ChemicalBook > CAS DataBase List > 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE

5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE

Product Name: 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE
CAS No.: 51094-17-8
Chemical Name: 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE
Synonyms: RARECHEM AS SA 0037;MESO-TETRA(P-HYDROXYPHENYL)PORPHINE;meso-Tetrakis(4-hydroxyphenyl)porphyrin;5,10,15,20-tetrakis(4-hydroxyphenyl)-21H;5,10,15,20-tetra(4-hydroxyphenyl)porphyrin;5,10,15,20-Tetrakis(4-hydroxyphenyl)porphin;5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin;5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE;5,10,15,20-TETRAKIS-(4-HYDROXYPHENYL)-21,23H-PORPHYRIN;5,10,15,20-Tetrakis(4-hydroxyphenyl)-21H,23H-porphyrin
CBNumber: CB7234897
Molecular Formula: C44H30N4O4
Formula Weight: 678.73
MOL File: 51094-17-8.mol

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5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE Property

Melting point:: >300 °C(lit.)
Density: 1.401±0.06 g/cm3(Predicted)
storage temp.: room temp
form: powder to crystal
color: Gray to Dark purple to Black
λmax: 421 nm
ε(extinction coefficient): ≥285000 at 417-423nm in methanol at 0.001g/L
InChIKey: VFHDWGAEEDVVPD-LWQDQPMZSA-N
SMILES: C1(C2=CC=C(O)C=C2)=C2N=C(C(C3=CC=C(O)C=C3)=C3NC(=C(C4=CC=C(O)C=C4)C4=NC(=C(C5=CC=C(O)C=C5)C5NC1=CC=5)C=C4)C=C3)C=C2 |c:20,t:8,23,35|

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Safety

Hazard Codes: C
Risk Statements: 34-37
Safety Statements: 26-36/37/39-45
RIDADR: UN 3263 8/PG 3
WGK Germany: 1
HS Code: 2934.30.5000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 477567
Product name: 5,10,15,20-Tetrakis(4-hydroxyphenyl)-21H,23H-porphine
Purity: Dye content 95%
Packaging: 250mg
Price: $107
Updated: 2025/07/31

Sigma-Aldrich

Product number: 477567
Product name: 5,10,15,20-Tetrakis(4-hydroxyphenyl)-21H,23H-porphine
Purity: Dye content 95%
Packaging: 1g
Price: $312
Updated: 2025/07/31

TCI Chemical

Product number: T1497
Product name: 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin
Purity: >95.0%(HPLC)
Packaging: 100mg
Price: $76
Updated: 2025/07/31

TRC

Product number: T310525
Product name: meso-Tetra(p-hydroxyphenyl)porphine
Packaging: 250mg
Price: $75
Updated: 2021/12/16

TRC

Product number: T310525
Product name: meso-Tetra(p-hydroxyphenyl)porphine
Packaging: 500mg
Price: $115
Updated: 2021/12/16

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5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE Chemical Properties,Usage,Production

Description

5,10,15,20-(tetra-4-hydroxyphenyl)porphyrin is a porphyrin derivative used for detection of water-soluble vitamins by matrix-assisted laser desorption/ionization (MALDI) mass spectrometry.

Uses

meso-Tetra(p-hydroxyphenyl)porphine is a porphyrin derivative used for research.

Synthesis

109-97-7

123-08-0

51094-17-8

6.1 g of p-hydroxybenzaldehyde was dissolved in 110 mL of propionic acid, 6 mL of dimethyl sulfoxide (DMSO) was added, the mixture was mechanically stirred and heated to 128°C. Freshly distilled 3.5 mL of pyrrole was dissolved in 10 mL of propionic acid and slowly added dropwise at a rate of 1 drop per second to the above reaction mixture. The temperature of the reaction system was then raised to 141 °C and the reaction was refluxed for 2 hours. Upon completion of the reaction, hot filtration was performed and the filter cake was washed twice with propionic acid to obtain a blue solid 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin crude product. 10 g of the dried crude product was placed in a 100 mL round-bottomed flask, 20 mL of anhydrous ethanol was added and heated to reflux for 15 minutes before continuing to heat for 1.5 hours. The reaction solution was cooled in an ice bath for 1.5 h. The reaction solution was filtered and washed twice with ethanol to give 0.6172 g of 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin in 7.27% yield. Finally, the purified product was purified by silica gel column chromatography (200 mesh) using acetone as eluent.

References

[1] Patent: CN105085536, 2018, B. Location in patent: Paragraph 0060; 0117-0122
[2] Journal of the American Chemical Society, 2013, vol. 135, # 49, p. 18513 - 18519
[3] Macromolecular Bioscience, 2013, vol. 13, # 6, p. 808 - 816
[4] Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 2001, vol. 364, p. 611 - 623
[5] Tetrahedron Letters, 2007, vol. 48, # 41, p. 7287 - 7290

5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 5,10,15,20-Tetrakis(4-hydroxyphenyl)-21H,23H-porphine 51094-17-8
Price: US $18.00-48.00/KG
Min. Order: 0.01KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2025-06-19

Career Henan Chemical Co

Product: 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin 51094-17-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100KG
Release date: 2018-12-25

51094-17-8, 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINERelated Search:

5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE meso-Tetra(4-carboxyphenyl)porphine TPP 5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE 5,10,15,20-TETRAKIS(4-FLUOROPHENYL)-21H,23H-PORPHINE) 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE meso-Tetra (4-chlorophenyl) porphine 4-Hydroxybenzyl alcohol TETRYL 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE 5,10,15,20-TETRAKIS(4-AMINOPHENYL)-21H,23H-PORPHINE 5,10,15,20-TETRAKIS(4-CARBOXYMETHYLOXYPHENYL)-21H,23H-PORPHINE 3A-AMINO-3A-DEOXY-(2AS,3AS)-BETA-CYCLODEXTRIN 5,10,15,20-TETRAKIS(3-HYDROXYPHENYL)-21H,23H-PORPHINE SALOR-INT L159018-1EA 5 10 15 20-TETRAKIS(4-(ALLYLOXY)PHENYL)& SALOR-INT L162485-1EA 5,10,15,20-TETRAKIS-(3-METHOXY-4-HYDROXY-PHENYL)-21,23H-PORPHYRIN

5,10,15,20-TETRAKIS-(4-HYDROXYPHENYL)-21,23H-PORPHYRIN

5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE

RARECHEM AS SA 0037

5,10,15,20-tetrakis(4-hydroxyphenyl)-21H

5,10,15,20-tetrakis(4-hydroxyphenyl)-21h,23h-porphine95+%

5,10,15,20-tetra(4-hydroxyphenyl)porphyrin

MESO-TETRA(P-HYDROXYPHENYL)PORPHINE

4,4',4'',4'''-(21H,23H-Porphyrin 5,10,15,20-tetrayl)tetrakisphenol

4,4',4'',4'''-(21H,23H-Porphyrin 5,10,15,20-tetryl)tetrakisphenol

4,4',4'',4'''-(21H,23H-Porphyrin-5,10,15,20-tetrayl)tetrakis(phenol)

4,4',4'',4'''-(21H,23H-Porphyrin-5,10,15,20-tetryl)tetrakis(phenol)

5,10,15,20-Tetrakis(4-hydroxyphenyl)-21H,23H-porphyrin

meso-Tetrakis(4-hydroxyphenyl)porphyrin

5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin

5,10,15,20- Tetrakis(4-hydroxyphenyl)-21H,23H- prophine

phenol, 4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl) tetrakis-

4-[(10Z,14Z)-10,15-bis(4-hydroxyphenyl)-20-(4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]cyclohexa-2,5-dien-1-one

javascript:showMsgDetail('ProductSynonyms.aspxCBNumber=CB7234897&postData3=CN&SYMBOL_Type=A')

5,10,15,20-Tetrakis(4-hydroxyphenyl)porphin

4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-Phenol

5,10,15,20-Tetrakis(4-hydroxyphenyl)-21<i>H</i>,23<i>H</i>-porphine

4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-Phenol

51094-17-8

C44H30N4O4

Porphyrins

Synthetic Porphyrins

Biochemistry

Photonic and Optical Materials

Phthalocyanine and Porphyrin Dyes

Porphyrines