Methyl 2-aMino-3-Methoxybenzoate
- Product Name
- Methyl 2-aMino-3-Methoxybenzoate
- CAS No.
- 5121-34-6
- Chemical Name
- Methyl 2-aMino-3-Methoxybenzoate
- Synonyms
- Benzoic acid, 2-aMino-3-Methoxy-, Methyl ester;Methyl 2-Amino-m-anisate;Methyl 3-methoxyanthranilate;methyl 2-amino-3-methoxybenzo;Methyl 2-aMino-3-Methoxybenzoate;Methyl 3-methoxy-2-aminobenzoate;Methyl 2-aMino-3-Methoxybenzoatec;Methyl -2-amino-3-methoy benzoate;2-Amino-m-anisic Acid Methyl Ester;2-Amino-3-methoxy-benzoic acid methyl ester
- CBNumber
- CB72549812
- Molecular Formula
- C9H11NO3
- Formula Weight
- 181.19
- MOL File
- 5121-34-6.mol
Methyl 2-aMino-3-Methoxybenzoate Property
- Melting point:
- 46.0 to 50.0 °C
- Boiling point:
- 117°C/2mmHg(lit.)
- Density
- 1.179±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- powder to crystal
- pka
- 2.13±0.10(Predicted)
- color
- White to Yellow to Orange
- InChI
- InChI=1S/C9H11NO3/c1-12-7-5-3-4-6(8(7)10)9(11)13-2/h3-5H,10H2,1-2H3
- InChIKey
- YJEZEMGLLFLMDF-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=CC(OC)=C1N
Safety
- HS Code
- 2922500090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P363Wash contaminated clothing before reuse.
P391Collect spillage. Hazardous to the aquatic environment
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- M2822
- Product name
- Methyl 2-Amino-3-methoxybenzoate
- Purity
- >98.0%(GC)(T)
- Packaging
- 1g
- Price
- $96
- Updated
- 2025/07/31
- Product number
- M2822
- Product name
- Methyl 2-Amino-3-methoxybenzoate
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $288
- Updated
- 2025/07/31
- Product number
- M331508
- Product name
- Methyl 2-Amino-3-methoxybenzoate
- Packaging
- 500mg
- Price
- $130
- Updated
- 2021/12/16
- Product number
- FA67661
- Product name
- 2-Amino-3-methoxybenzoic acid methyl ester
- Packaging
- 2g
- Price
- $72
- Updated
- 2021/12/16
- Product number
- 119297
- Product name
- Methyl 2-amino-3-methoxybenzoate
- Purity
- 95+%
- Packaging
- 1g
- Price
- $118
- Updated
- 2021/12/16
Methyl 2-aMino-3-Methoxybenzoate Chemical Properties,Usage,Production
Synthesis
67-56-1
3177-80-8
5121-34-6
(c) Synthesis of methyl 2-amino-3-methoxybenzoate: To a solution of 2-amino-3-methoxybenzoic acid (34.5 g, 206 mmol) in methanol (250 mL) was slowly added concentrated sulfuric acid (50 mL). The reaction mixture was heated to 95 °C and kept reacting overnight. Upon completion of the reaction, the mixture was cooled to room temperature and subsequently concentrated under vacuum. The resulting residue was a beige-colored slurry, which was mixed with ether and slowly poured into a mixture of ether and a cold saturated aqueous sodium carbonate solution containing an excess of sodium carbonate. The ether layer is separated and the aqueous layer is extracted twice more with ether. The ether extracts were combined, washed sequentially with dilute sodium hydroxide solution (twice), brine, dried with anhydrous sodium sulfate, filtered through a short silica gel column, and finally concentrated in vacuum to give methyl 2-amino-3-methoxybenzoate (34.0 g, 91% yield) as a brown solid.LC-MS (ES) m/z = 182 [M + H]+.
References
[1] Patent: WO2014/195919, 2014, A1. Location in patent: Page/Page column 68
[2] Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985, vol. 24, p. 602 - 604
[3] Patent: WO2007/30582, 2007, A2. Location in patent: Page/Page column 95
Methyl 2-aMino-3-Methoxybenzoate Preparation Products And Raw materials
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View Lastest Price from Methyl 2-aMino-3-Methoxybenzoate manufacturers
- Product
- methyl 2-amino-3-methoxybenzoate 5121-34-6
- Price
- US $0.00/kg
- Min. Order
- 20kg
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2024-08-26
- Product
- Methyl 2-aMino-3-Methoxybenzoate 5121-34-6
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 99%min
- Supply Ability
- 500kg
- Release date
- 2020-03-06
- Product
- Methyl 2-aMino-3-Methoxybenzoate 5121-34-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 95-99%
- Supply Ability
- 1ton
- Release date
- 2020-01-08