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3-(4-Bromophenyl)-4H-1,2,4-triazole

Product Name
3-(4-Bromophenyl)-4H-1,2,4-triazole
CAS No.
118863-62-0
Chemical Name
3-(4-Bromophenyl)-4H-1,2,4-triazole
Synonyms
3-(4-Bromophenyl)-4H-1,2,4-triazole;5-(4-broMophenyl)-1H-1,2,4-triazole;1H-1,2,4-Triazole, 5-(4-bromophenyl)-
CBNumber
CB72513154
Molecular Formula
C8H6BrN3
Formula Weight
224.06
MOL File
118863-62-0.mol
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3-(4-Bromophenyl)-4H-1,2,4-triazole Property

Boiling point:
376.7±44.0 °C(Predicted)
Density 
1.651±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
9.28±0.20(Predicted)
Appearance
White to off-white Solid
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
B700290
Product name
3-(4-Bromophenyl)-1H-[1,2,4]triazole
Packaging
500mg
Price
$155
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB138820
Product name
3-(4-Bromophenyl)-1H-1,2,4-triazole
Packaging
500mg
Price
$165
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB138820
Product name
3-(4-Bromophenyl)-1H-1,2,4-triazole
Packaging
1g
Price
$260
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB138820
Product name
3-(4-Bromophenyl)-1H-1,2,4-triazole
Packaging
100mg
Price
$60
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB138820
Product name
3-(4-Bromophenyl)-1H-1,2,4-triazole
Packaging
250mg
Price
$105
Updated
2021/12/16
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3-(4-Bromophenyl)-4H-1,2,4-triazole Chemical Properties,Usage,Production

Synthesis

1269646-41-4

118863-62-0

The general procedure for the synthesis of 3-(4-bromophenyl)-1H-[1,2,4]triazole from the compound (CAS:1269646-41-4) is as follows: Example 7: Preparation of 3-(4-bromophenyl)-1H-1,2,4-triazole (C4) 1. cool 17.2 g (67.3 mmol) of a 35 mL solution of (E)-4-bromo-N-((dimethylamino)methylene)benzamide (C3) in an ice bath in 35 mL of acetic acid. 2. 6.50 mL (104 mmol) of hydrazine monohydrate was added slowly while stirring vigorously. Observe that a white solid begins to form. 3. The reaction mixture was heated to 90°C for 3 hours. 4. Upon completion of the reaction, the solution was cooled to room temperature and poured into 150 mL of cold water. 5. The precipitate was collected by filtration, washed with cold water, and then dried under vacuum overnight to afford 3-(4-bromophenyl)-1H-[1,2,4]triazole as a white solid (14.5 g, 91% yield). Product characterization: melting point >200 °C (decomposition); 1H NMR (400 MHz, DMSO-d6) δ 14.24 (s, 1H), 8.52 (s, 1H), 8.04-7.91 (m, 2H), 7.75-7.63 (m, 2H); ESIMS m/z 224 ([M]+).

References

[1] Patent: US2016/24027, 2016, A1. Location in patent: Paragraph 0172-0173
[2] Patent: US2014/274688, 2014, A1. Location in patent: Paragraph 0378; 0379

3-(4-Bromophenyl)-4H-1,2,4-triazole Preparation Products And Raw materials

Raw materials

Preparation Products

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3-(4-Bromophenyl)-4H-1,2,4-triazole Suppliers

Heterochem
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027-88041443 13072715837
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Shanghai Topbiochem Technology Co., Ltd
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Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.
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Shanghai Jovan Biochemical Technology Co. Ltd.
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Shanghai Tombiopharma Chemical Co. Ltd.
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Shanghai CP Pharmaceutical Technology Co., Ltd.
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View Lastest Price from 3-(4-Bromophenyl)-4H-1,2,4-triazole manufacturers

Career Henan Chemical Co
Product
3-(4-Bromophenyl)-4H-1,2,4-triazole 118863-62-0
Price
US $2.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
ask
Release date
2019-12-24

118863-62-0, 3-(4-Bromophenyl)-4H-1,2,4-triazoleRelated Search:


  • 5-(4-broMophenyl)-1H-1,2,4-triazole
  • 3-(4-Bromophenyl)-4H-1,2,4-triazole
  • 1H-1,2,4-Triazole, 5-(4-bromophenyl)-
  • 118863-62-0