Methyl 4-(benzyloxy)-5-methoxy-2-nitrobenzoate
- Product Name
- Methyl 4-(benzyloxy)-5-methoxy-2-nitrobenzoate
- CAS No.
- 61032-41-5
- Chemical Name
- Methyl 4-(benzyloxy)-5-methoxy-2-nitrobenzoate
- Synonyms
- ethyl 4-(benzyloxy)-5-Methoxy-2-nitrobenzoate;Methyl 4-(benzyloxy)-5-methoxy-2-nitrobenzoate;Methyl 5-methoxy-2-nitro-4-(benzyloxy)benzoate;methyl 5-methoxy-2-nitro-4-phenylmethoxybenzoate;4-Benzyloxy-5-methoxy-2-nitrobenzoic acid methyl ester;Benzoic acid, 5-Methoxy-2-nitro-4-(phenylMethoxy)-, Methyl ester
- CBNumber
- CB72520767
- Molecular Formula
- C16H15NO6
- Formula Weight
- 317.29
- MOL File
- 61032-41-5.mol
Methyl 4-(benzyloxy)-5-methoxy-2-nitrobenzoate Property
- Boiling point:
- 482.4±40.0 °C(Predicted)
- Density
- 1.280
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- White to off-white Solid
- InChI
- InChI=1S/C16H15NO6/c1-21-14-8-12(16(18)22-2)13(17(19)20)9-15(14)23-10-11-6-4-3-5-7-11/h3-9H,10H2,1-2H3
- InChIKey
- GUOGVJFNFLXSLK-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC(OC)=C(OCC2=CC=CC=C2)C=C1[N+]([O-])=O
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M600000
- Product name
- Methyl4-(Benzyloxy)-5-methoxy-2-nitrobenzoate
- Packaging
- 500mg
- Price
- $110
- Updated
- 2021/12/16
- Product number
- CS-M0194
- Product name
- methyl4-(benzyloxy)-5-methoxy-2-nitrobenzoate
- Purity
- 97.61%
- Packaging
- 25g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- CS-M0194
- Product name
- methyl4-(benzyloxy)-5-methoxy-2-nitrobenzoate
- Purity
- 97.61%
- Packaging
- 100g
- Price
- $230
- Updated
- 2021/12/16
- Product number
- CS-M0194
- Product name
- methyl4-(benzyloxy)-5-methoxy-2-nitrobenzoate
- Purity
- 97.61%
- Packaging
- 1g
- Price
- $9
- Updated
- 2021/12/16
- Product number
- CS-M0194
- Product name
- methyl4-(benzyloxy)-5-methoxy-2-nitrobenzoate
- Purity
- 97.61%
- Packaging
- 5g
- Price
- $22
- Updated
- 2021/12/16
Methyl 4-(benzyloxy)-5-methoxy-2-nitrobenzoate Chemical Properties,Usage,Production
Synthesis
56441-97-5
61032-41-5
4.1.4 Synthesis of methyl 4-benzyloxy-5-methoxy-2-nitrobenzoate (12): intermediate 11 (10.1 g, 37 mmol) was suspended in acetic acid (100 mL) and 70% nitric acid (20 mL) was added slowly. Subsequently, the reaction mixture was heated to 50 °C and maintained at this temperature for 5 hours. Upon completion of the reaction, the mixture was cooled to room temperature and poured into ice water (500 mL). After stirring for 1 hour, the precipitate precipitated was collected by filtration, washed with water and dried to give nitro compound 12 as a white solid. Yield: 86%, melting point: 126-128°C.
References
[1] Patent: WO2016/148674, 2016, A1. Location in patent: Page/Page column 114
[2] Patent: US2009/76044, 2009, A1. Location in patent: Page/Page column 26
[3] Patent: US2017/95570, 2017, A1. Location in patent: Paragraph 0571; 0573
[4] Patent: US2014/235634, 2014, A1. Location in patent: Paragraph 0390; 0392
[5] Asian Journal of Chemistry, 2015, vol. 27, # 7, p. 2647 - 2650
Methyl 4-(benzyloxy)-5-methoxy-2-nitrobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Methyl 4-(benzyloxy)-5-methoxy-2-nitrobenzoate manufacturers
- Product
- methyl 4-(benzyloxy)-5-methoxy-2-nitrobenzoate 61032-41-5
- Price
- US $0.00/kg
- Min. Order
- 10kg
- Purity
- 99%
- Supply Ability
- 10 tons
- Release date
- 2025-05-11
- Product
- Methyl 4-(benzyloxy)-5-methoxy-2-nitrobenzoate 61032-41-5
- Price
- US $10.00/g
- Min. Order
- 10g
- Purity
- 0.99
- Supply Ability
- 1ton
- Release date
- 2024-10-31
- Product
- Methyl 4-(benzyloxy)-5-methoxy-2-nitrobenzoate 61032-41-5
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 95%-99%
- Supply Ability
- 1kg; 100kg; 1000kg
- Release date
- 2019-12-24