Lithium sulfide

ChemicalBook > CAS DataBase List > Lithium sulfide

Product Name: Lithium sulfide
CAS No.: 12136-58-2
Chemical Name: Lithium sulfide
Synonyms: Thiobislithium;LITHIUMSULPHIDE;LITHIUM SULFIDE;dilithiumsulfide;Lithium sulfide 99%;lithiumsulfide(li2s);dilithiummonosulfide;Lithium sulphide, 99%+;(lithiosulfanyl)lithium;Lithium sulphide, 99.9%
CBNumber: CB7245998
Molecular Formula: Li2S
Formula Weight: 45.95
MOL File: 12136-58-2.mol

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Lithium sulfide Property

Melting point:

>900°C

Density

1.66 g/mL at 25 °C (lit.)

storage temp.

2-8°C

form

Powder

Specific Gravity

1.66

color

Yellow

Water Solubility

soluble in water and ethanol

Crystal Structure

Reverse CaF2 type

Sensitive

Moisture Sensitive

crystal system

Cube

Space group

Fm3m

Lattice constant

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
0.5718	0.5718	0.5718	90	90	90	0.187

InChI

InChI=1S/2Li.S

InChIKey

ZWDBUTFCWLVLCQ-UHFFFAOYSA-N

SMILES

S([Li])[Li]

CAS DataBase Reference

12136-58-2(CAS DataBase Reference)

EPA Substance Registry System

Lithium sulfide (Li2S) (12136-58-2)

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Safety

Hazard Codes: C
Risk Statements: 22-31-34
Safety Statements: 26-36/37/39-45
RIDADR: UN 2923 8/PG 2
WGK Germany: 3
RTECS: OJ6439500
F: 8-10-13
TSCA: Yes
HazardClass: 8
PackingGroup: II

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 213241
Product name: Lithium sulfide
Purity: 99.98% trace metals basis
Packaging: 5g
Price: $147
Updated: 2024/03/01

Sigma-Aldrich

Product number: 213241
Product name: Lithium sulfide
Purity: 99.98% trace metals basis
Packaging: 10g
Price: $257
Updated: 2024/03/01

Alfa Aesar

Product number: 012839
Product name: Lithium sulfide, 99.9% (metals basis)
Packaging: 2g
Price: $52
Updated: 2023/06/20

Alfa Aesar

Product number: 012839
Product name: Lithium sulfide, 99.9% (metals basis)
Packaging: 10g
Price: $160
Updated: 2023/06/20

Strem Chemicals

Product number: 93-0378
Product name: Lithium sulfide, 98% (99.9%-Li)
Packaging: 5g
Price: $102
Updated: 2024/03/01

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Lithium sulfide Chemical Properties,Usage,Production

Chemical Properties

Lithium sulfide is the inorganic compound with the formula Li2S. It crystallizes in the antifluorite motif, described as the salt (Li+)2S2−. It forms a solid yellow-white deliquescent powder. In air, it easily hydrolyses to release hydrogen sulfide (rotten egg odor) Lithium sulfide is prepared by treating lithium with sulfur. This reaction is conveniently conducted in anhydrous ammonia. The THF-soluble triethylborane adduct of lithium sulfide can be generated using superhydride.

Lithium sulfide (Li2S) is considered the promising cathode material for its high theoretical capacity, high melting point, affordable volume expansion, and lithium composition.

Physical properties

Lithium Sulfide, Li2S, is an anti-fluorite semiconductor with a band-gap of 3.865 eV. It also has exactly the same valence electron count, Ne, and atomic number, Z, as magnesium diboride, MgB2. Both have almost the same formula weight. This qualifies Li2S as a magnesium-diboride like material. Li2S passes the same computational material specific test for superconductivity as MgB2.
Lithium sulfide is a much studied material, though never tested for superconductivity. Li2S can exist in two forms: orthorhombic and cubic. The orthorhombic form belongs to space group Pmnb and has dimensions: a = 3.808Å; b = 6.311Å; c = 7.262Å. It has density of 1.75g/cm3 . The cubic version has density of 1.63g/ cm3, belongs to space group Fm-3m and has cubic dimensions 4.046Å. The electronic structure and density of states indicate that cubic Li2S is an indirect band-gap semiconductor with a band gap of 3.865 eV. Lithium sulfide melts between 900 – 975 degrees centigrade.

Uses

Lithium sulfide has been studied as a MgB₂- like superconductor. It is also used as a cathode material in rechargeable lithium-sulfur batteries.

Uses

Lithium sulfide (Li2S) is a product specially designed for the use in high performance batteries which can be either applied as electrode material or as precursor for solid electrolytes. It as an electrode material not only has high capacity but also overcomes many problems caused by pure sulfur electrodes.
Lithium sulfide is an anti fluorite semiconductor (bandgap 3.865eV). It exists in orthorhombic and cubic structures. The densities of the orthorhombic and cubic structures are 1.75g/cm3 and 1.63g/cm3 respectively.
Lithium sulfide has been studied as a MgB2- like superconductor. It is also used as a cathode material in rechargeable lithium-sulfur batteries.

Preparation

Lithium sulfide, Li2S, is formed in the reaction of lithium with sulfur in liquid ammonia, by the decomposition of the ethanol adduct of lithium hydrogen sulfide with lithium ethanolate, and, more recently, by the reaction of hydrogen sulfide with lithium amylate to yield lithium hydrogen sulfide, LiSH, which is thermally decomposed in a vacuum to yield the sulfide. A very high quality anhydrous lithium sulfide may be prepared by the reaction of lithium metal and hydrogen sulfide in tetrahydrofuran if care is taken to exclude water. The reaction product is filtered from the reaction medium, and it is vacuum dried to remove tetrahydrofuran and to decompose the small amount of lithium hydrogen sulfide which forms. Lithium sulfide is reported to have an antifluorite structure. Lithium sulfide is readily hydrolyzed, even by water in the air, yielding hydrogen sulfide. The sulfide also reacts with sulfur to form a variety of polysulfides.

General Description

Lithium sulfide is an anti fluorite semiconductor (bandgap 3.865eV). It exists in orthorhombic and cubic structures. The densities of the orthorhombic and cubic structures are 1.75g/cm³ and 1.63g/cm³ respectively.

Toxicology

Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of repeated exposure to lithium ion.

Lithium sulfide Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Lithium sulfide manufacturers

Hebei Yanxi Chemical Co., Ltd.

Product: Lithium sulfide 12136-58-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.9%/99.99%
Supply Ability: 100KG/Month
Release date: 2024-03-21

Henan Fengda Chemical Co., Ltd

Product: Lithium sulfide 12136-58-2
Price: US $32.00-1.40/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-07

Hubei Langyou International Trading Co., Ltd

Product: Lithium sulfide 12136-58-2
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99.9%
Supply Ability: 10000kg/month
Release date: 2023-03-13

12136-58-2, Lithium sulfideRelated Search:

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dilithiummonosulfide

dilithiumsulfide

lithiumsulfide(li2s)

lithiumsulphide,anhydrous

LITHIUM SULFIDE

Lithiumsulfide,98%(99.9%-Li)

LITHIUMSULPHIDE

LITHIUM SULFIDE (99.9% LI)

Lithium sulfide, 99.9% (metals basis)

Thiobislithium

Lithium sulfide 99%

LithiuM sulfide 99.98% trace Metals basis

(lithiosulfanyl)lithium

Lithium sulfide, 99.9% trace metals basis

99% Lithium Sulfide Li2S CAS 12136-58-2 for Batteries

Z% metel basisLithium Sulfide

Lithiumsulfid, wasserfrei

Lithium sulphide, 99%+

Lithium sulphide, 99.9%

12136-58-2

Catalysis and Inorganic Chemistry

Lithium

metal chalcogenides

Catalysis and Inorganic Chemistry

ChalcogenidesChemical Synthesis

Lithium

Materials Science

Metal and Ceramic Science