(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE

Reaction

Product Name: (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
CAS No.: 447440-43-9
Chemical Name: (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
Synonyms: 1-Oxa-3-aza-2-silacyclopentane,2-chloro-3,4-dimethyl-5-pheny...;(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine;(4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-prop-2-enyl-1,3,2-oxazasilolidine;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane ;1-Oxa-3-aza-2-silacyclopentane, 2-chloro-3,4-dimethyl-5-phenyl-2-(2-propen-1-yl)-, (4S,5S)-
CBNumber: CB72134999
Molecular Formula: C13H18ClNOSi
Formula Weight: 267.83
MOL File: 447440-43-9.mol

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(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Property

Density: 1.095 g/mL at 25 °C
refractive index: n20/D1.517
Flash point:: 38℃
pka: 4.43±0.60(Predicted)
Specific Gravity: 1.01
optical activity: [α]20/D 72.5°, c = 0.6 in ethanol (200 proof)
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Sensitive: moisture sensitive, store cold
Boiling point:: 120°C/5 mmHg

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Safety

Hazard Codes: F,Xi
Risk Statements: 10-15-36/37/38
Safety Statements: 26
RIDADR: UN 3132 / PGII
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H261In contact with water releases flammable gas

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P422Store contents under …

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 14-1815
Product name: (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
Packaging: 1g
Price: $99
Updated: 2024/03/01

Strem Chemicals

Product number: 14-1815
Product name: (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
Packaging: 5g
Price: $395
Updated: 2024/03/01

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(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Chemical Properties,Usage,Production

Reaction

Versatile reagent for the enantioselective allylation of aldehydes and hydrazones.

Uses

Leighton′s Strained Silacycles: Powerful Enantioselective Allylation Reagents

Practical, enantioselective allylation of acylhydrazones
Enantioselective allylation of ketimines: synthesis of tertiary carbinamines

General Description

This product is a mixture of diastereomers.

(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Suppliers

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447440-43-9, (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINERelated Search:

DIMETHYLAMINOMETHYLETHOXYSILANE Norpseudoephedrine hydrochloride (1S,2S)-(+)-PSEUDOEPHEDRINE-D3 HCL (N-METHYL-D3) (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE

(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE

(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane

(4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-prop-2-enyl-1,3,2-oxazasilolidine

(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine

1-Oxa-3-aza-2-silacyclopentane,2-chloro-3,4-dimethyl-5-pheny...

1-Oxa-3-aza-2-silacyclopentane, 2-chloro-3,4-dimethyl-5-phenyl-2-(2-propen-1-yl)-, (4S,5S)-

447440-43-9

C13H18ClNOSi

organosilicon compound