TITANIUM OXYSULFATE

ChemicalBook > CAS DataBase List > TITANIUM OXYSULFATE

Product Name: TITANIUM OXYSULFATE
CAS No.: 13825-74-6
Chemical Name: TITANIUM OXYSULFATE
Synonyms: TITANYL SULFATE;TITANYL SULFATE;TITANYL SULFATE;fate soL;TITANYL SULFATE;Provide Titanyl;TITANIUMSULPHATE;Titanium(IV) oxysuL;TITANIUM OXYSULFATE;Titanium oxysulphate
CBNumber: CB7211739
Molecular Formula: O5STi
Formula Weight: 159.93
MOL File: 13825-74-6.mol

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TITANIUM OXYSULFATE Property

Boiling point:: >100 °C
Density: 1.32 g/mL at 20 °C
solubility: reacts with H2O
form: Powder
color: White
Water Solubility: Soluble in water.
Merck: 14,9475
Stability:: Stable. Incompatible with bases, carbides, chlorates, fulminates, nitrates, picrates, permanganates, nitrites, phosphorus and other materials. May react violently with organic materials, halides, finely powdered metals.
CAS DataBase Reference: 13825-74-6(CAS DataBase Reference)
EPA Substance Registry System: Titanium, oxo[sulfato(2-)-.kappa.O,.kappa.O']- (13825-74-6)

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Safety

Hazard Codes: C,Xi
Risk Statements: 35-41-38
Safety Statements: 26-36/37/39-45-39
RIDADR: UN 2796 8/PG 2
WGK Germany: 2
TSCA: Yes
HazardClass: 8
PackingGroup: II

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 14023
Product name: Titanium(IV) oxysulfate
Purity: ≥29% Ti (as TiO
Packaging: 1kg
Price: $254
Updated: 2024/03/01

Sigma-Aldrich

Product number: 14023
Product name: Titanium(IV) oxysulfate
Purity: ≥29% Ti (as TiO
Packaging: 6x1kg
Price: $1450
Updated: 2024/03/01

Alfa Aesar

Product number: 039591
Product name: Titanium(IV) oxide sulfate sulfuric acid hydrate
Packaging: 500g
Price: $88.7
Updated: 2021/12/16

Alfa Aesar

Product number: 039591
Product name: Titanium(IV) oxide sulfate sulfuric acid hydrate
Packaging: 2kg
Price: $249
Updated: 2021/12/16

Sigma-Aldrich

Product number: 495379
Product name: Titanium(IV) oxysulfate solution
Purity: ~15 wt. % in dilute sulfuric acid, 99.99% trace metals basis
Packaging: 250ml
Price: $62.2
Updated: 2024/03/01

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TITANIUM OXYSULFATE Chemical Properties,Usage,Production

Chemical Properties

White, cake-like solid. Highly acidic, similar to 50% sulfuric acid, typical composition 20% TiO2, 50% sulfuric acid, 30% water, hygroscopic. Soluble in water; solutions hydrolyze readily unless protected from heat and dilution.

Uses

TiOSO₄ (titanium (IV) oxysulfate) was used for the preparation of stable amorphous titanium oxide (TiO₂) hollow microspheres.

Uses

In tanning; in production of pigment grade and of anatase-structured titanium dioxide.

Production Methods

Pure, multiple-distilled TiCl4 is added in drops (vigorous stirring) to the stoichiometric quantity of 50% H2SO4. The precipitate formed after each addition should dissolve completely before the next portion of TiCl4 is added. After adding about 3/4 of the TiCl4, the liquid turns into a viscous, yellowish solution. It is diluted with 1/5 its volume of water, and the dropwise addition of TiCl4 is completed. The resultant solution, which is still highly concentrated in HCl, is evaporated to dryness in a water bath. The residue is pulverized, dried, and freed of HCl by heating it for several days at 80-100°C in a drying pistol at a pressure of a few mm. The sulfate obtained in this manner (TiO2: SO3 = 1:1.07) is colourless and free of HCl. It is hygroscopic and soluble in water, yielding a clear solution.

General Description

A colorless or violet colored liquid. Dilution releases heat and may cause precipitation of solid titanium sulfate. Corrosive to metals and tissue. TITANIUM OXYSULFATE is used to make pigments and in dyeing.

Air & Water Reactions

Can generate heat on dilution with water.

Reactivity Profile

A highly acidic liquid.

Hazard

Irritant to skin and tissue.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Safety Profile

A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of SOx. See also TITANIUM COMPOUNDS and SULFATES.

Purification Methods

Dissolve it in water, filter and crystallise it three times from boiling 45% H2SO4, washing with EtOH to remove excess acid, then with Et2O. Dry it in air for several hours, then in an oven at 105-110o. [Hixson & Fredrickson Ind Eng Chem 37 678 1945.]

Structure and conformation

The structure of titanium(IV) oxysulfate consists of dense polymeric network with tetrahedral sulfur and octahedral titanium centers. The six ligands attached to titanium are derived from four different sulfate moieties and a bridging oxide.

TITANIUM OXYSULFATE Preparation Products And Raw materials

Raw materials

Metatitanic acid Sulfuric acid

Preparation Products

Lead(II) carbonate basic

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View Lastest Price from TITANIUM OXYSULFATE manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: TITANIUM OXYSULFATE 13825-74-6
Price: US $25.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-11

Hebei Weibang Biotechnology Co., Ltd

Product: TITANIUM OXYSULFATE 13825-74-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-31

Hebei Yanxi Chemical Co., Ltd.

Product: TITANIUM OXYSULFATE 13825-74-6
Price: US $20.00-1.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-11-02

13825-74-6, TITANIUM OXYSULFATERelated Search:

Manganese sulfide Titanium carbide Magnesium nitride TITANIUM NITRIDE ZINC TELLURIDE TITANIUM(VI) SULFIDE TITANIUM OXYSULFATE TITANIUM OXYSULFATE,TITANIUM OXYSULFATE-SULFURIC ACID COMPLEX HYDRATE,titanium oxysulfate sulfuric acid solution TITANIUM SULFATE

oxo(sulfato(2-)-O,O’)-Titanium

oxo[sulfato(2-)-o,o’]-titaniu

Titanium(IV) oxysulfate >=29% Ti (as TiO2) basis

Titanium(IV) oxysulfate solution ~15t. % in dilute sulfuric acid

TitaniuM,oxo[sulfato(2-)-kO,kO']-

TitaniuM(IV) oxysulfate >=29% Ti (as TiO2) basis, technical

TitaniuM(IV) oxysulfate solution ~15 wt. % in dilute sulfuric acid, 99.99% trace Metals basis

oxotitanium(2+):sulfate

TITANIUM(IV) OXIDE SULFATE

TITANIUM OXIDE SULFATE HYDRATE

TITANYL SULFATE HYDRATE

TITANYL SULFATE

TITANIUM SULFATE, BASIC

titanium oxide sulphate

Titanium(IV) oxide sulfate sulfuric acid hydrate

Titanium(IV) oxysulfate, 99.99% metals basis, ca.15 wt. % solution in dilute sulfuric acid

Titanium, oxosulfato(2-)-.kappa.O,.kappa.O-

titanium(iv) oxysulfate solution

TITANIUMSULPHATE

oxo(sulfato-O,O')-Titanium

oxo[sulfato-o,o']-titaniu

Titanium, oxo[sulfato(2-)-O,O']-

Titanium oxysulphate

Titanium oxide sulfate

Titanium oxysulfate - sulfuric acid hy

TITANIUM SULFATE, PURIFIEDTITANIUM SULFATE, PURIFIEDTITANIUM SULFATE, PURIFIED

fate soL

Titanium(IV) oxysuL

Provide Titanyl

TITANYL SULFATE

TITANIUM OXYSULFATE

TITANYL SULFATE

Oxo(sulfato(2-)-O,O')-Titanium

oxo[sulfato(2-)-o,o']-titaniu

13825-74-6

H2O9S2Ti

HO5STi

TiOSO4aq

TiOSO4xH2OH2SO4

O5STixH2O

Catalysis and Inorganic Chemistry

Titanium

Inorganics

TitaniumMetal and Ceramic Science

Catalysis and Inorganic Chemistry

Chemical Synthesis

Salts

Titanium Salts

Analytical Reagents

Waste Water

Water Test