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Methyl 2-aMino-3-Methoxybenzoate

Product Name
Methyl 2-aMino-3-Methoxybenzoate
CAS No.
5121-34-6
Chemical Name
Methyl 2-aMino-3-Methoxybenzoate
Synonyms
Benzoic acid, 2-aMino-3-Methoxy-, Methyl ester;Methyl 2-Amino-m-anisate;Methyl 3-methoxyanthranilate;methyl 2-amino-3-methoxybenzo;Methyl 2-aMino-3-Methoxybenzoate;Methyl 3-methoxy-2-aminobenzoate;Methyl 2-aMino-3-Methoxybenzoatec;Methyl -2-amino-3-methoy benzoate;2-Amino-m-anisic Acid Methyl Ester;2-Amino-3-methoxy-benzoic acid methyl ester
CBNumber
CB72549812
Molecular Formula
C9H11NO3
Formula Weight
181.19
MOL File
5121-34-6.mol
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Methyl 2-aMino-3-Methoxybenzoate Property

Melting point:
46.0 to 50.0 °C
Boiling point:
117°C/2mmHg(lit.)
Density 
1.179±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
powder to crystal
pka
2.13±0.10(Predicted)
color 
White to Yellow to Orange
InChI
InChI=1S/C9H11NO3/c1-12-7-5-3-4-6(8(7)10)9(11)13-2/h3-5H,10H2,1-2H3
InChIKey
YJEZEMGLLFLMDF-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=CC(OC)=C1N
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Safety

HS Code 
2922500090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P363Wash contaminated clothing before reuse.

P391Collect spillage. Hazardous to the aquatic environment

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
M2822
Product name
Methyl 2-Amino-3-methoxybenzoate
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$96
Updated
2025/07/31
TCI Chemical
Product number
M2822
Product name
Methyl 2-Amino-3-methoxybenzoate
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$288
Updated
2025/07/31
TRC
Product number
M331508
Product name
Methyl 2-Amino-3-methoxybenzoate
Packaging
500mg
Price
$130
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA67661
Product name
2-Amino-3-methoxybenzoic acid methyl ester
Packaging
10g
Price
$300
Updated
2021/12/16
Matrix Scientific
Product number
119297
Product name
Methyl 2-amino-3-methoxybenzoate
Purity
95+%
Packaging
5g
Price
$468
Updated
2021/12/16
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Methyl 2-aMino-3-Methoxybenzoate Chemical Properties,Usage,Production

Synthesis

67-56-1

3177-80-8

5121-34-6

(c) Synthesis of methyl 2-amino-3-methoxybenzoate: To a solution of 2-amino-3-methoxybenzoic acid (34.5 g, 206 mmol) in methanol (250 mL) was slowly added concentrated sulfuric acid (50 mL). The reaction mixture was heated to 95 °C and kept reacting overnight. Upon completion of the reaction, the mixture was cooled to room temperature and subsequently concentrated under vacuum. The resulting residue was a beige-colored slurry, which was mixed with ether and slowly poured into a mixture of ether and a cold saturated aqueous sodium carbonate solution containing an excess of sodium carbonate. The ether layer is separated and the aqueous layer is extracted twice more with ether. The ether extracts were combined, washed sequentially with dilute sodium hydroxide solution (twice), brine, dried with anhydrous sodium sulfate, filtered through a short silica gel column, and finally concentrated in vacuum to give methyl 2-amino-3-methoxybenzoate (34.0 g, 91% yield) as a brown solid.LC-MS (ES) m/z = 182 [M + H]+.

References

[1] Patent: WO2014/195919, 2014, A1. Location in patent: Page/Page column 68
[2] Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985, vol. 24, p. 602 - 604
[3] Patent: WO2007/30582, 2007, A2. Location in patent: Page/Page column 95

Methyl 2-aMino-3-Methoxybenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-aMino-3-Methoxybenzoate Suppliers

Alchem Pharmtech,Inc.
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8485655694
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sales@alchempharmtech.com
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United States
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Aladdin Scientific
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tp@aladdinsci.com
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United States
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57505
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Aceschem Inc.
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+1-817863-6948 +1-(817)863-6948
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sales@aceschem.com
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United States
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19632
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Alichem Inc.
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United States
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OChem Incorporation
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sales@ocheminc.com
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United States
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TCI America
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sales@tciamerica.com
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United States
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Matrix Scientific
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sales@matrixscientific.com
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United States
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6632
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View Lastest Price from Methyl 2-aMino-3-Methoxybenzoate manufacturers

Qingdao RENAS Polymer Material Co., Ltd.
Product
methyl 2-amino-3-methoxybenzoate 5121-34-6
Price
US $0.00/kg
Min. Order
20kg
Purity
99%
Supply Ability
20 tons
Release date
2024-08-26
Career Henan Chemical Co
Product
Methyl 2-aMino-3-Methoxybenzoate 5121-34-6
Price
US $3.00/KG
Min. Order
1KG
Purity
99%min
Supply Ability
500kg
Release date
2020-03-06
Career Henan Chemical Co
Product
Methyl 2-aMino-3-Methoxybenzoate 5121-34-6
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
1ton
Release date
2020-01-08

5121-34-6, Methyl 2-aMino-3-MethoxybenzoateRelated Search:


  • Methyl 2-aMino-3-Methoxybenzoate
  • Benzoic acid, 2-aMino-3-Methoxy-, Methyl ester
  • Methyl 2-aMino-3-Methoxybenzoatec
  • 2-Amino-3-methoxy-benzoic acid methyl ester
  • Methyl 3-methoxy-2-aminobenzoate
  • Methyl 3-methoxyanthranilate
  • 2-Amino-m-anisic Acid Methyl Ester
  • Methyl 2-Amino-m-anisate
  • Methyl -2-amino-3-methoy benzoate
  • methyl 2-amino-3-methoxybenzo
  • 5121-34-6