ChemicalBook > CAS DataBase List > (+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE

(+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE

Product Name
(+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE
CAS No.
109306-21-0
Chemical Name
(+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE
Synonyms
3R)-1;Bishydroxydiphenylmethylphenyldioxolane;(+)-4,5-Bis[hydroxy(diphenyl)methyl-2-phenyl-1,3-dioxolane;(+)-(4R,5R)-BIS[HYDROXY(DIPHENYL)METHYL]-2-PHENYL-1,3-DIOXOLANE;(+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane;(4R,5R)-2-Methyl-α,α,α',α',2-pentaphenyl-1,3-dioxolane-4,5-dimethanol;[(4R,5R)-2-Methyl-2-phenyl-1,3-dioxolane-4,5-diyl]bis(diphenylMethanol);(4R,5R)-2-Methyl-α4,α4,α5,α5,2-pentaphenyl-1,3-dioxolane-4,5-dimethanol;(2R,3R)-2,3-O-(1-PHENYLETHYLIDENE)-1,1,4,4-TETRAPHENYL-1,2,3,4-BUTANETETROL;(2R,3R)-1,1,4,4-TETRAPHENYL-2,3-O-(1-PHENYLETHYLIDENE)-1,2,3,4-BUTANETETROL
CBNumber
CB7255577
Molecular Formula
C36H32O4
Formula Weight
528.64
MOL File
109306-21-0.mol
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(+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE Property

Melting point:
120 °C
Boiling point:
701.9±55.0 °C(Predicted)
Density 
1+-.0.06 g/cm3(Predicted)
pka
12.28±0.29(Predicted)
form 
powder to crystal
color 
White to Orange to Green
InChIKey
QVQMFUMIQACODH-DPMCXAKDNA-N
SMILES
[C@H]1(O[C@](C)(C2C=CC=CC=2)O[C@H]1C(O)(C1C=CC=CC=1)C1=CC=CC=C1)C(O)(C1=CC=CC=C1)C1=CC=CC=C1 |&1:0,2,11,r|
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Safety

HS Code 
2932.99.7000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B1615
Product name
(+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane
Packaging
1g
Price
$148
Updated
2026/03/19
TRC
Product number
B447443
Product name
(+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane
Packaging
10mg
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB59915
Product name
(+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane
Packaging
250mg
Price
$67
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB59915
Product name
(+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane
Packaging
500mg
Price
$116
Updated
2021/12/16
AK Scientific
Product number
3950AL
Product name
(+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane
Packaging
250mg
Price
$141
Updated
2021/12/16
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(+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE Chemical Properties,Usage,Production

Uses

(+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane (CAS# 109306-21-0) is a TADDOL (α,α,α'',α''-tetraaryl-2,2-disubstituted 1,3-dioxolane-4,5-dimethanol) and is a chiral building block used in the perparation of optically active organotin derivatives. Via Ni catalyzation, (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane has been used in the cycloisomerization of dienes.

(+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE Suppliers

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109306-21-0, (+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANERelated Search:


  • (2R,3R)-1,1,4,4-TETRAPHENYL-2,3-O-(1-PHENYLETHYLIDENE)-1,2,3,4-BUTANETETROL
  • (2R,3R)-2,3-O-(1-PHENYLETHYLIDENE)-1,1,4,4-TETRAPHENYL-1,2,3,4-BUTANETETROL
  • (+)-(4R,5R)-BIS[HYDROXY(DIPHENYL)METHYL]-2-PHENYL-1,3-DIOXOLANE
  • (+)-4,5-Bis[hydroxy(diphenyl)methyl-2-phenyl-1,3-dioxolane
  • Bishydroxydiphenylmethylphenyldioxolane
  • (2R,3R)-2,3-O-(1-Phenylethylidene)-1,1,4,4-tetraphenyl-1,2,3,4-butanetetrol (2R,3R)-1,1,4,4-Tetraphenyl-2,3-O-(1-phenylethylidene)-1,2,3,4-butanetetrol [(4R,5R)-2-Methyl-2-phenyl-1,3-dioxolane-4,5-diyl]bis(diphenylmethanol)
  • [(4R,5R)-2-Methyl-2-phenyl-1,3-dioxolane-4,5-diyl]bis(diphenylMethanol)
  • 3R)-1
  • (4R,5R)-2-Methyl-α,α,α',α',2-pentaphenyl-1,3-dioxolane-4,5-dimethanol
  • (4R,5R)-2-Methyl-alpha,alpha,alpha',alpha',2-pentaphenyl-1,3-dioxolane-4,5-dimethanol
  • 1,3-Dioxolane-4,5-dimethanol, 2-methyl-α4,α4,α5,α5,2-pentaphenyl-, (4R,5R)-
  • (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane
  • (4R,5R)-2-Methyl-α4,α4,α5,α5,2-pentaphenyl-1,3-dioxolane-4,5-dimethanol
  • 109306-21-0
  • C36H32O4
  • Dioxanes & Dioxolanes
  • Asymmetric Synthesis
  • Dioxolanes
  • Asymmetric Synthesis
  • Dioxanes & Dioxolanes
  • Dioxolanes
  • Synthetic Organic Chemistry