Hercynine

ChemicalBook > CAS DataBase List > Hercynine

Product Name: Hercynine
CAS No.: 534-30-5
Chemical Name: Hercynine
Synonyms: Hercynine;Histidine-betaine;N(alpha),N(alpha),N(alpha)-trimethyl-L-histidine;N(alpha),N(alpha),N(alpha)-trimethyl-L-histidinium(1+);(S)-3-(1H-Imidazol-5-yl)-2-(trimethylammonio)propanoate;(alphaS)-alpha-Carboxy-N,N,N-trimethyl-1H-imidazole-4-ethanaminium inner salt;(S) -3- (1H imidazol-5-yl) -2-trimethylammonium) propionic acid internal salt
CBNumber: CB72520909
Molecular Formula: C9H15N3O2
Formula Weight: 197.24
MOL File: 534-30-5.mol

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Hercynine Property

Melting point:: 237-238° (dec)
alpha: D22 +44.5° (5N HCl)
solubility: Methanol (Slightly), Water (Slightly)
form: Solid
color: Off-White to Pale Yellow
Stability:: Hygroscopic
InChI: InChI=1/C9H15N3O2/c1-12(2,3)8(9(13)14)4-7-5-10-6-11-7/h5-6,8H,4H2,1-3H3,(H-,10,11,13,14)/t8-/s3
InChIKey: GPPYTCRVKHULJH-SBYBRXNCNA-N
SMILES: [C@H](C(=O)[O-])([N+](C)(C)C)CC1NC=NC=1 |&1:0,r|

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: H288900
Product name: L-Hercynine
Packaging: 250mg
Price: $640
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: PXT0002264
Product name: HERCYNINE
Purity: 95.00%
Packaging: 5MG
Price: $505.59
Updated: 2021/12/16

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Hercynine Chemical Properties,Usage,Production

Uses

L-Hercynine is a precursor of L-(+)-Ergothioneine (E600000); a natural molecule isolated from the rye ergot fungus and later identified in rat erythrocytes and liver and in numerous other animal tissues. Its antioxidizing properties may afford the compound therapeutic potential or it may be used as a food additive or in cosmetics.

Definition

ChEBI: N(alpha),N(alpha),N(alpha)-trimethyl-L-histidine is an amino-acid betaine and a member of N(alpha)-methyl-L-histidines. It is a conjugate base of a N(alpha),N(alpha),N(alpha)-trimethyl-L-histidinium(1+).

Definition

Hercynine is an intermediate (precursor) in ERGO biosynthesis; thus, fungi and mycobacteria can synthesize hercynine, but animals cannot. A human study showed that hercynine was detected in whole blood, plasma, urine, and saliva, and another clinical study showed that the levels of hercynine correlated with those of ERGO in whole blood, which suggested that hercynine is a metabolite of ERGO. However, the levels of hercynine were lower than those of ERGO, which presented the possibility that hercynine was further oxidized.

Hercynine Preparation Products And Raw materials

Raw materials

Preparation Products

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534-30-5, HercynineRelated Search:

N(alpha),N(alpha),N(alpha)-trimethyl-L-histidinium(1+)

N(alpha),N(alpha),N(alpha)-trimethyl-L-histidine

Hercynine

(S)-3-(1H-Imidazol-5-yl)-2-(trimethylammonio)propanoate

Histidine-betaine

(S) -3- (1H imidazol-5-yl) -2-trimethylammonium) propionic acid internal salt

(alphaS)-alpha-Carboxy-N,N,N-trimethyl-1H-imidazole-4-ethanaminium inner salt

534-30-5