ChemicalBook > CAS DataBase List > 7-METHOXY-2-METHYLQUINOLINE

7-METHOXY-2-METHYLQUINOLINE

Product Name: 7-METHOXY-2-METHYLQUINOLINE
CAS No.: 19490-87-0
Chemical Name: 7-METHOXY-2-METHYLQUINOLINE
Synonyms: 2-Methyl-7-Methoxyquinoline;7-METHOXY-2-METHYLQUINOLINE;Quinoline, 7-methoxy-2-methyl-
CBNumber: CB72450747
Molecular Formula: C11H11NO
Formula Weight: 173.21
MOL File: 19490-87-0.mol

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7-METHOXY-2-METHYLQUINOLINE Property

Boiling point:: 286.0±20.0 °C(Predicted)
Density: 1.102±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 6.15±0.50(Predicted)
Appearance: Colorless to light yellow Liquid

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Safety

Hazard Codes: Xn
Risk Statements: 22-41
Safety Statements: 26-39
WGK Germany: 3
HS Code: 2933499090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: BBO000218
Product name: 7-Methoxy-2-methylquinoline
Purity: Aldrich
Packaging: 1g
Price: $332
Updated: 2023/01/07

TRC

Product number: M341710
Product name: 7-Methoxy-2-methylquinoline
Packaging: 500mg
Price: $285
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H56-1-549
Product name: 7-Methoxy-2-methylquinoline
Packaging: 1g
Price: $456
Updated: 2021/12/16

AK Scientific

Product number: 0084AB
Product name: 7-Methoxy-2-methylquinoline
Packaging: 5g
Price: $1615
Updated: 2021/12/16

Crysdot

Product number: CD11174454
Product name: 7-Methoxy-2-methylquinoline
Purity: 95+%
Packaging: 1g
Price: $347
Updated: 2021/12/16

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7-METHOXY-2-METHYLQUINOLINE Chemical Properties,Usage,Production

Synthesis

64-17-5

536-90-3

19490-87-0

General procedure for the synthesis of 2-methyl-7-methoxyquinoline from ethanol and m-aminoanisole: 0.005 mmol (1.1 mg) of transition metal catalyst was accurately weighed and placed in a 10 mL Young reaction tube equipped with a magnetic stirrer. Under oxygen atmosphere, 0.04 mmol of co-catalyst I, 0.08 mmol of co-catalyst II, 0.2 mmol of 3-methoxyaniline and 1 mL of anhydrous ethanol were added sequentially to the reaction tube. The reaction mixture was stirred at 150 °C for 16 hours. After completion of the reaction, the pH of the reaction solution was adjusted to neutral and left to stand for subsequent processing. The target product 2-methyl-7-methoxyquinoline was purified by column chromatography in 88% yield.

References

[1] Patent: CN106543078, 2017, A. Location in patent: Paragraph 0089; 0090
[2] Tetrahedron Letters, 2010, vol. 51, # 37, p. 4911 - 4914
[3] Research on Chemical Intermediates, 2012, vol. 38, # 3-5, p. 761 - 773
[4] Journal of Organic Chemistry, 2017, vol. 82, # 6, p. 3284 - 3290
[5] Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2013, vol. 43, # 4, p. 500 - 508

7-METHOXY-2-METHYLQUINOLINE Preparation Products And Raw materials

Raw materials

Preparation Products

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19490-87-0, 7-METHOXY-2-METHYLQUINOLINERelated Search:

Lurtotecan Minocromil Acequinoline 2-(2-ISOPROPYLAMINO-THIAZOL-4-YL)-7-METHOXY-QUINOLIN-4-OL AKOS BBS-00001550 7-METHOXY-2-METHYLQUINOLINE-3-CARBOXYLIC ACID 7-METHOXY-2-METHYL-4-QUINOLINOL AURORA KA-5155 DIMETHYL 8-METHYL[1,3]DIOXOLO[4,5-G]QUINOLINE-6,7-DICARBOXYLATE 9-Acridinamine, 1,2,3,4-tetrahydro-6-methoxy- METHYL 4-OXO-3-(2,2,2-TRIFLUOROETHYL)-3,4-DIHYDRO[1,3]BENZODIOXOLO[5,6-C][2,7]NAPHTHYRIDINE-5-CARBOXYLATE 4-CHLORO-2-METHYL-5,6,7-TRIMETHOXYQUINOLINE AURORA KA-6336 7-(4-HYDROXY-3-METHOXY-PHENYL)-2,3-DIHYDRO-[1,4]DIOXINO[2,3-G]QUINOLINE-9-CARBOXYLIC ACID 9-(4-FLUOROPHENYL)[1,3]DIOXOLO[4,5-G]FURO[3,4-B]QUINOLIN-8(6H)-ONE 2,3-DIMETHOXY-11-PHENYLINDENO[3,2-B]QUINOLIN-10-ONE 9-Acridinamine, 1,2,3,4-tetrahydro-N-heptyl-6-methoxy- 7-METHOXY-2-METHYL-1-OXO-1,2-DIHYDROBENZO[B]-1,6-NAPHTHYRIDINE-4-CARBALDEHYDE

7-METHOXY-2-METHYLQUINOLINE

2-Methyl-7-Methoxyquinoline

Quinoline, 7-methoxy-2-methyl-

19490-87-0