-3048.
[3] Colin D. McMillen, Henry G. Giesber, Joseph W. Kolis, The hydrothermal synthesis, growth, and optical properties of γ-LiBO2, Journal of Crystal Growth, 310, 2008, 299-305.

LITHIUM METABORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from LITHIUM METABORATE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: LITHIUM METABORATE 13453-69-5
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-13

Shandong Deshang Chemical Co., Ltd.

Product: LITHIUM METABORATE 13453-69-5
Price: US $6.00-3.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10 tons
Release date: 2024-08-15

Hebei Chuanghai Biotechnology Co,.LTD

Product: Lithium Metaborate 13453-69-5
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-23

13453-69-5, LITHIUM METABORATERelated Search:

Metaphosphoric acid BARIUM METAPHOSPHATE Lithium sulfide Barium boron oxide Lithium tetraborate Strontium carbonate Lithium bromide Sodium metaborate Magnesium titanium oxide Aluminum metaphosphate SODIUM METASILICATE PENTAHYDRATE AMMONIUM (META)TUNGSTATE HYDRATE Sodium metavanadate METABORIC ACID Lithium hydroxide Lithium hydroxide monohydrate LITHIUM METABORATE DIHYDRATE Lithium ion (1+)

boricacid(hbo2),lithiumsalt

Boricacidlithiumsalt

lithiummetaborate,anhydrous

LITHIUM METABORATE, ANHYDROUS, BIO-REFINEDLITHIUM METABORATE, ANHYDROUS, BIO-REFINEDLITHIUM METABORATE, ANHYDROUS, BIO-REFINEDLITHIUM METABORATE, ANHYDROUS, BIO-REFINED

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Lithiummetaborate,octahydrat

SPECTROMELT A 20

SPECTROMELT C 20

SPECTROMELT(R) C20

LITHIUM METABORATE

LITHIUM METABORATE 2-HYDRATE

LITHIUM BORATE (META)

Lithium metaborate, 99.995% metals basis

LITHIUM METABORATE ACS REAGENT

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Lithium metaborate, 99.9+% metals basis

LithiumMetaborateAnhydrousGr

Lithium metaborate, 99+%

Lithium metaborate, pure, 99%

LITHIUM METABORATE, ANHYDROUS BIO-REFINED

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LITHIUM METABORATE, ANHYDROUS REAGENT (ACS)

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Lithium metaborateACS reagent, 98.0-102.0% (Titration)

Lithium metaborate anhydrous≥ 99% (Metal basis)

Lithium metaborate anhydrous≥ 99.9% (Metal basis)

Lithium metaborate, dried

Lithium metaborate, anhydrous, (99.9%-Li)

LITHIUMMETABORATE,ANHYDROUS,BIOTECHGRADE

LITHIUMMETABORATE,REAGENT,ACS

Lithiummetaborat

LITHIUM METABORATE, ANHYDROUS: 99.9%

Lithium metaborate, Puratronic(R), 99.997% (metals basis)

Lithium metaborate, anhydrous, 99.9% (metals basis)

Lithium metaborate, ACS, 98.0-102.0%

Lithium metaborate, Puratronic, 99.997% (metals basis)

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Lithium metaborate/ 99.995+%

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SPECTROMELT A 20 LITHIUM METABORATE

LithiuM Metaborate 99.9% trace Metals basis

Lithium metaborate 99.995% trace metals basis

Lithium metaborate ACS reagent, >=98.0%

ithium metaborate

LITHIUM METABORATE ISO 9001：2015 REACH

Lithium metaborate, 99.9%

13453-69-5 LITHIUM METABORATE

LITHIUM METABORATE AR

Spectromelt<sup>?</sup> A 20

13453-69-5

LiBO28H2O

LiBO2