1-Bromo-4-(bromomethyl)-2-methylbenzene

Product Name: 1-Bromo-4-(bromomethyl)-2-methylbenzene
CAS No.: 27561-51-9
Chemical Name: 1-Bromo-4-(bromomethyl)-2-methylbenzene
Synonyms: -2-methylbenzene;1-Bromo-4-(bromomethyl);4-bromo-3-methylbromobenzyl;4-Bromo-3-methylbenzylbromide;3-Methyl-4-bromobenzylbromide;1-Bromo-4-(bromomethyl)-2-methylbenzene;Benzene, 1-bromo-4-(bromomethyl)-2-methyl-
CBNumber: CB72498907
Molecular Formula: C8H8Br2
Formula Weight: 263.96
MOL File: 27561-51-9.mol

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1-Bromo-4-(bromomethyl)-2-methylbenzene Property

Melting point:: 26-27 °C
Boiling point:: 275.4±25.0 °C(Predicted)
Density: 1.743±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: fused solid
color: Orange/tan

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Safety

HS Code: 2909309090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC

Product number: B687573
Product name: 1-Bromo-4-(bromomethyl)-2-methylbenzene
Packaging: 500mg
Price: $130
Updated: 2021/12/16

AK Scientific

Product number: 2629AB
Product name: 1-Bromo-4-(bromomethyl)-2-methylbenzene
Packaging: 1g
Price: $151
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0356791
Product name: 1-BROMO-4-(BROMOMETHYL)-2-METHYLBENZENE
Purity: 95.00%
Packaging: 1G
Price: $202.65
Updated: 2021/12/16

Apolloscientific

Product number: OR400670
Product name: 4-Bromo-3-methylbenzylbromide
Packaging: 1g
Price: $87
Updated: 2021/12/16

SynQuest Laboratories

Product number: 1700-9-68
Product name: 4-Bromo-3-methylbenzyl bromide
Packaging: 1g
Price: $96
Updated: 2021/12/16

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1-Bromo-4-(bromomethyl)-2-methylbenzene Chemical Properties,Usage,Production

Synthesis

149104-89-2

27561-51-9

Procedure for the synthesis of 1-bromo-4-(bromomethyl)-2-toluene: To a solution of 4-bromo-3-methylbenzyl alcohol (27.5 g, 136.8 mmol) in dichloromethane (250 mL) was added triphenylphosphine (39.4 g, 150.5 mmol) and carbon tetrabromide (49.9 g, 150.5 mmol) in sequence. The reaction mixture was stirred at room temperature for 2 hours. After completion of the reaction, water was added to quench the reaction. The organic layer was separated and dried over anhydrous sodium sulfate, followed by concentration under reduced pressure to remove the solvent. The crude product was purified by column chromatography to afford 1-bromo-4-(bromomethyl)-2-toluene (34 g, 94% yield). The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 7.94-7.92 (d, 1H), 7.70 (s, 1H), 7.53-7.51 (d, 1H), 4.86 (s, 2H), 2.83 (s, 3H).

References

[1] Patent: WO2015/42532, 2015, A1. Location in patent: Paragraph 0164
[2] Patent: US2011/82165, 2011, A1. Location in patent: Page/Page column 53
[3] Patent: WO2017/34994, 2017, A1. Location in patent: Page/Page column 38
[4] Macromolecules, 2013, vol. 46, # 21, p. 8500 - 8508
[5] Patent: WO2012/67664, 2012, A1. Location in patent: Page/Page column 45

1-Bromo-4-(bromomethyl)-2-methylbenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Bromo-4-(bromomethyl)-2-methylbenzene Suppliers

China 52 India 2 United Kingdom 1 United States 4 Global 59

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27561-51-9, 1-Bromo-4-(bromomethyl)-2-methylbenzeneRelated Search:

1-Bromo-4-(bromomethyl)-2-methylbenzene

3-Methyl-4-bromobenzylbromide

4-Bromo-3-methylbenzylbromide

1-Bromo-4-(bromomethyl)

-2-methylbenzene

Benzene, 1-bromo-4-(bromomethyl)-2-methyl-

4-bromo-3-methylbromobenzyl

27561-51-9