ChemicalBook > CAS DataBase List > 3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID

3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID

Product Name: 3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID
CAS No.: 19947-39-8
Chemical Name: 3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID
Synonyms: 3-AMINO-3-(4-CHLOROPHENYL)PROPANOIC ACID;3-Amino-3-(4-chL;BUTTPARK 94\04-04;AKOS BBS-00001407;RARECHEM AK HC T318;3-(4-Chlorophenyl)-β-Alanine;DL-BETA-(P-CHLOROPHENYL)ALANINE;3-(4-Chlorophenyl)-beta-alanine;3-(P-CHLOROPHENYL)-DL-BETA-ALANINE;β-Amino-4-chlorobenzenepropanoic acid
CBNumber: CB7248717
Molecular Formula: C9H10ClNO2
Formula Weight: 199.63
MOL File: 19947-39-8.mol

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3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID Property

Melting point:: 223 °C (dec.)(lit.)
Boiling point:: 345.8±32.0 °C(Predicted)
Density: 1.2409 (rough estimate)
refractive index: 1.5790 (estimate)
storage temp.: Sealed in dry,Room Temperature
pka: 3.62±0.10(Predicted)
form: Powder
color: Off-white
BRN: 2365902
CAS DataBase Reference: 19947-39-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 24/25
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29224999

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

H330Fatal if inhaled

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P391Collect spillage. Hazardous to the aquatic environment

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 573353
Product name: 3-Amino-3-(4-chlorophenyl)propionic acid
Purity: 97%
Packaging: 1g
Price: $51.8
Updated: 2023/06/20

TCI Chemical

Product number: A2429
Product name: 3-Amino-3-(4-chlorophenyl)propionic Acid
Purity: >97.0%(HPLC)(T)
Packaging: 1g
Price: $249
Updated: 2024/03/01

TCI Chemical

Product number: A2429
Product name: 3-Amino-3-(4-chlorophenyl)propionic Acid
Purity: >97.0%(HPLC)(T)
Packaging: 5g
Price: $1054
Updated: 2024/03/01

TRC

Product number: A604018
Product name: 3-Amino-3-(4-chlorophenyl)propanoicAcid
Packaging: 100mg
Price: $60
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA11139
Product name: 3-Amino-3-(p-chlorophenyl)propionic acid
Packaging: 2g
Price: $60
Updated: 2021/12/16

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3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Synthesis

141-82-2

104-88-1

19947-39-8

To 25 mL of ethanol were sequentially added 5.00 g (35.6 mmol) of 4-chlorobenzaldehyde, 3.70 g (35.6 mmol) of malonic acid and 4.10 g (53.2 mmol) of ammonium acetate, and the reaction mixture was stirred at reflux for 8 hr at 75 to 80°C. The reaction was carried out by stirring the mixture for 1 hr at room temperature. After completion of the reaction, the mixture was continued to be stirred at room temperature for 1 h. Subsequent filtration afforded 5.9 g of 3-amino-3-(4-chlorophenyl)propionic acid (racemic mixture) as a white powder (82.3% isolated yield based on 4-chlorobenzaldehyde). The physical properties of the compound were as follows: 1H-NMR (δ, ppm, D2O): 2.93 (dd, 1H, J = 17.1, 6.8 Hz), 3.04 (dd, 1H, J = 17.1, 7.8 Hz), 4.63 (dd, 1H, J = 7.8, 6.8 Hz), 7.22 (s, 1H), 7.24 (s, 1H), 7.47 (s, 1H), 7.49 (s, 1H); 13C-NMR (δ, ppm, D2O): 40.4, 53.9, 126.0, 131.9, 135.3, 137.1, 175.9; MS (EI) m/z: 199 (M+); MS (CI, i-C4H10) m/z: 200 (MH+).

References

[1] Patent: EP1621529, 2006, A1. Location in patent: Page/Page column 31
[2] Preparative Biochemistry and Biotechnology, 2013, vol. 43, # 2, p. 207 - 216
[3] European Journal of Medicinal Chemistry, 2018, vol. 156, p. 252 - 268
[4] Advanced Synthesis and Catalysis, 2017, vol. 359, # 9, p. 1570 - 1576
[5] Heterocycles, 1989, vol. 28, # 2, p. 1015 - 1035

3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID Suppliers

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View Lastest Price from 3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID manufacturers

Career Henan Chemical Co

Product: 3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID 19947-39-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-07-04

19947-39-8, 3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACIDRelated Search:

3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID FMOC-D-2-Chlorophe FMOC-(S)-3-AMINO-3-(2-CHLORO-PHENYL)-PROPIONIC ACID 2-Chloro-D-phenylalanine 3-AMINO-3-(2-CHLOROPHENYL)PROPIONIC ACID, 98+% FMOC-(R)-3-AMINO-3-(2-CHLORO-PHENYL)-PROPIONIC ACID BOC-(S)-3-AMINO-3-(2-CHLORO-PHENYL)-PROPIONIC ACID FMOC-(R)-3-AMINO-3-(3-CHLORO-PHENYL)-PROPIONIC ACID BOC-D-2-Chlorophe (R)-3-AMINO-3-(2-CHLORO-PHENYL)-PROPIONIC ACID BOC-L-2-Chlorophe 2-Chloro-L-phenylalanine (R)-2-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID HYDROCHLORIDE Methyl (S)-3-acetamido-3-(4-chlorophenyl)propanoate 3-AMINO-3-(3-CHLORO-PHENYL)-PROPIONIC ACID Boc-(R)-3-Amino-3-(4-chlorophenyl)propionic acid BOC-(S)-3-AMINO-3-(3-CHLORO-PHENYL)-PROPIONIC ACID (S)-2-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID HYDROCHLORIDE

BUTTPARK 94\04-04

DL-3-AMINO-3-(4'-CHLOROPHENYL)PROPIONIC ACID

DL-3-AMINO-3-(4-CHLORO-PHENYL)-PROPIONIC ACID

DL-BETA-(P-CHLOROPHENYL)ALANINE

3-AMINO-3-(4-CHLOROPHENYL)PROPANOIC ACID

3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACID

3-AMINO-3-(P-CHLOROPHENYL)PROPIONIC ACID

AKOS BBS-00001407

RARECHEM AK HC T318

3-AMINO-3-(4-CHLOROPHENYL)PROPIONIC ACI&

3-AMINO-3-(P-CHLOROPHENYL)PROPIONIC ACID 98%

3-(P-CHLOROPHENYL)-DL-BETA-ALANINE

Boc-(+/-)-3-Amino-3-(4-chlorophenyl)propanoic Acid

1-(1-Amino-2-carboxyethyl)-4-chlorobenzene, 3-Amino-3-(4-chloro-phenyl)propionic acid

3-(4-Chlorophenyl)-beta-alanine

Benzenepropanoic acid, β-amino-4-chloro-

β-Amino-4-chlorobenzenepropanoic acid

3-Amino-3-(p-chlorophenyl)propionic acid,98%

(RS)-3-Amino-3-(4-chlorophenyl)-propionic acid

3-Amino-3-(4-chlorophenyl)propionicAcid&gt

3-Amino-3-(4-chL

3-amino-3-(4-chlorophenyl)propanoicaci

3-(4-Chlorophenyl)-β-Alanine

19947-39-8

19967-39-8

ClC6H4CHNH2CH2CO2H

Organic Building Blocks

Carboxylic Acids

Carbonyl Compounds

Building Blocks

B-Amino

Aromatic Propionic Acids

API intermediates

Carbonyl Compounds

Carboxylic Acids