Benzyl 6-aminonicotinate

Product Name: Benzyl 6-aminonicotinate
CAS No.: 935687-49-3
Chemical Name: Benzyl 6-aminonicotinate
Synonyms: Benzyl 6-aminonicotinate;6-Aminonicotinic acid benzyl ester;Benzyl 6-aminopyridine-3-carboxylate;2-Amino-5-(benzyloxycarbonyl)pyridine;3-Pyridinecarboxylic acid, 6-amino-, phenylmethyl ester
CBNumber: CB72502482
Molecular Formula: C13H12N2O2
Formula Weight: 228.25
MOL File: 935687-49-3.mol

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Benzyl 6-aminonicotinate Property

Boiling point:: 420.5±30.0 °C(Predicted)
Density: 1.243±0.06 g/cm3(Predicted)
storage temp.: 2-8°C(protect from light)
pka: 4.71±0.13(Predicted)

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Safety

HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B225075
Product name: Benzyl6-aminonicotinate
Packaging: 250mg
Price: $200
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0391922
Product name: BENZYL-6-AMINONICOTINATE
Purity: 95.00%
Packaging: 5MG
Price: $504.96
Updated: 2021/12/16

Crysdot

Product number: CD11009698
Product name: Benzyl6-aminonicotinate
Purity: 98%
Packaging: 250mg
Price: $62
Updated: 2021/12/16

Crysdot

Product number: CD11009698
Product name: Benzyl6-aminonicotinate
Purity: 98%
Packaging: 1g
Price: $156
Updated: 2021/12/16

Chemenu

Product number: CM177603
Product name: benzyl6-aminonicotinate
Purity: 98%
Packaging: 5g
Price: $533
Updated: 2021/12/16

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Benzyl 6-aminonicotinate Chemical Properties,Usage,Production

Synthesis

3167-49-5

100-39-0

935687-49-3

Example 46 Procedure for the synthesis of benzyl 6-{3-[7-fluoro-2-(4-fluorobenzyl)-3-oxo-2,3-dihydro-1H-isoindol-1-yl]-propionylamino}- nicotinate: A. Synthesis of benzyl 6-aminonicotinate: to a mixture of DMF (4 mL) containing 6-aminonicotinic acid (1.0 g, 7.2 mmol) and potassium carbonate (1.5 g, 10.8 mmol), benzyl bromide (0.86 ml, 7.9 mmol) was added. The reaction mixture was stirred at room temperature for 16 hours. After completion of the reaction, the reaction mixture was diluted with water (50 mL) and extracted with ethyl acetate (3 x 50 mL). The organic layers were combined, washed with saturated brine, dried over anhydrous magnesium sulfate and concentrated under reduced pressure to give the crude product. The crude product was recrystallized with ether to give the title compound as a light yellow solid (0.88 g, 53% yield).

References

[1] Patent: WO2010/29461, 2010, A1. Location in patent: Page/Page column 65-66
[2] Patent: US2007/99930, 2007, A1. Location in patent: Page/Page column 48
[3] Patent: US2011/190267, 2011, A1. Location in patent: Page/Page column 53
[4] Journal of Medicinal Chemistry, 2012, vol. 55, # 3, p. 1318 - 1333

Benzyl 6-aminonicotinate Preparation Products And Raw materials

Raw materials

Preparation Products

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Benzyl 6-aminonicotinate Suppliers

China 27 India 2 United Kingdom 1 United States 5 Global 35

Energy Chemical

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935687-49-3, Benzyl 6-aminonicotinateRelated Search:

Benzyl 6-aminonicotinate

Benzyl 6-aminopyridine-3-carboxylate

2-Amino-5-(benzyloxycarbonyl)pyridine

6-Aminonicotinic acid benzyl ester

3-Pyridinecarboxylic acid, 6-amino-, phenylmethyl ester

935687-49-3